scholarly journals Post-illumination activity of Bi2WO6 in the dark from the photocatalytic “memory” effect

2021 ◽  
Vol 10 (2) ◽  
pp. 355-367
Author(s):  
Weiyi Yang ◽  
Yan Chen ◽  
Shuang Gao ◽  
Licheng Sang ◽  
Ruoge Tao ◽  
...  

AbstractPhotocatalysts with the photocatalytic “memory” effect could resolve the intrinsic activity loss of traditional photocatalysts when the light illumination is turned off. Due to the dual requirements of light absorption and energy storage/release functions, most previously reported photocatalysts with the photocatalytic “memory” effect were composite photocatalysts of two phase components, which may lose their performance due to gradually deteriorated interface conditions during their applications. In this work, a simple solvothermal process was developed to synthesize Bi2WO6 microspheres constructed by aggregated nanoflakes. The pure phase Bi2WO6 was found to possess the photocatalytic “memory” effect through the trapping and release of photogenerated electrons by the reversible chemical state change of W component in the (WO4)2− layers. When the illumination was switched off, Bi2WO6 microspheres continuously produced H2O2 in the dark as those trapped photogenerated electrons were gradually released to react with O2 through the two-electron O2 reduction process, resulting in the continuous disinfection of Escherichia coli bacteria in the dark through the photocatalytic “memory” effect. No deterioration of their cycling H2O2 production performance in the dark was observed, which verified their stable photocatalytic “memory” effect.

2021 ◽  
pp. 1-23
Author(s):  
Daniel O'Reilly ◽  
Manouchehr Haghighi ◽  
Mohammad Sayyafzadeh ◽  
Matthew Flett

Summary An approach to the analysis of production data from waterflooded oil fields is proposed in this paper. The method builds on the established techniques of rate-transient analysis (RTA) and extends the analysis period to include the transient- and steady-state effects caused by a water-injection well. This includes the initial rate transient during primary production, the depletion period of boundary-dominated flow (BDF), a transient period after injection starts and diffuses across the reservoir, and the steady-state production that follows. RTA will be applied to immiscible displacement using a graph that can be used to ascertain reservoir properties and evaluate performance aspects of the waterflood. The developed solutions can also be used for accurate and rapid forecasting of all production transience and boundary-dominated behavior at all stages of field life. Rigorous solutions are derived for the transient unit mobility displacement of a reservoir fluid, and for both constant-rate-injection and constant-pressure-injection after a period of reservoir depletion. A simple treatment of two-phase flow is given to extend this to the water/oil-displacement problem. The solutions are analytical and are validated using reservoir simulation and applied to field cases. Individual wells or total fields can be studied with this technique; several examples of both will be given. Practical cases are given for use of the new theory. The equations can be applied to production-data interpretation, production forecasting, injection-water allocation, and for the diagnosis of waterflood-performanceproblems. Correction Note: The y-axis of Fig. 8d was corrected to "Dimensionless Decline Rate Integral, qDdi". No other content was changed.


1992 ◽  
Vol 3 (2) ◽  
pp. 181-191
Author(s):  
A. M. Meirmanov ◽  
N. V. Shemetov

In this paper we investigate the mathematical model of the equilibrium of a finite volume in ℝn (n = 1,2, 3) of a two-phase continuous medium, under the assumption that each pure phase is an isotropic elastic solid. The main results in this paper are:(i) the existence and uniqueness of a solution of this mathematical model;(ii) a discussion of the stress-strain law associated with the free energy of this two-phase continuous medium, which is multiple-valued due to the non-smoothness of the Gibbs potential (complementary energy);(iii) a description of the structure of solutions in plane strain.


2013 ◽  
Vol 734-737 ◽  
pp. 1488-1492
Author(s):  
Zhen Yu Liu ◽  
Li Hong Yao ◽  
Hu Zhen Wang ◽  
Cui Cui Ye

The fractures after artificial steering fracturing appear in shades of curved surface. Aiming at the problem of steering fracture, in the paper, numerical simulation method under the condition of three-dimensional two-phase flow is presented based on finite element method. In this method, of steering fracture was achieved by adopting surface elements fractures and tetrahedron elements to describe formation. By numerical simulation, the change rule of oil and water production performance of steering fractures can be calculated, and then the steering fracture parameters can be optimized before fracturing. A new method was supplied for the numerical simulation of artificial fractured well.


SPE Journal ◽  
2018 ◽  
Vol 24 (02) ◽  
pp. 681-697 ◽  
Author(s):  
Zheng Sun ◽  
Juntai Shi ◽  
Keliu Wu ◽  
Tao Zhang ◽  
Dong Feng ◽  
...  

Summary Low-permeability coalbed-methane (CBM) reservoirs possess unique pressure-propagation behavior, which can be classified further as the expansion characteristics of the drainage area and the desorption area [i.e., a formation in which the pressure is lower than the initial formation pressure and critical-desorption pressure (CDP), respectively]. Inevitably, several fluid-flow mechanisms will coexist in realistic coal seams at a certain production time, which is closely related to dynamic pressure and saturation distribution. To the best of our knowledge, a production-prediction model for CBM wells considering pressure-propagation behavior is still lacking. The objective of this work is to perform extensive investigations into the effect of pressure-propagation behavior on the gas-production performance of CBM wells. First, the pressure-squared approach is used to describe the pressure profile in the desorption area, which has been clarified as an effective-approximation method. Also, the pressure/saturation relationship that was developed in our previous research is used; therefore, saturation distribution can be obtained. Second, an efficient iteration algorithm is established to predict gas-production performance by combining a new gas-phase-productivity equation and a material-balance equation. Finally, using the proposed prediction model, we shed light on the optimization method for production strategy regarding the entire production life of CBM wells. Results show that the decrease rate of bottomhole pressure (BHP) should be slow at the water single-phase-flow stage, fast at the early gas/water two-phase-flow stage, and slow at the late gas/water two-phase-flow stage, which is referred to as the slow/fast/slow (SFS) control method. Remarkably, in the SFS control method, the decrease rate of the BHP at each period can be quantified on the basis of the proposed prediction model. To examine the applicability of the proposed SFS method, it is applied to an actual CBM well in Hancheng Field, China, and it enhances the cumulative gas production by a factor of approximately 1.65.


2014 ◽  
Vol 884-885 ◽  
pp. 104-107
Author(s):  
Zhi Jun Li ◽  
Ji Qiang Li ◽  
Wen De Yan

For the water-sweeping gas reservoir, especially when the water-body is active, water invasion can play positive roles in maintaining formation pressure and keeping the gas well production. But when the water-cone break through and towards the well bottom, suffers from the influencing of gas-water two phase flows, permeability of gas phase decrease sharply and will have a serious impact on the production performance of the gas well. Moreover, the time when the water-cone breakthrough will directly affect the final recovery of the gas wells, therefore, the numerical simulation method is used to conduct the research on the key influencing factors of water-invasion performance for the gas wells with bottom-water, which is the basis of the mechanical model for the typical gas wells with bottom-water. It indicate that as followings: (1) the key influencing factors of water-invasion performance for the gas wells with bottom-water are those, such as the open degree of the gas beds, well gas production and the amount of Kv/Kh value; and (2) the barrier will be in charge of great significance on the water-controlling for the bottom water gas wells, and its radius is the key factor to affect water-invasion performance for the bottom water gas wells where the barriers exist nearby.


2010 ◽  
Vol 654-656 ◽  
pp. 2150-2153 ◽  
Author(s):  
Hideki Hosoda ◽  
Makoto Taniguchi ◽  
Tomonari Inamura ◽  
Hiroyasu Kanetaka ◽  
Shuichi Miyazaki

Effects of single- and multi-step aging on mechanical properties and shape memory properties of Ti-6Mo-8Al (mol%) biomedical shape memory alloy were studied using tensile tests at room temperature (RT). The solution-treated alloy at RT was two phase of bcc β and martensite α". Tensile tests revealed that the solution-treated alloy exhibited good shape memory effect. As for the single-step aging, (1) pseudoelastic shape recovery by unloading was observed after aging at 623K, (2) the alloy became brittle after aging at 773K due to ω embrittlement, and (3) strength was improved with small shape memory effect by aging at 1023K. On the other hand, after a multistep aging at 773K-1023K-1123K, the alloy was strengthened and showed perfect shape recovery. The improvement must be achieved by the formation of fine and uniform hcp α precipitates.


Author(s):  
A. A´lvarez del Castillo ◽  
E. Santoyo ◽  
O. Garci´a-Valladares ◽  
P. Sa´nchez-Upton

The modeling of heat and fluid flow inside two-phase geothermal wells is a vital task required for the study of the production performance. Gas void fraction is one of the crucial parameters required for a better prediction of pressure and temperature gradients in two-phase geothermal wells. This parameter affects the correct matching between simulated and measured data. Modeling of two-phase flow inside wells is complex because two phases exist concurrently (exhibiting various flow patterns that depend on their relative concentrations, the pipe geometry, and the mass flowrate). A reliable modeling requires the precise knowledge of the two-phase flow patterns (including their transitions and some flow parameters). In this work, ten empirical correlations were used to estimate the gas void fraction in vertical-inclined pipes, and to evaluate their effect on the prediction of two-phase flow characteristics of some Mexican geothermal wells. High quality downhole pressure/ temperature logs collected from four producing geothermal wells were studied [Los Azufres, Mich. (Az-18); Los Humeros, Pue. (H-1), and Cerro Prieto, B.C. (M-90 and M-201)]. The pressure/ temperature gradients were simulated using an improved version of the wellbore simulator GEOPOZO, and the gas void fraction correlations. The simulated results were statistically compared with measured field data.


Lithosphere ◽  
2021 ◽  
Vol 2021 (Special 4) ◽  
Author(s):  
Suran Wang ◽  
Yuhu Bai ◽  
Bingxiang Xu ◽  
Yanzun Li ◽  
Ling Chen ◽  
...  

Abstract Two-phase (gas+water) flow is quite common in tight sandstone gas reservoirs during flowback and early-time production periods. However, many analytical models are restricted to single-phase flow problems and three-dimensional fracture characteristics are seldom considered. Numerical simulations are good choices for this problem, but it is time consuming in gridding and simulating. This paper presents a comprehensive hybrid model to characterize two-phase flow behaviour and predict the production performance of a fractured tight gas well with a three-dimensional discrete fracture. In this approach, the hydraulic fracture is discretized into several panels and the transient flow equation is solved by the finite difference method numerically. A three-dimensional volumetric source function and superposition principle are deployed to capture the flow behaviour in the reservoir analytically. The transient responses are obtained by coupling the flow in the reservoir and three-dimensional discrete fracture dynamically. The accuracy and practicability of the proposed model are validated by the numerical simulation result. The results indicate that the proposed model is highly efficient and precise in simulating the gas/water two-phase flow and evaluating the early-time production performance of fractured tight sandstone gas wells considering a three-dimensional discrete fracture. The results also show that the gas production rate will be overestimated without considering the two-phase flow in the hydraulic fracture. In addition, the influences of fracture permeability, fracture half-length, and matrix permeability on production performance are significant. The gas production rate will be higher with larger fracture permeability at the early production period, but the production curves will merge after fracturing fluid flows back. A larger fracture half-length and matrix permeability can enhance the gas production rate.


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