Synthesis of the Bifunctional Phosphinidene Cluster, Fe3(CO)9(μ3-PH)2, and a Systematic Study of the Reactivity of the Cluster-Bound P−H Functional Group

2000 ◽  
Vol 122 (16) ◽  
pp. 3952-3962 ◽  
Author(s):  
Caryn C. Borg-Breen ◽  
Maria T. Bautista ◽  
Cynthia K. Schauer ◽  
Peter S. White
Synthesis ◽  
2018 ◽  
Vol 50 (22) ◽  
pp. 4395-4412 ◽  
Author(s):  
Victor Snieckus ◽  
Claude Quesnelle

A systematic study of the widely used, titled name reaction transition-metal-catalyzed cross-coupling reactions with attention to context with the directed ortho metalation (DoM) is reported. In general, the Suzuki–Miyaura and Negishi protocols show greater scope and better yields than the Corriu–Kumada variant, although the latter qualitatively proceeds at fastest rate but has low functional group tolerance. The Negishi process is shown to be useful for substrates with nucleophile and base-sensitive functionality and it is comparable to the Suzuki–Miyaura reaction in efficiency. The link of these cross-coupling reactions to the DoM strategy lends itself to the regioselective construction of diversely substituted aromatics and heteroaromatics.


RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 54449-54455 ◽  
Author(s):  
Bhavani Shankar Chinta ◽  
Beeraiah Baire

99% selectivity for cross coupling. Excellent yields (upto 94%). Low basic reaction medium, high functional group tolerance. Use of green solvent water.


Author(s):  
Gianluigi Botton ◽  
Gilles L'espérance

As interest for parallel EELS spectrum imaging grows in laboratories equipped with commercial spectrometers, different approaches were used in recent years by a few research groups in the development of the technique of spectrum imaging as reported in the literature. Either by controlling, with a personal computer both the microsope and the spectrometer or using more powerful workstations interfaced to conventional multichannel analysers with commercially available programs to control the microscope and the spectrometer, spectrum images can now be obtained. Work on the limits of the technique, in terms of the quantitative performance was reported, however, by the present author where a systematic study of artifacts detection limits, statistical errors as a function of desired spatial resolution and range of chemical elements to be studied in a map was carried out The aim of the present paper is to show an application of quantitative parallel EELS spectrum imaging where statistical analysis is performed at each pixel and interpretation is carried out using criteria established from the statistical analysis and variations in composition are analyzed with the help of information retreived from t/γ maps so that artifacts are avoided.


1979 ◽  
Vol 40 (C1) ◽  
pp. C1-208-C1-210 ◽  
Author(s):  
J. P. Forester ◽  
D. J. Pegg ◽  
P. M. Griffin ◽  
G. D. Alton ◽  
S. B. Elston ◽  
...  

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