Phase diagram of the BaOCuOY2O3 system and the relationship between composition and superconductivity

1988 ◽  
Vol 138 (1) ◽  
pp. 137-142 ◽  
Author(s):  
G.C. Che ◽  
J.K. Liang ◽  
W. Chen ◽  
Q.S. Yang ◽  
G.H. Chen ◽  
...  
2021 ◽  
Vol 118 (34) ◽  
pp. e2106881118
Author(s):  
Naman K. Gupta ◽  
Christopher McMahon ◽  
Ronny Sutarto ◽  
Tianyu Shi ◽  
Rantong Gong ◽  
...  

During the last decade, translational and rotational symmetry-breaking phases—density wave order and electronic nematicity—have been established as generic and distinct features of many correlated electron systems, including pnictide and cuprate superconductors. However, in cuprates, the relationship between these electronic symmetry-breaking phases and the enigmatic pseudogap phase remains unclear. Here, we employ resonant X-ray scattering in a cuprate high-temperature superconductor La1.6−xNd0.4SrxCuO4 (Nd-LSCO) to navigate the cuprate phase diagram, probing the relationship between electronic nematicity of the Cu 3d orbitals, charge order, and the pseudogap phase as a function of doping. We find evidence for a considerable decrease in electronic nematicity beyond the pseudogap phase, either by raising the temperature through the pseudogap onset temperature T* or increasing doping through the pseudogap critical point, p*. These results establish a clear link between electronic nematicity, the pseudogap, and its associated quantum criticality in overdoped cuprates. Our findings anticipate that electronic nematicity may play a larger role in understanding the cuprate phase diagram than previously recognized, possibly having a crucial role in the phenomenology of the pseudogap phase.


1995 ◽  
Vol 50 (3) ◽  
pp. 417-431 ◽  
Author(s):  
Sinn-Wen Chen ◽  
Cheng-Chia Huang ◽  
Jen-Chwen Lin

1988 ◽  
Vol 135 ◽  
Author(s):  
J. Rouxel

AbstractLow-dimensional solids are known to be among the best host structures to practice intercalation chemistry. Besides geometrical aspects which play an important role but are now quite well understood, this paper emphasizes the relationship between chemical reactivity and the electronic structure of the host. A special attention is paid to the nature of redox centers involved in the intercalation process and to the connection between the phase diagram and the band structure of the host material.


2011 ◽  
Vol 172-174 ◽  
pp. 291-296
Author(s):  
Abdelahad Chbihi ◽  
Xavier Sauvage ◽  
Didier Blavette

The early stages of precipitation of Cr rich precipitates were investigated by Atom Probe Tomography (APT) in a Cu-1Cr-0.1Zr (wt.%). This way, quantitative data were obtained about their size, 3D shape, density, composition and volume fraction. Surprisingly, in the early stage of precipitation, nanoscaled precipitates exhibit various shapes (spherical, plates and ellipsoid) and contain a large amount of Cu (up to 50%), in contradiction with the equilibrium Cu-Cr phase diagram. APT data also show that some impurities (Fe) segregate along Cu/Cr interfaces. A precipitation sequence is proposed and the relationship between mechanical properties and microstructure is discussed.


1999 ◽  
Vol 14 (7) ◽  
pp. 2739-2750 ◽  
Author(s):  
J. Maeda ◽  
Y. Shiohara

The microstructures and the solidification behavior in unidirectionally solidified Y–Ba–Cu–O/Ag (YBCO/Ag) superconducting current leads were investigated. The solidification model of this system was discussed by the Y2Ba1Cu1O5–Ba3Cu5Ox–Ag quasiternary phase diagrams constructed by analysis of the solute compositions in the melt. The diffusion fields and the spacing between silver particles in the YBCO/Ag system were discussed. The relationship between the shapes of entrapped silver particulates, the miscibility gap in the phase diagram, and the wetting behavior at the growth interface in two-dimensional monotectic reactions were also discussed.


ChemInform ◽  
1988 ◽  
Vol 19 (17) ◽  
Author(s):  
G. C. CHE ◽  
J. K. LIANG ◽  
W. CHEN ◽  
Q. S. YANG ◽  
G. H. CHEN ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16824-16831 ◽  
Author(s):  
Kang Yin ◽  
Xianli Su ◽  
Yonggao Yan ◽  
Ctirad Uher ◽  
Xinfeng Tang

The relationship between the temperature and the composition as well as the microstructure of a Sb-doped Mg2Si0.30Sn0.70 solid solution was systematically studied according to the Mg2Si–Mg2Sn pseudo-binary phase diagram.


Author(s):  
Gordon Bell

A model has been designed to predict the phase which forms in water for a non-ionic surfactant, at a given concentration and temperature. The full phase diagram is generated by selecting enough data points to cover the region of interest. The model estimates the probability for each one of 10 possible phases and selects the one with the highest likelihood. The probabilities are based on the recursive partitioning of a dataset of 10 000 known observations. The model covers alkyl chain length and branching, ethoxylate head length and number, and end capping of one or more of the ethoxylate chains. The relationship between chemical structure, shape and phase behaviour is discussed. This article is part of the themed issue ‘Soft interfacial materials: from fundamentals to formulation’.


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