scholarly journals Aspects of the thermogravimetric analysis of liquid mixtures as predictive or interpretation tool for batch distillation

2021 ◽  
Author(s):  
Antonio Tripodi ◽  
Ilenia Rossetti
Keyword(s):  
Thermogravimetric Analysis ◽  
Liquid Mixtures ◽  
Fast Method ◽  
Batch Distillation ◽  
Liquid Equilibrium ◽  
Distillation Design ◽  
Energy Balances ◽  
First Time ◽  
Liquid Binary Mixtures ◽  
Mass And Energy Balances

AbstractThe thermogravimetric analysis when applied to liquid binary mixtures of acetonitrile–water and methanol–water reproduces the whole course of a batch distillation with an appreciable saving of time and materials. The experimental mass and energy balances correlate with good approximation to the vapor–liquid equilibrium compositions without the need of gas-phase measures or thermodynamic models. This technique was here applied for the first time as fast method for distillation design and complementary tool for DSC boiling-point measurements.

Innovative energy and mass balance of a continuous evaporating crystallizer

2019 ◽  
pp. 646-654
Author(s):  
Jan Iciek ◽  
Kornel Hulak ◽  
Radosław Gruska
Keyword(s):  
Energy Balance ◽  
Mass Balance ◽  
Working Conditions ◽  
Crystallization Process ◽  
Heat Losses ◽  
Inert Gas ◽  
Gas Removal ◽  
Energy Balances ◽  
Heat Released ◽  
Mass And Energy Balances

The article presents the mass and energy balances of the sucrose crystallization process in a continuous evaporating crystallizer. The developed algorithm allows to assess the working conditions of the continuous evaporating crystallizers and the technological and energy parameters. The energy balance algorithm takes into account the heat released during the crystallization of sucrose, which was analyzed in this study, heat losses to the environment and heat losses due the vapor used for inert gas removal.

scholarly journals Reactive Dual Magnetron Sputtering: A Fast Method for Preparing Stoichiometric Microcrystalline ZnWO4 Thin Films

Surfaces ◽  
2021 ◽  
Vol 4 (2) ◽  
pp. 106-114
Author(s):  
Yannick Hermans ◽  
Faraz Mehmood ◽  
Kerstin Lakus-Wollny ◽  
Jan P. Hofmann ◽  
Thomas Mayer ◽  
...  
Keyword(s):  
Thin Films ◽  
Magnetron Sputtering ◽  
Photoelectron Spectroscopy ◽  
Fast Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Glass Substrates ◽  
Post Annealing ◽  
Rf Signal ◽  
First Time

Thin films of ZnWO4, a promising photocatalytic and scintillator material, were deposited for the first time using a reactive dual magnetron sputtering procedure. A ZnO target was operated using an RF signal, and a W target was operated using a DC signal. The power on the ZnO target was changed so that it would match the sputtering rate of the W target operated at 25 W. The effects of the process parameters were characterized using optical spectroscopy, X-ray diffraction, and scanning electron microscopy, including energy dispersive X-ray spectroscopy as well as X-ray photoelectron spectroscopy. It was found that stoichiometric microcrystalline ZnWO4 thin films could be obtained, by operating the ZnO target during the sputtering procedure at a power of 55 W and by post-annealing the resulting thin films for at least 10 h at 600 °C. As FTO coated glass substrates were used, annealing led as well to the incorporation of Na, resulting in n+ doped ZnWO4 thin films.

Mass and energy balances of an autothermal pilot carbonization unit

2019 ◽  
Vol 120 ◽  
pp. 144-155 ◽  
Author(s):  
Andrea Maria Rizzo ◽  
Marco Pettorali ◽  
Renato Nistri ◽  
David Chiaramonti
Keyword(s):  
Energy Balances ◽  
Mass And Energy Balances

scholarly journals A continuum model for meltwater flow through compacting snow

2017 ◽  
Vol 11 (6) ◽  
pp. 2799-2813 ◽  
Author(s):  
Colin R. Meyer ◽  
Ian J. Hewitt
Keyword(s):  
Continuum Model ◽  
Pore Space ◽  
Water Storage ◽  
Greenland Ice Sheet ◽  
Percolation Process ◽  
Surface Mass ◽  
Run Off ◽  
Flow Through ◽  
Energy Balances ◽  
Mass And Energy Balances

Abstract. Meltwater is produced on the surface of glaciers and ice sheets when the seasonal energy forcing warms the snow to its melting temperature. This meltwater percolates into the snow and subsequently runs off laterally in streams, is stored as liquid water, or refreezes, thus warming the subsurface through the release of latent heat. We present a continuum model for the percolation process that includes heat conduction, meltwater percolation and refreezing, as well as mechanical compaction. The model is forced by surface mass and energy balances, and the percolation process is described using Darcy's law, allowing for both partially and fully saturated pore space. Water is allowed to run off from the surface if the snow is fully saturated. The model outputs include the temperature, density, and water-content profiles and the surface runoff and water storage. We compare the propagation of freezing fronts that occur in the model to observations from the Greenland Ice Sheet. We show that the model applies to both accumulation and ablation areas and allows for a transition between the two as the surface energy forcing varies. The largest average firn temperatures occur at intermediate values of the surface forcing when perennial water storage is predicted.

scholarly journals Exergy analysis of a co-generation plant

2008 ◽  
Vol 12 (4) ◽  
pp. 75-88 ◽  
Author(s):  
Nenad Ferdelji ◽  
Antun Galovic ◽  
Zvonimir Guzovic
Keyword(s):  
Exergy Analysis ◽  
Plant Performance ◽  
Total System ◽  
Process Unit ◽  
Generation Plant ◽  
Thermodynamic Performance ◽  
Valuable Method ◽  
Energy Balances ◽  
Mass And Energy Balances ◽  
Research Resources

Limitations of traditional first-law analysis, based upon thermodynamic performance of process unit coupled with mass and energy balances, are not a serious limitation when dealing with familiar systems. However, when dealing with more uncongenial, complex ones, it provides incomplete insight for such evaluation. These limitations came from the fact that first-law analysis does not indicate the sources or magnitudes of entropy production, which is, by the second law, essential criterion for scaling losses. An evaluation of plant performance will usually require a comparison of the thermodynamic performance of process units with available data from existing plants. Therefore, exergy analysis is more than useful, providing information about magnitudes of losses and their distribution throughout the system as well. Such analysis is very thankful at the level of process units but applied on higher system levels e.g. the comparison of overall plant performance (total system) or the performance of subsystems, represents the valuable method for indicating where research resources can be directed to best advantage.

scholarly journals Isolation and Identification of Vibrio cholerae causes Epidemic cholera 2007 in Iraq by Rapid Method (Immunochromatographic one step rapid visual test) and comparing it with the traditional Bacterlogical Methods

2011 ◽  
Vol 8 (1) ◽  
pp. 29-34
Author(s):  
Baghdad Science Journal
Keyword(s):  
Vibrio Cholerae ◽  
Rapid Method ◽  
Fast Method ◽  
Visual Test ◽  
Cultural Characteristics ◽  
Isolation And Identification ◽  
One Step ◽  
Anti Body ◽  
First Time ◽  
Cultural Media

This study was for searching for Cholera Bacteria serotype which causes epidemiology Cholera in the 2007 in a fast method which contains (Rapid Visual Test) (Crystal V.C.) which was used for the first time in Iraq to diagnosis of Cholera Bacteria & compared with the traditional bacteriology method. The Cholera disease is one of the most dangerous epidemiological diseases which lead to death with a percentage of (50 – 70) % in the severe cases for untreated patients . For this purpose, 100 samples of stool from the patients from a (13) hospitals in Baghdad Governorate in the period from August to the end of December. The Cholera was diagnosis in two methods, 1st method was the fast method using the nitrocellulose which is coated with anti-body of Cholera Bacteria .The results was compared with the 2nd method which depends on the cultural characteristics of the cultural media, also the bacteria was diagnosis using the biochemical inspects by the system of API 20E in addition to the using of antisera to specify serotype& sub-serotype ( Monovalent, Polyvalent(O1) . Also, the relation between the disease & the months in the year in which the disease appear was studied. The results show the ability to isolate & identifecate (78) isolate for the serotype (01) in the fast method ( Rapid Visual Test ) ( Crystal V-C ) , & after the bacteriology inspects on these (78) isolate the all isolates were belongs for Cholera Bacteria of the serotype (01) till the sub-serotype , all the (78) isolates were belongs to the sub-serotype (Inaba). The results show, the most infection was in September (36) , & October (22).

From Component to Macro Energy Systems: A Common Design and Off-Design Modeling Approach

2011 ◽  
Author(s):  
S. Rech ◽  
A. Lazzaretto
Keyword(s):  
Energy Systems ◽  
Level Of Detail ◽  
Design Specification ◽  
Mathematical Functions ◽  
Independent Variables ◽  
Performance Curves ◽  
Systems Models ◽  
Energy And Momentum ◽  
Energy Balances ◽  
Mass And Energy Balances

A common approach for simulation of energy systems at design and off-design conditions is presented, which uses the same concepts and terminology independently of system dimension, complexity and detail. The paper shows that the higher the dimension of the system, the simpler is the model of each part of the system, but concepts and approach to built the model remain the same, being those commonly used in the literature. The approach consists in organizing energy systems models according to some criteria, which help enhance system models comprehension, and build them more easily. For any dimension and level of detail of the system these criteria consist in identifying the design specification from the environment surrounding the system, choosing the independent variables depending on the nature of the model, organizing them into categories, defining performance curves (characteristic maps) of each part of the system and organizing mass and energy balances into categories. Particular emphasis is given on modeling of system units behavior, which is generally described by the mathematical functions (characteristic maps) linking outflow to inflow variables. Examples of characteristic maps of the system units at each level of detail are shown, and models are then completed by mass, energy and momentum balances linking the behavior of all system units.

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