Extraction of Cellulose Nanocrystals with Structure I and II and Their Applications for Reduction of Graphene Oxide and Nanocomposite Elaboration

2018 ◽  
Vol 10 (7) ◽  
pp. 1913-1927 ◽  
Author(s):  
Faouzia Khili ◽  
Joao Borges ◽  
Pedro L. Almeida ◽  
Rabah Boukherroub ◽  
Amel Dakhlaoui Omrani
Author(s):  
kexia Jin ◽  
Jianxiong Xing ◽  
Xinge Liu ◽  
Zehui Jiang ◽  
Shumin Yang ◽  
...  

To achieve high mechanical strength electromagnetic interference (EMI) shielding materials for practical application, cellulose nanocrystals (CNC) as a reinforcing and dispersing agent, are intercalated into reduced graphene oxide (RGO) layers,...


2020 ◽  
Vol 7 (10) ◽  
pp. 200857 ◽  
Author(s):  
Junhong Tao ◽  
Jie Yang ◽  
Chengxiao Ma ◽  
Junfeng Li ◽  
Keqing Du ◽  
...  

Residual antibiotics in water are often persistent organic pollutants. The purpose of this study was to prepare a cellulose nanocrystals/graphene oxide composite (CNCs-GO) with a three-dimensional structure for the removal of the antibiotic levofloxacin hydrochloride (Levo-HCl) in water by adsorption. The scanning electron microscope, Fourier transform infrared (FT-IR), energy-dispersive spectroscopy, X-ray photoelectron spectroscopy and other characterization methods were used to study the physical structure and chemical properties of the CNCs-GO. The three-dimensional structure of the composite material rendered a high surface area and electrostatic attraction, resulting in increased adsorption capacity of the CNCs-GO for Levo-HCl. Based on the Box–Behnken design, the effects of different factors on the removal of Levo-HCl by the CNCs-GO were explored. The composite material exhibited good antibiotic adsorption capacity, with a removal percentage exceeding 80.1% at an optimal pH of 4, the adsorbent dosage of 1.0 g l −1 , initial pollutant concentration of 10.0 mg l −1 and contact time of 4 h. The adsorption isotherm was well fitted by the Sips model, and kinetics studies demonstrated that the adsorption process conformed to a quasi-second-order kinetics model. Consequently, the as-synthesized CNCs-GO demonstrates good potential for the effective removal of antibiotics such as levofloxacin hydrochloride from aqueous media.


2021 ◽  
Author(s):  
Xudong Zheng ◽  
Wen Sun ◽  
Ang Li ◽  
Bin Wang ◽  
Rong Jiang ◽  
...  

Abstract Because of dysprosium's unique physical and chemical properties and limited supply, the price of rare earth dysprosium has been high in recent years. Therefore, the study of the method of high efficiency selective separation of dysprosium has the double value of scientific research and practical economy. In this paper, we used periodic cellulose nanocrystals as the basic structure, polyethylenimine and graphene oxide were introduced, combined with imprinting technology, to construct porous imprinted aerogel and use it for selective adsorption of Dy(III). The physical and chemical properties were characterized by SEM, TEM, FT-IR and TGA. It was proved that both polyethylenimine and graphene oxide were crosslinked effectively with cellulose nanocrystals. Adsorption experiments showed that the composite imprinted aerogel could selectively adsorb dysprosium effectively, and the maximum adsorption capacity for Dy(III) was 36.495 mg g− 1. The reproducibility experiment showed that aerogel had good regeneration ability. In conclusion, cellulose nanocrystals aerogel, which is environmentally friendly, efficient and repeatable, is expected to provide a new direction for the recovery of rare earth elements.


RSC Advances ◽  
2019 ◽  
Vol 9 (62) ◽  
pp. 36040-36049 ◽  
Author(s):  
Dinesh K. Patel ◽  
Yu-Ri Seo ◽  
Sayan Deb Dutta ◽  
Ki-Taek Lim

Cellulose nanocrystals (CNCs) have received a great amount of attention to the production of micro/nano-platforms for tissue engineering applications.


2021 ◽  
Author(s):  
Xudong Zheng ◽  
Wen Sun ◽  
Ang Li ◽  
Bin Wang ◽  
Rong Jiang ◽  
...  

Abstract Because of dysprosium's unique physical and chemical properties and limited supply, the price of rare earth dysprosium has been high in recent years. Therefore, the study of the method of high efficiency selective separation of dysprosium has the double value of scientific research and practical economy. In this paper, we used periodic cellulose nanocrystals as the basic structure, polyethylenimine and graphene oxide were introduced, combined with imprinting technology, to construct porous imprinted aerogel and use it for selective adsorption of Dy(III). The physical and chemical properties were characterized by SEM, TEM, FT-IR and TGA. It was proved that both polyethylenimine and graphene oxide were crosslinked effectively with cellulose nanocrystals. Adsorption experiments showed that the composite imprinted aerogel could selectively adsorb dysprosium effectively, and the maximum adsorption capacity for Dy(III) was 39.027 mg g− 1. The reproducibility experiment showed that aerogel had good regeneration ability. In conclusion, cellulose nanocrystals aerogel, which is environmentally friendly, efficient and repeatable, is expected to provide a new direction for the recovery of rare earth elements.


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