scholarly journals Hydraulic fracturing flowback chemical composition diversity as a factor determining possibilities of its management

Author(s):  
Joanna Fajfer ◽  
Olga Lipińska ◽  
Monika Konieczyńska

AbstractThe chemical characteristic of flowback fluid from hydraulic fracturing for shale gas exploration/production in various localizations is presented. The results of statistical analysis have shown that variability in the chemical composition of these fluids is statistically significant and depends on the time difference between fracturing process and flowback sampling as well as sampling spot within the installation for flowback collection. Parameters which depend on sampling schedule (time and spot of sampling) are as follows: electrical conductivity and concentration of ammonia, boron, barium, calcium, lithium, sodium, magnesium, manganese, sodium, strontium, silicate, bromide, and chloride. Independent parameters are pH, total organic carbon (TOC), concentration of potassium, and iron. The ranges of the values of the characteristic parameters were determined, taking into account the representativeness of the samples, supported by statistical tests. The methods for the reuse of flowback fluids in terms of chemical composition are presented.

2021 ◽  
Vol 74 (8) ◽  
pp. 1869-1875
Author(s):  
Svitlana P. Yarova ◽  
Iryna I. Zabolotna ◽  
Olena S. Genzytska ◽  
Andrii A. Komlev

The aim: Is to define dentine chemical composition of intact teeth and those with wedge-shaped defects followed by the analysis of revealed differences. Materials and methods: Longitudinal sections of 22 clinically removed teeth (12 – clinically intact ones, 10 – with wedge-shaped defects) from both jaws were studied in patients aged between 25-54 years. JSM-6490 LV focused beam electron microscope (scanning) with system of energy-dispersive X-ray microanalysis INCA Penta FETх3 was used. The chemical composition of 148 dentine areas in the incisal region (tubercle), equator, cervical area has been determined as a percentage of the weight amounts of carbon, oxygen, calcium, phosphorus, sodium, magnesium, sulfur, chlorine, zinc, potassium, aluminum. Results: Dentine chemical composition of teeth with wedge-shaped defects differed from those of intact teeth by significantly lower content: sodium, chlorine and calcium – in the incisal region (tubercle); sodium, magnesium − at the equator; sodium, chlorine and calcium – in the cervical region (p≤0.05). In the sample groups with cervical pathology there was more sulfur and oxygen in the incisal region (tubercle), phosphorus and zinc – at the equator, carbon and potassium – in the cervical region (p≤0.05). Conclusions: Differences in the chemical composition of intact teeth and teeth with wedge-shaped defects, the presence of correlation between the studied chemical elements confirm the role of macro- and microelements in the pathogenesis of non-carious cervical lesions.


2018 ◽  
Vol 2018 ◽  
pp. 1-16 ◽  
Author(s):  
Zhigang Yuan ◽  
Yaohua Shao

The mechanism of how hydraulic fracturing influences gas drainage in coal-rock mass is still not clear due to its complex mechanism. In this work, statistical distributions are firstly introduced to describe heterogeneity of coal-rock mass; a novel simultaneously coupled mathematical model, which can describe the fully coupled process including seepage-damage coupling during hydraulic fracturing process and subsequent gas flow during gas drainage process, is established; its numerical implementation procedure is coded into a Matlab program to calculate the damage variables, and it partly uses COMSOL solver to obtain numerical solutions of governing equations with damage-flow coupling; the mathematical model and its implementation are validated for initial damage pressure and mode of a single solid model without considering flow-damage coupling, as well as fracture initiation pressure and influence of heterogeneity on damage evolution of hydraulic fracturing considering flow-damage coupling; and finally, based on an engineering practice of hydraulic fracturing with two boreholes, the mechanism of how hydraulic fracturing influences gas drainage is investigated, numerical simulation results indicate that coal-rock mass pore-fissure structure has been improved, and there would exist a gas migration channel with characteristics of higher porosity and lower stresses, which demonstrates significant effects and mechanism of hydraulic fracturing on improving coal-rock permeability and enhancing gas drainage. The research results provide a guide for operation of hydraulic fracturing and optimal layout of gas drainage boreholes.


Fuel ◽  
2020 ◽  
Vol 264 ◽  
pp. 116906 ◽  
Author(s):  
Xie Jingna ◽  
Xie Jun ◽  
Ni Guanhua ◽  
Sheik Rahman ◽  
Sun Qian ◽  
...  

2010 ◽  
Vol 24 (15n16) ◽  
pp. 3263-3268
Author(s):  
DOND GAO ◽  
FANWEI ZHANG ◽  
YUE ZHANG ◽  
YANG SONG ◽  
XIAOBIN SHI

Amorphous materials of the Si -( B )- C - N system have recently attracted considerable interest because of its hardness, low density, durability at extremely high temperature and easy to be prepared from precursor compounds by polymer route. The materials show a great potential to be used in the field of the Thermal Protective System (TPS) for the aircrafts, while the microstructure and chemical configuration are still not clearly revealed due to its complicated covalent character for this multi-component amorphous material. This paper focused on the characterization of polymer derived Si -( B )- C - N amorphous ceramic, various method were employed in order to obtain accurate information about the microstructure, chemical composition, bonding mode of components, such as TEM, EPMA, NMR and FT-IR. SiC crystalline was found existing in the amorphous glass, which indicates the preparation process was achieved accompanied by crystallization of SiC from polymer precursor. The microstructure of the researched material was analyzed and relative accurate chemical composition was obtained on the basis of characterization result, furthermore the covalent character of the amorphous material was deduced according to the characterization results obtained.


2020 ◽  
Author(s):  
Hsiao-Yuan Tammy Hsu ◽  
Fred Worrall ◽  
Andy Aplin

<p>     The potential development of shale gas has brought with it several concerns about environmental impacts, these include: induced seismicity, air pollution, and groundwater contamination. During hydraulic fracturing for shale gas, large volumes of oxic and acidic water are injected into the gas-bearing formations. The injected fluids contain a range of additives and will mix and react with the in-situ groundwater and shale rock with the potential to drive water-rock interactions; release metal contaminants; alter the permeability of the bedrock; with each of these affecting the transport and recovery of water, hydrocarbons, and contamination. The purpose of this study is to understand the geochemical processes and inorganic metals release during hydraulic fracturing to assess the potential contribution of fluid-rock interaction for the composition of produced waters and alteration of shale mechanical properties.<br>     The study has: <br>i) Statistically analysed the chemical composition of hydraulic fracturing in USGS dataset to create prior distributions for the prediction of the salinity and chemical composition of flowback fluids in the UK. <br>ii) Statistically analysed the composition and controls on geothermal waters in the UK. Deep geothermal waters are an analogue for the in-situ groundwater composition with which injected fracking fluids will react and mix.<br>iii) Both sources of information have assisted in the design of the high pressure, high temperature experiments that will simulate the fracking fluid processes<br>iv) Undertaken sequential extraction of target shales to understand the data from existing batch experiments undertaker</p><p>     Future work will include isotope proxy and mineralogical texture studies to predict flowback fluid composition and the post-frack condition of the shale.</p>


1980 ◽  
Vol 20 (06) ◽  
pp. 487-500 ◽  
Author(s):  
A. Settari

Abstract A mathematical model of the fracturing process, coupling the fracture mechanics and fracture propagation with reservoir flow and heat transfer, has been formulated. The model is applicable to fracturing treatments as well as to high leakoff applications such as fractured waterfloods and thermal fractures. The numerical technique developed is capable of simulating fracture extension for reasonably coarse grids, with truncation error being minimized for high leakoff applications when the grid next to the fracture is approximately square. With the aid of the model, a generalization of Carter's propagation formula has been developed that is also valid for high fluid-loss conditions. The capabilities of the model are illustrated by examples of heat transfer and massive-hydraulic-fracturing (MHF) treatment calculation. Introduction Induced fracturing of reservoir rock occurs under many different circumstances. Controlled hydraulic fracturing is an established method for increasing productivity of wells in low-permeability reservoirs. The technology of fracturing and the earlier design methods are reviewed by Howard and Fast.1 In waterflooding, injection pressures also often exceed fracturing pressures. This may result from poor operational practices, but it also could be intended to increase injectivity.2 In heavy oils, such as Alberta oil sands, most in-situ thermal recovery techniques rely on creating injectivity by fracturing the formation with steam.3 Fracturing also is being used as a method for deterining in-situ stresses4 and for establishing communication between wells for extraction of geothermal energy.5,6 Finally, fractures may be produced by explosive treatment or induced thermal stresses (such as in radioactive waste disposal). To date, most of the research has been directed toward the understanding and design of fracture stimulation treatments, with emphasis on predicting fracture geometry.7–11 The influence of fluid flow and heat transfer in the reservoir has been neglected or accounted for by various approximations in these methods. On the other hand, the need for reservoir engineering analysis of fractured wells led to the development of analytical techniques and numerical models for predicting postfracture performance.1 A common feature of all these methods is that they treat only stationary fractures, which therefore must be computed using some of the methods of the first category mentioned earlier. With the high costs associated with MHF,17–19 and with increasing complexity of the treatments, it is becoming important to be able to understand the interaction of the physical mechanisms involved and to improve the designs. This paper presents a numerical model of the fracturing process that simultaneously accounts for the rock mechanics, two-phase fluid flow, and heat transfer, both in the fracture and in the reservoir. The model is capable of predicting fracture propagation, fluid leakoff and heat transfer, fracture closure, cleanup, and postfracture performance. Although the detailed calculations of geometry, proppant transport, etc., have not been included, they can be integrated in a natural way within the present model. Because vertical fractures are prevalent except for very shallow depths, the discussion is limited to vertical fracturing. The paper focuses attention on the formulation of the basic model and the numerical techniques in general. Applications to fracturing treatments and the specific enhancements of the model are described in a more recent paper.20


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