Ochre-based pigments have been employed since the first artistic expressions of mankind, with widespread diffusion during the Roman civilization. Such prominent use influenced their technological development, focused on functional and aesthetic optimization through complex manufacturing procedures. Furthermore, their appearance is also influenced by degradation processes, sometimes driven by natural disasters such as the eruption of Mount Vesuvius in 79 AD, in which yellow ochres of Vesuvian sites were sometimes converted to red by thermal alteration. In this contribution, a multi-analytical approach was adopted based on preliminary non-invasive investigations complemented by laboratory analyses to characterize the painted surfaces of the tablinum of the House of the Bicentenary (Herculaneum) with a particular focus on the ochre-based monochrome backgrounds. The study was aimed at (a) reconstructing the original color scheme of the walls and (b) deciphering the complex decorative techniques adopted by Roman craftsmen. The analytical results allowed testing and defining analytical procedures for the discrimination between the original and converted red pigments. Furthermore, these studies indicated that specific decorative technologies were adopted according to aesthetic, functional, and economic purposes, including the utilization of various qualities of ochre with different compositional and textural properties, and the mixture of ochre pigments with other compounds.
Novel environmentally friendly inorganic red pigments based on calcium bismuth oxides
