Nanostructured Films: Langmuir–Blodgett (LB) and Layer-by-Layer (LbL) Techniques

2017 ◽  
pp. 105-123 ◽  
Author(s):  
R.F. de Oliveira ◽  
A. de Barros ◽  
M. Ferreira
2004 ◽  
Vol 14 (3) ◽  
pp. 303-309 ◽  
Author(s):  
Dirk M. Guldi ◽  
Israel Zilbermann ◽  
Gregory A. Anderson ◽  
Konstantinos Kordatos ◽  
Maurizio Prato ◽  
...  

2016 ◽  
Vol 20 (08n11) ◽  
pp. 889-894 ◽  
Author(s):  
Maria Luz Rodriguez-Mendez ◽  
Celia García-Hernandez ◽  
Cristina Medina-Plaza ◽  
Cristina García-Cabezón ◽  
Jose Antonio de Saja

Arrays of phthalocyanine-based sensors with complementary activity have been used to develop voltammetric electronic tongues. Such systems have demonstrated to be useful in enology for the evaluation of quality of wines in different production stages, from grapes to bottles. In this paper, the state of the art of multisensor systems based on phthalocyanines dedicated to the analysis of musts (juices obtained from crushed grapes) is described. Such multisensor systems cover different types of sensors from simple Carbon Paste Electrodes, to sophiticated nanostructured sensors, including Langmuir–Blodgett or Layer by Layer thin films and biomimetic biosensors where phthalocyanines play a crucial role as electron mediator between enzymes and electrodes. In all cases, multisensor systems based on phthalocyanines have been able to discriminate musts prepared from different varieties of grapes. The performance of these systems can be improved by combining non-specific sensors with biosensors containing enzymes selective to phenols. In this case, excellent relationships have been found between the responses provided by the array and the content in phenols and acids provided by traditional chemical analysis.


2014 ◽  
Vol 21 (02) ◽  
pp. 1450030
Author(s):  
INDRA GHOSH ◽  
AJITESH PAL ◽  
JAYASREE NATH ◽  
BIJAY KUMAR MISHRA ◽  
RANENDU KUMAR NATH

Anti-malarial methylene blue (MB) doped in arachidic acid (AA) have been incorporated in the Langmuir monolayer at the air–water interface and also in the Langmuir–Blodgett films deposited on quartz substrate. The pressure–area (π–A) isotherm studies at different concentrations of MB pointed out that pure MB could not form stable monolayer at the air–water interface and collapse readily at very low surface pressures. However, mixture of MB with AA formed stable monolayers and they could be transferred into solid quartz substrate to form mono/multi layered films of MB. The area per molecule of floating mixed monolayers was systematically decreased with the increasing concentrations of MB in the mixture. The pressure–time (π - t) isotherm study indicated the interaction kinetics between MB and AA. Higher the concentration of MB, higher is the increase in pressure. The spectroscopic characteristics of the mixed LB films have been compared with that of pure MB solution, microcrystal and layer-by-layer self assembled film with UV-Vis absorption spectroscopy. Surface morphology of the mixed LB and LbL film of MB was measured with atomic force microscopy (AFM).


2013 ◽  
Vol 2013 (CICMT) ◽  
pp. 000014-000018 ◽  
Author(s):  
M. Osada ◽  
T. Sasaki

We present a novel procedure for ceramic nanocoating using oxide nanosheet as a building block. A variety of oxide nanosheets (such as Ti1−δO2, MnO2 and perovsites) were synthesized by delaminating appropriate layered precursors into their molecular single sheets. These nanosheets are exceptionally rich in both structural diversity and electronic properties, with potential applications including conductors, semiconductors, insulators, and ferromagnets. Another attractive aspect is that nanosheets can be organized into various nanoarchitectures by applying solution-based synthetic techniques involving electrostatic layer-by-layer assembly and Langmuir-Blodgett deposition. It is even possible to tailor superlattice assemblies, incorporating into the nanosheet galleries with a wide range of materials such as organic molecules, polymers, and inorganic/metal nanoparticles. Sophisticated functionalities or paper-like devices can be designed through the selection of nanosheets and combining materials, and precise control over their arrangement at the molecular scale.


2016 ◽  
Vol 7 ◽  
pp. 209-219 ◽  
Author(s):  
Nik J Walch ◽  
Alexei Nabok ◽  
Frank Davis ◽  
Séamus P J Higson

In this paper we detail a novel semi-automated method for the production of graphene by sonochemical exfoliation of graphite in the presence of ionic surfactants, e.g., sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB). The formation of individual graphene flakes was confirmed by Raman spectroscopy, while the interaction of graphene with surfactants was proven by NMR spectroscopy. The resulting graphene–surfactant composite material formed a stable suspension in water and some organic solvents, such as chloroform. Graphene thin films were then produced using Langmuir–Blodgett (LB) or electrostatic layer-by-layer (LbL) deposition techniques. The composition and morphology of the films produced was studied with SEM/EDX and AFM. The best results in terms of adhesion and surface coverage were achieved using LbL deposition of graphene(−)SDS alternated with polyethyleneimine (PEI). The optical study of graphene thin films deposited on different substrates was carried out using UV–vis absorption spectroscopy and spectroscopic ellipsometry. A particular focus was on studying graphene layers deposited on gold-coated glass using a method of total internal reflection ellipsometry (TIRE) which revealed the enhancement of the surface plasmon resonance in thin gold films by depositing graphene layers.


2016 ◽  
Vol 4 (38) ◽  
pp. 14709-14719 ◽  
Author(s):  
M. S. Kim ◽  
L. Ma ◽  
S. Choudhury ◽  
S. S. Moganty ◽  
S. Wei ◽  
...  

This article reports two new Langmuir–Blodgett techniques designed to create ordered, multifunctional nanoparticle films.


2007 ◽  
Vol 17 (11) ◽  
pp. 1821-1827 ◽  
Author(s):  
F. Shi ◽  
Z. Liu ◽  
G.-L. Wu ◽  
M. Zhang ◽  
H. Chen ◽  
...  

2022 ◽  
pp. 407-441
Author(s):  
Celina M. Miyazaki ◽  
Flavio M. Shimizu ◽  
Marystela Ferreira

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Luiza A. Mercante ◽  
Vanessa P. Scagion ◽  
Adriana Pavinatto ◽  
Rafaela C. Sanfelice ◽  
Luiz H. C. Mattoso ◽  
...  

The use of gold nanoparticles combined with other organic and inorganic materials for designing nanostructured films has demonstrated their versatility for various applications, including optoelectronic devices and chemical sensors. In this study, we reported the synthesis and characterization of gold nanoparticles stabilized with poly(allylamine hydrochloride) (Au@PAH NPs), as well as the capability of this material to form multilayer Layer-by-Layer (LbL) nanostructured films with metal tetrasulfonated phthalocyanines (MTsPc). Film growth was monitored by UV-Vis absorption spectroscopy, atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR). Once LbL films have been applied as active layers in chemical sensors, Au@PAH/MTsPc and PAH/MTsPc LbL films were used in an electronic tongue system for milk analysis regarding fat content. The capacitance data were treated using Principal Component Analysis (PCA), revealing the role played by the gold nanoparticles on the LbL films electrical properties, enabling this kind of system to be used for analyzing complex matrices such as milk without any prior pretreatment.


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