A preliminary study on the alkali activation of ground granulated blast-furnace slag

1990 ◽  
Vol 20 (5) ◽  
pp. 746-756 ◽  
Author(s):  
E. Douglas ◽  
J. Brandstetr
2016 ◽  
Vol 865 ◽  
pp. 107-113 ◽  
Author(s):  
Pavel Mec ◽  
Jana Boháčová ◽  
Josef Koňařík

Alkali activated systems are materials formed by alkali-activation of latent hydraulic or pozzolanic materials. The outcome is a polymeric structure with properties comparable to materials based on cement.The principle of the experiment is to compare selected properties of alkali-activated materials based on blast furnace slag and using various types of activator (sodium water glass, potassium water glass, DESIL AL and sodium metasilicate) to binders based on white and Portland cements of the highest quality. The samples were left for one year in environments simulating the conditions in the interior and exterior. Selected physical-mechanical properties were evaluated and compared.


2003 ◽  
Vol 18 (11) ◽  
pp. 2571-2579 ◽  
Author(s):  
I. Lecomte ◽  
M. Liégeois ◽  
A. Rulmont ◽  
R. Cloots ◽  
F. Maseri

Alkali activation of dehydroxylated kaolin or clay yielded high-strength polymeric materials, so-called geopolymers. They were synthesized by mixing the aluminosilicate with solutions of sodium metasilicate and KOH followed by adding 45 wt.% of ground-granulated blast furnace slag. The influence of the aluminosilicate source, its activation temperature, and the order of mixing raw materials were studied on the workability of the blending paste, the microstructure, and the Vickers hardness of the geopolymer samples. The polymeric material is completely amorphous according to x-ray diffraction. Solid-state 27Al and 29Si magic-angle-spinning nuclear magnetic resonance showed that the geopolymer consists of AlO4 and SiO4 tetrahedra linked together through a polymeric network constituted by branched entities SiQ4(4Al) and SiQ4(3Al), but also by less-polymerized silicates SiQ1 and SiQ2. Scanning electron microscopy showed a homogeneous polymeric gel matrix containing unreacted slag (and quartz) grains; thermogravimetric analysis and differential scanning calorimetry exhibited a high content of water and an elevated melting point (1260°C). Vickers hardness values are in the range of 200 MPa.


2011 ◽  
Vol 287-290 ◽  
pp. 1275-1279
Author(s):  
Yong Jia He ◽  
Lin Nu Lu ◽  
Shu Guang Hu

Compound binding material was prepared by the alkali activation of metakaolin and ground granulated blast furnace slag. Hydration product components, microstructure and mechanical properties of the hardened paste were investigated by IR, XRD, SEM, MIP, and compressive strength measurement. Results indicated that hydration products included C-S-H and geopolymer, and both of them were amorphous although there were differences in their structure and morphology. When the dosage of slag was less than 50%, the compressive strength of hardened paste increased as the dosage increased, which was mainly because C-S-H produced by the reaction of GGBFS and alkali filled void in geopolymer phase, and part of unreacted slag particles acting as microaggregate to prevent from extension of microcrack in the hardened paste, so the porosity of hardened paste decreased and compressive strength increased.


2018 ◽  
Vol 20 (2) ◽  
pp. 208-215

The paper presents a laboratory study of concrete mixes based on the alkali-activation of an industrial by-product, ground granulated blast furnace slag (GGBS). A number of factors potentially affecting the resulting concrete quality in terms of workability and strengths were investigated (namely activator type, molarity, curing conditions and times). The statistical significance of the effect of these factors was supported by ANOVA. Higher workability and strengths (with lower activator concentrations) were obtained for KOH containing mixes. Curing at constant moisture and ambient temperature was successful for most alkaline activators and mixes, which showed good concrete strengths at all curing times; when Na2SiO3 was used in addition to NaOH or KOH activators of moderate to high molarity, strengths exceeded those of Ordinary Portland Cement (CEM-I) concrete of a similar water/cement ratio.


2016 ◽  
Vol 249 ◽  
pp. 3-7 ◽  
Author(s):  
Vlastimil Bílek ◽  
Jan Hurta ◽  
Petra Done ◽  
Libor Zidek ◽  
Tomas Zajdlik

Hybrid cements represent a relatively new type of binders which combine some of the advantages of Ordinary Portland Cement (OPC), the application of mineral admixtures and alkali activation. Hybrid cements represent blends containing a low portion of OPC and a high proportion of mineral additions (such as blast furnace slag, fly ash, metakaolin ....). The paper is focused on the study of properties of mortars prepared from hybrid cements. Mortars with hybrid cements were prepared for an evaluation of the effects of the dosage and the composition of alkali activator, the dosage of OPC and the ratio between ground granulated blast furnace slag and fly ash. The results make it possible to optimize the composition of hybrid alkali activated concretes.


2017 ◽  
Vol 68 (6) ◽  
pp. 1182-1187
Author(s):  
Ilenuta Severin ◽  
Maria Vlad

This article presents the influence of the properties of the materials in the geopolymeric mixture, ground granulated blast furnace slag (GGBFS) + wheat straw ash (WSA) + uncalcined red mud (RMu), and ground granulated blast furnace slag + wheat straw ash + calcined red mud (RMc), over the microstructure and mechanical properties of the synthesised geopolymers. The activation solutions used were a NaOH solution with 8M concentration, and a solution realised from 50%wt NaOH and 50%wt Na2SiO3. The samples were analysed: from the microstructural point of view through SEM microscopy; the chemical composition was determined through EDX analysis; and the compressive strength tests was done for samples tested at 7 and 28 days, respectively. The SEM micrographies of the geopolymers have highlighted a complex structure and an variable compressive strength. Compressive strength varied from 24 MPa in the case of the same recipe obtained from 70% of GGBFS + 25% WSA +5% RMu, alkaline activated with NaOH 8M (7 days testing) to 85 MPa in the case of the recipe but replacing RMu with RMc with calcined red mud, alkaline activated with the 50%wt NaOH and 50%wt Na2SiO3 solution (28 days testing). This variation in the sense of the rise in compressive strength can be attributed to the difference in reactivity of the materials used in the recipes, the curing period, the geopolymers structure, and the presence of a lower or higher rate of pores, as well as the alkalinity and the nature of the activation solutions used.


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 382 ◽  
Author(s):  
Danying Gao ◽  
Zhenqing Zhang ◽  
Yang Meng ◽  
Jiyu Tang ◽  
Lin Yang

This work aims to investigate the effect of additional flue gas desulfurization gypsum (FGDG) on the properties of calcium sulfoaluminate cement (CSAC) blended with ground granulated blast furnace slag (GGBFS). The hydration rate, setting time, mechanical strength, pore structure and hydration products of the CSAC-GGBFS mixture containing FGDG were investigated systematically. The results show that the addition of FGDG promotes the hydration of the CSAC-GGBFS mixture and improves its mechanical strength; however, the FGDG content should not exceed 6%.


Sign in / Sign up

Export Citation Format

Share Document