A systematic study of the absorbance of the nitro functional group in the vacuum UV region

2021 ◽  
Vol 1185 ◽  
pp. 339042
Author(s):  
Courtney A. Cruse ◽  
John V. Goodpaster
Synthesis ◽  
2018 ◽  
Vol 50 (22) ◽  
pp. 4395-4412 ◽  
Author(s):  
Victor Snieckus ◽  
Claude Quesnelle

A systematic study of the widely used, titled name reaction transition-metal-catalyzed cross-coupling reactions with attention to context with the directed ortho metalation (DoM) is reported. In general, the Suzuki–Miyaura and Negishi protocols show greater scope and better yields than the Corriu–Kumada variant, although the latter qualitatively proceeds at fastest rate but has low functional group tolerance. The Negishi process is shown to be useful for substrates with nucleophile and base-sensitive functionality and it is comparable to the Suzuki–Miyaura reaction in efficiency. The link of these cross-coupling reactions to the DoM strategy lends itself to the regioselective construction of diversely substituted aromatics and heteroaromatics.


2000 ◽  
Vol 122 (16) ◽  
pp. 3952-3962 ◽  
Author(s):  
Caryn C. Borg-Breen ◽  
Maria T. Bautista ◽  
Cynthia K. Schauer ◽  
Peter S. White

2005 ◽  
Vol 887 ◽  
Author(s):  
B. Parekh ◽  
Thomas Debies ◽  
Pam Knight ◽  
K. S. V. Santhanam ◽  
Gerald A. Takacs

ABSTRACTMWNTs were photo-oxidized in quartz boats using low-pressure Hg lamps and emission downstream from Ar microwave plasmas which are primarily atomic line sources of 253.7 and 184.9 nm UV, and 106.7 and 104.8 nm vacuum UV (VUV) radiation, respectively. X-ray photoelectron spectroscopy (XPS) showed rapid oxidation during the first hour of UV treatment and then an increase that was directly proportional to the time of treatment up to 4 h where the oxygen concentration was 7.5 at%. VUV photo-oxidation resulted in an oxygen concentration up to 9.5 at% with exposure time for the initial 2 h of treatment. Beyond 2 h, the oxygen concentration decreased with VUV exposure due to a larger rate of de-oxidation than oxidation at the surface. Curve fitting of the XPS C1s spectra revealed mainly the C-O-C functional group with the presence of C=O, O-C=O and O=C-O-C=O moieties. SEM micrographs showed no apparent effect on the structure or appearance of the MWNTs as expected for surface modification.


RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 54449-54455 ◽  
Author(s):  
Bhavani Shankar Chinta ◽  
Beeraiah Baire

99% selectivity for cross coupling. Excellent yields (upto 94%). Low basic reaction medium, high functional group tolerance. Use of green solvent water.


Author(s):  
Gianluigi Botton ◽  
Gilles L'espérance

As interest for parallel EELS spectrum imaging grows in laboratories equipped with commercial spectrometers, different approaches were used in recent years by a few research groups in the development of the technique of spectrum imaging as reported in the literature. Either by controlling, with a personal computer both the microsope and the spectrometer or using more powerful workstations interfaced to conventional multichannel analysers with commercially available programs to control the microscope and the spectrometer, spectrum images can now be obtained. Work on the limits of the technique, in terms of the quantitative performance was reported, however, by the present author where a systematic study of artifacts detection limits, statistical errors as a function of desired spatial resolution and range of chemical elements to be studied in a map was carried out The aim of the present paper is to show an application of quantitative parallel EELS spectrum imaging where statistical analysis is performed at each pixel and interpretation is carried out using criteria established from the statistical analysis and variations in composition are analyzed with the help of information retreived from t/γ maps so that artifacts are avoided.


1976 ◽  
Vol 73 ◽  
pp. 436-440 ◽  
Author(s):  
Jan A. Herman ◽  
Janusz Gawlowski
Keyword(s):  

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