The effect of γ-mercaptopropyltrimethoxysilane coupling agent on t90, tensile strength and tear strength of silica-filled ENR vulcanisates

1989 ◽  
Vol 25 (3) ◽  
pp. 267-273 ◽  
Author(s):  
M. Nasir ◽  
B.T. Poh ◽  
P.S. Ng
Keyword(s):  
Tensile Strength ◽  
Coupling Agent ◽  
Tear Strength

Effect of Oyster Shell Powder Loading on the Mechanical and Thermal Properties of Natural Rubber/Oyster Shell Composites

2017 ◽  
Vol 25 (1) ◽  
pp. 17-22 ◽  
Author(s):  
Lefan Li ◽  
Zongqiang Zeng ◽  
Zhifen Wang ◽  
Zheng Peng ◽  
Xiaodong She ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Coupling Agent ◽  
Oyster Shell ◽  
Absorption Bands ◽  
Tear Strength ◽  
Oyster Shell Powder ◽  
Shell Powder

The oyster shell powder/natural rubber composites were successfully prepared by blending the modified oyster shell powder with natural rubber (NR). The oyster shell powder with a particle size of 209 nm were well distributed within the rubber matrix. The characteristic Fourier transform infrared spectroscopy (FTIR) absorption bands of both oyster shell powder and natural rubber were observed in the FTIR spectra of NR/oyster shell powder composites. The C-O absorption bands in carbonates of composites exhibit a shift from 1425 cm−1 to 1446 cm−1 which suggests the bonds formed among oyster shell powder, earth coupling agent and NR. The tensile strength and stress at 500% elongation increased with rising of the earth coupling agent. Composites with 1.5 parts per hundred rubber (phr) coupling agent achieved the highest mechanical properties, where an increase of 13.4% in tensile strength was found. The tensile strength and tear strength increased along with an increment of oyster shell powder. When the content of oyster shell powder attained 25–30 phr, the composites exhibited the best mechanical properties. In particular, the tensile strength and tear strength increased by 27.9% and 17.2% when compared with those of the control samples. Furthermore, the addition of the oyster shell powder leads to the improvement of thermal stability which is evidenced by an increase of 8 °C in the initial degradation temperature. The improvement of the mechanical properties and thermal stability of the composites have demonstrated that the oyster shell powder can be used as potential fillers for natural rubber.

scholarly journals Utilization of Leather Waste Fibers in Polymer Matrix Composites Based on Acrylonitrile-Butadiene Rubber

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 117
Author(s):  
Le Thuy Hang ◽  
Do Quoc Viet ◽  
Nguyen Pham Duy Linh ◽  
Vu Anh Doan ◽  
Hai-Linh Thi Dang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polymer Matrix Composites ◽  
Waste Product ◽  
Dynamic Mechanical Properties ◽  
Hammer Mill ◽  
Butadiene Rubber ◽  
Matrix Composites ◽  
Leather Industry ◽  
Tear Strength

In this study, we present the fabrication of nitrile butadiene rubber/waste leather fiber (NBR/WLF) composites with different weight percentages of WLF and NBR (0/100, 20/80, 30/70, 40/60, 50/50, 60/40 wt/wt). WLF was prepared by cutting the scrap leathers from the waste product of the Vietnamese leather industry. Subsequently, in order to make the short fibers, it was mixed by a hammer mill. The characteristics of WLF/NBR composites such as mechanical properties (tensile strength, tear strength, hardness), dynamic mechanical properties, toluene absorption, and morphology were carefully evaluated. As a result, the tensile strength and tear strength become larger with increasing WLF content from 0 to 50 wt% and they decrease when further increasing WLF content. The highest tensile strength of 12.5 MPa and tear strength of 72.47 N/mm were achieved with the WLF/NBR ratio of 50/50 wt%. Both hardness and resistance of the developed materials with toluene increased with increasing WLF content. The SEM results showed a good adhesion of NBR matrix and the WLF. The increasing of storage modulus (E’) in comparison with raw NBR showed good compatibility between WLF and NBR matrix. This research showed that the recycled material from waste leather and NBR was successfully prepared and has great potential for manufacturing products such as floor covering courts and playgrounds, etc.

scholarly journals Evaluation of Maleated Polyethylene in Natural Rubber and Teline monspessulana Flour Composites

2020 ◽  
Author(s):  
Oscar Palacio ◽  
Emilio Delgado
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Coupling Agent ◽  
Tensile Testing ◽  
Process Analysis ◽  
Coupling Reaction ◽  
Molding Process ◽  
Elongation At Break ◽  
Content Determination ◽  
Two Factors

The effect of the addition of maleated polyethylene (MAPE) to compounds of natural rubber (NR) and Teline monspessulana flour (TMF) previously mercerized was investigated. Two factors were analyzed: A. concentration of MAPE with five levels 2; 4; 6; 8; 10 phr (parts per hundred rubber), B. concentration of TMF with two levels 25 and 40 phr. The effect of MAPE on compatibility between NR and HTM was evaluated by tensile testing the compounds. The mixing was performed in a laboratory scale mill. The test tubes were obtained by cutting or die-cutting crosslinked peroxide sheets, these were obtained during the compression molding process. Analysis indicate that the MAPE coupling agent improved the compatibility between HTM and NR, this effect was evidenced by the values of tensile strength and elongation at break. However, the gel content determination indicates that the addition of 10 phr of MAPE crosslinking decreases due to competition with coupling reaction MAPE - HTM.

APPROACHES TO CONTROLLING MICRO-ORGANISMS IN COTTON AND COTTON/ELASTANE CLOTHINGS

2021 ◽  
Vol 16 (3) ◽  
pp. 124-135
Author(s):  
Nilüfer Yıldız Varan
Keyword(s):  
Mechanical Properties ◽  
Antimicrobial Activity ◽  
Tensile Strength ◽  
Untreated Control ◽  
Physical And Mechanical Properties ◽  
Emergency Rooms ◽  
Tear Strength ◽  
Antifungal Properties ◽  
Micro Organisms ◽  
Control Samples

Antimicrobials are substances or mixtures of substances used to destroy or suppress the growth of harmful microorganisms such as bacteria, viruses, or fungi on inanimate objects and surfaces. In this study, an alternative method is presented using triclosan agents that can kill bacteria and viruses to help keep patient, operating, and emergency rooms free of germs. Samples were treated with triclosan to achieve antimicrobial/antiviral/antifungal properties for further designs to help comfort and bacteria, virus, fungi (BVF) resistantance during use. The physical, and mechanical properties of triclosan treated cotton and cotton/elastane fabrics in comparison with untreated control samples was investigated. The results showed that a small significant decrease was observed for tensile strength (strip and grab methods), tear strength and seam strength. Besides, statistically a small significant decrease was observed with the increase in triclosan concentration for all samples. The panama weaves showed the lowest tensile strength and the highest tear strength and statistically small significant decrease was observed for all treated samples. The antimicrobial tests showed that all treated samples have a very good antimicrobial activity which can also lead to antivirus protection by providing hygienic environment for the users during future designs.

Effect of abrasive particle size on tribological behavior of elastomers

2019 ◽  
Vol 234 (3) ◽  
pp. 373-385 ◽  
Author(s):  
F Hakami ◽  
A Pramanik ◽  
AK Basak ◽  
N Ridgway ◽  
MN Islam
Keyword(s):  
Particle Size ◽  
Tensile Strength ◽  
Wear Rate ◽  
Coefficient Of Friction ◽  
Abrasive Particle ◽  
Tribological Behaviour ◽  
Elongation At Break ◽  
Tear Strength ◽  
Wear And Friction ◽  
Abrasive Size

Effect of abrasive particle size on tribological behaviour of different elastomers was investigated experimentally in this study. The size of abrasive particle size was varied from coarse (425 µm) to fine (82 µm). Wear rate and coefficient of friction were calculated and analyzed accordingly followed by the examination of worn surfaces by a scanning electron microscope to unravel the wear mechanism. Experimental results showed that abrasive size had a significant effect on wear and friction behaviour of the elastomers. As the abrasive particle size increased, wear rate and coefficient of friction also increased at different rates and exhibited different wear mechanisms that changed from friction to fatigue and roll formation. Mechanical properties of elastomers such as hardness, tensile strength, tear strength, and elongation at break also contributed to wear and friction. The effect of elongation at break and tensile strength on wear rate is more pronounced at lower abrasive particle size, whereas hardness and tear strength play a pivotal role at the higher abrasive size.

scholarly journals PENGARUH PERBEDAAN BAHAN PENYAMAK TERHADAP KUALITAS KULIT IKAN PARI MONDOL (Himantura gerrardi) TERSAMAK The Effect of Different Tanning Materials towards Leather Quality of Tanned Mondol Stingray (Himantura gerrardi)

2016 ◽  
Vol 11 (2) ◽  
pp. 140
Author(s):  
Tika Kusmaryanti ◽  
Ratna Ibrahim ◽  
Putut Har Riyadi
Keyword(s):  
Tensile Strength ◽  
Moisture Content ◽  
Ph Value ◽  
Block Design ◽  
Shrinkage Temperature ◽  
Quality Requirements ◽  
Tear Strength ◽  
Randomized Block Design ◽  
Significant Difference

ABSTRAK   Usaha penyamakan kulit ikan Pari umumnya dilakukan oleh usaha kecil menengah dan hanya menggunakan metode aldehid dengan bahan samak formalin, Selain itu juga belum diketahui kualitas kulit ikan Pari Mondol tersamak yang menggunakan bahan samak krom. Penelitian ini bertujuan untuk mengetahui pengaruh perbedaan penggunaan jenis bahan penyamak terhadap kualitas fisik dan kimiawi kulit ikan Pari Mondol tersamak. Materi penelitian berupa kulit ikan Pari Mondol (Himantura gerrardi) dan bahan samak. Penelitian dilakukan dengan metode eksperimental laboratoris. Rancangan percobaan yang digunakan adalah Rancangan Acak Kelompok dengan perlakuan bahan samak yang berbeda, yaitu formalin, krom, dan kombinasi. Masing-masing perlakuan diulang tiga kali. Variabel mutu yang diamati adalah kekuatan tarik, kemuluran, kekuatan sobek, ketebalan, suhu kerut, ketahanan bengkuk (bengkok), pH dan kadar air. Data dianalisis menggunakan ANOVA dan perbedaan diantara perlakuan diuji dengan Uji Tukey. Hasil penelitian menunjukkan bahwa perbedaan bahan penyamak menyebabkan pengaruh nyata terhadap nilai kekuatan tarik, kekuatan sobek dan ketebalan tetapi tidak memberikan pengaruh nyata terhadap nilai pH, kadar air dan ketahanan bengkuk. Produk yang terbaik yaitu kulit ikan Pari Mondol yang disamak dengan bahan samak kombinasi antara krom dan mimosa, yang sebagian persyaratan mutunya sudah memenuhi persyaratan mutu kulit ikan Pari tersamak menurut SNI 06-6121-1999.   Kata kunci: Kualitas, kulit Ikan Pari, penyamak     ABSTRACT  Meanwhile the quality of Stingray tanned leather which using chrome tannin materials was not yet known. This research aims to determine the effect of different types used tannin materials towards physical and chemical quality of Stingray leather quality. The materials used in this research isStingray (Himantura gerrardi) skin and tannin materials. The study was conducted with laboratory experimental method. The experiments was designed according to the Randomized Block Design with different tanning materials (formalin, chrome, and chrome-combination). Each treatment was done with in triplicate. The quality variables that measured were tensile strength, elongation, tear strength, thickness, shrinkage temperature, bent resistance, pH and moisture content. Data were analyzed using Analysis of Variance. To find the difference between treatments, the data were tested with Honestly Significant Difference Test . The results showed that various of tannin materials gave significant effects to the values of tensile strength, tear strength and thickness however there was not any significant effect on bent resistance, moisture content and pH value. The best product were Stingray tanned leather with chrome-combination tannin material, which partially quality requirements has been comply with Stingray tanned leather quality requirements according to SNI. Keywords: Quality, stingray skin, tanning

scholarly journals PENGARUH PENYAMAKAN ZIRKONIUM TERHADAP UJI KEKUATAN TARIK, UJI KEKUATAN SOBEK, UJI KEMULURAN DAN UJI SUHU KERUT PADA BERBAGAI JENIS KULIT IKAN (The Effect of Zirconium Tanning Against Tensile Strength Test, Strength Test of Tear, Glide Test, and Wrinkle Temperature Test on Different Fish Types)

2018 ◽  
Vol 13 (2) ◽  
pp. 105
Author(s):  
Rokhmah Hergiyani ◽  
Y. S. Darmanto ◽  
Lukita Purnamayati
Keyword(s):  
Tensile Strength ◽  
Negative Impact ◽  
Strength Test ◽  
Collagen Fibers ◽  
Raw Material ◽  
Tear Strength ◽  
Complex Processes ◽  
Materials Used ◽  
The One ◽  
Physical Changes

Kulit ikan merupakan limbah perikanan yang dapat memberikan dampak negatif pada lingkungan. Salah satu cara untuk menanggulangi limbah tersebut adalah dengan proses penyamakan kulit. Penyamakan kulit adalah rangkaian proses yang sangat kompleks terjadi banyak perubahan fisik dan kimia di satu sisi, bagian yang tidak berguna dihilangkan dari kulit mentah untuk mendapatkan serat kolagen murni dan membuka struktur serat kolagen. Proses penyamakan yang tidak baik mengakibatkan kulit menjadi rusak, lemas, dan kebusukan, sehingga penanganannya dapat dengan cara menambah bahan penyamak untuk menguatkan dan menghindari kebusukan. Bahan penyamak yang digunakan yaitu zirconium. Tujuan penelitian ini adalah untuk mengetahui pengaruh penyamakan zirkonium terhadap uji kekuatan tarik, uji kekuatan sobek, uji kemuluran dan uji suhu kerut pada berbagai jenis ikan. Bahan baku yang digunakan adalah kulit ikan nila, kakap dan bandeng. Metode penelitian yang digunakan adalah experimental laboratories menggunakan Rancangan Acak Lengkap (RAL) dengan tiga kali ulangan dan  menggunakan analisa ragam ANOVA. Hasil uji menunjukan penggunaan zirkonium 7,5% terhadap kulit ikan nila, kakap, dan bandeng berpengaruh nyata (p<0,05) pada kekuatan tarik, kekuatan sobek, kemuluran dan suhu kerut pada karakteristik penyamakan. Penggunaan bahan penyamak zirkonium 7,5% terbaik dihasilkan oleh kulit ikan kakap pada uji kekuatan tarik 1675,84 N/cm2, kekuatan sobek 163,92 N/cm2 dan uji suhu kerut 103,45˚C sedangkan kemuluran untuk hasil terbaik pada kulit bandeng sebesar 28,74%, jadi setiap ikan mempunyai ciri kulit tersendiri pada setiap parameter uji. The skin of the fish waste is a fishery that can give a negative impact on the environment. One way of tackling the waste is by the process of tanning leather. Tanning is a very complex processes occur many chemical and physical changes on the one hand, the useless removed from rawhide to get pure collagen fibers and the open structure of the collagen fibers. The process of tanning is not a good result in the skin becomes broken, buckled, and corruption, so that responses can be with how to add ingredients to strengthen Tanner and avoid corruption. On the research of materials used i.e. Tanners used are zirconium.. The purpose of this research is to know the influence of zirconium tanning against test tensile strength, tear strength test, test and test temperature wrinkle elongation on various types of fish. The raw material used is leather fish tilapia, milkfish and snapper. Research methods used are experimental laboratories using Complete Random Design (RAL) with three-time repeats and a range of analysis using ANOVA. Test results showed the use of zirconium 7.5% against the skin of the fish, snapper, tilapia and milkfish influential real (p < 0.05) on the tensile strength, tear strength, elongation and wrinkle on temperature characteristics of tanning. The use of zirconium Tanner 7.5% best produced by skin test on a snapper 1675.84 tensile strength N/cm2, the strength of RIP 163.92 N/cm2 and test the temperature of the wrinkle 103,45 ˚ C while elongation for the best results on the skin of the banding of 28.74%, so each fish has its own skin characteristics on each test parameter.

Mechanochemical Devulcanization of Vulcanized Gum Natural Rubber

2005 ◽  
Vol 21 (3) ◽  
pp. 183-199
Author(s):  
G.K. Jana ◽  
C.K. Das
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Three Dimensional ◽  
Elongation At Break ◽  
Tear Strength ◽  
Vulcanized Rubber ◽  
Dimensional Network ◽  
Polymeric Chains ◽  
Cure Time

De-vulcanization of vulcanized elastomers represents a great challenge because of their three-dimensional network structure. Sulfur-cured gum natural rubbers containing three different sulfur/accelerator ratios were de-vulcanized by thio-acids. The process was carried out at 90 °C for 10 minutes in an open two-roll cracker-cum-mixing mill. Two concentrations of de-vulcanizing agent were tried in order to study the cleavage of the sulfidic bonds. The mechanical properties of the re-vulcanized rubber (like tensile strength, modulus, tear strength and elongation at break) were improved with increasing concentrations of de-vulcanizing agent, because the crosslink density increased. A decrease in scorch time and in optimum cure time and an increase in the state of cure were observed when vulcanized rubber was treated with high amounts of de-vulcanizing agent. The temperature of onset of degradation was also increased with increasing concentration of thio-acid. DMA analysis revealed that the storage modulus increased on re-vulcanization. From IR spectroscopy it was observed that oxidation of the main polymeric chains did not occur at the time of high temperature milling. Over 80% retention of the original mechanical properties (like tensile strength, modulus, tear strength and elongation at break) of the vulcanized natural rubber was achieved by this mechanochemical process.

Effect of Carbon Black Reinforcing Fillers on Mechanical Properties of NBR Materials Used for the Progressing Cavity Pump

2015 ◽  
Vol 750 ◽  
pp. 339-344 ◽  
Author(s):  
Long Pan ◽  
Jin Zhu Tan ◽  
Liu Fei Fan ◽  
Xue Mei Han
Keyword(s):  
Mechanical Properties ◽  
Mechanical Property ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Carbon Black ◽  
Heat Resistance ◽  
Tear Strength ◽  
Resistance Property ◽  
Reinforcing Fillers ◽  
Materials Used

Three kinds of reinforcing fillers (i.e. carbon black N330, carbon black N880 and carbon-white) were used to study effect of the reinforcing fillers on the mechanical properties of NBR materials. The NBR materials with various reinforcing fillers were fabricated, and the mechanical property tests were performed in this work. The results show that the carbon black N330 made the NBR material have better tensile strength, hardness, elongation and compression elastic modulus compared to the carbon black N880 and the carbon-white, while the carbon-white made NBR material have better heat resistance, tear strength and elongation compared to the carbon black N330 and the carbon black N880. In addition, the tensile strength, tear strength, elongation and the heat resistance property of the NBR materials increased significantly with the increase of the carbon-white, but the compression elastic modulus decreased with the increase of the carbon-white.

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