Mechanism study of mechanochemical bromination on fly ash mercury removal adsorbent

Chemosphere ◽  
2021 ◽  
Vol 274 ◽  
pp. 129637
Author(s):  
Xinze Geng ◽  
Yufeng Duan ◽  
Shilin Zhao ◽  
Jiwei Hu ◽  
Weimeng Zhao
Fuel ◽  
2021 ◽  
Vol 301 ◽  
pp. 121054
Author(s):  
Yue Peng ◽  
Tao Wang ◽  
Yongzheng Gu ◽  
Jiawei Wang ◽  
Yongsheng Zhang ◽  
...  

2015 ◽  
Vol 136 ◽  
pp. 96-105 ◽  
Author(s):  
Jiancheng Wang ◽  
Dekui Li ◽  
Fenglong Ju ◽  
Lina Han ◽  
Liping Chang ◽  
...  

2011 ◽  
Vol 255-260 ◽  
pp. 3404-3410
Author(s):  
Shuang Xi Li ◽  
An Quan Xu ◽  
Xin Jun Tang ◽  
Quan Hu

It takes on the technical and economic double benefits that fly ash taking the place of cement. However, water/binder of modern concrete is generally low; the research on the concrete performance which is based on large water/binder is no longer suitable for analysis of modern concrete. As to this problem, using different proportions of W/B and FA dosage as influencing factors, specimen is compounded for the compressive strength test. Then, mechanical properties of HPC are studied systematically. Based on this, macro-performance is analyzed from a micro-mechanism point of view through taking the electron micrograph. As the study shows, strength of HPC mixed with fly ash has low characteristics at early period while high ones at later period. At later hydration, fly ash effect plays a significant role, the growth rate of concrete strength increases as the increase of FA dosage. Compressive strength of concrete decreases as the increase of W/B and FA dosage. When the W/B is high, compressive strength is not sensitive to the change of W/B and FA dosage; but when the W/B decreases from 0.30 to 0.25, the concrete strength transition occurs. The influence of W/B on concrete compressive strength is more significant than that of the FA dosage; in the preparation of HPC, fly ash can be added more and cement is added less relatively by decreasing the W/B, displaying the role of micro-aggregate filling and modification, improving the strength and other performance of concrete. The study on micro-mechanism proves well the macro-phenomena above.


2013 ◽  
Vol 800 ◽  
pp. 132-138 ◽  
Author(s):  
Li Li ◽  
Si Wei Pan ◽  
Jiang Jun Hu ◽  
Ji Fu Kuang ◽  
Min Qi ◽  
...  

Mercury in the flue gas in coal-fired power plant as the research object using halogen compound as the modified material, the fly ash was modified by chemical immersion method,Study on adsorption agent, the adsorption temperature, modified material and loading on mercury adsorption of flue gas in coal-fired power plants. Experiments showed that, iodine adsorption properties of modified fly ash was the most significant, with the increase of the sorbent dosage, Hg removal efficiency increased, fly ash adsorption amount of change was not obvious, between 80-140°C temperature range, fly ash on mercury existed mainly physical adsorption, the mercury removal efficiency decreased with the increase of temperature, chemical adsorption occurred at 160°C, mercury removal efficiency increased.


2013 ◽  
Vol 864-867 ◽  
pp. 1546-1551
Author(s):  
Yin Xia Cao ◽  
Ji Hui Fang ◽  
Jiang Wu ◽  
Xian Li ◽  
Chong Zhang ◽  
...  

The original fly ash samples fetched from the power plant and the treated fly ash samples after screening, magnetic separation and mixing were used in the experiment of photocatalytic removal on mercury in flue gas. The fly ash samples and the absorption solution after experiment were tested for mercury content. The results showed that different sizes of the original fly ash had different characteristics of photocatalytic removal of mercury. The adsorption of mercury by fly ash was an important condition for the occurrence of photocatalytic effect. When the mercury adsorption capacity of fly ash was stronger, the capacity of photocatalytic removal mercury was also greater. The presence of iron oxide on the fly ash surface can promote the capability of photocatalytic removal of mercury by fly ash. The presence of ultraviolet light can significantly promote Hg0 oxidize to Hg2+ by fly ash. Thus the oxidized mercury in the flue gas can be easily absorbed by the solution.


2017 ◽  
Vol 5 (1) ◽  
pp. 391-399 ◽  
Author(s):  
Mahshid Attari ◽  
Syed Salman Bukhari ◽  
Hossein Kazemian ◽  
Sohrab Rohani

2021 ◽  
Author(s):  
Liqiang QI ◽  
Xu WANG ◽  
Wen WANG ◽  
Jingxin LI ◽  
Yan HUANG

Abstract Pyrite and fly ash have certain advantages in adsorption and mercury oxidation. The pyrite-modified fly ash (PY+AC-FA) mercury adsorbent was prepared by mixing pyrite (PY) with acid-modified fly ash (AC-FA), which has better mercury removal effect than AC-FA. The experimental results of mercury adsorption show: when the reaction temperature is 50°C, the best doping proportion of modified fly ash is 20wt%, the mass proportion of pyrite to acid modified fly ash is 4:1, and the flue gas flow rate is 1.0L/min, the adsorbent has the best performance, and the adsorption rate of mercury reaches 91.92%. BET, XRD, SEM, TG-DSG and XRF were used to characterize these adsorbents. And the mechanism of mercury removal of pyrite-modified fly ash adsorbent is inferred: Hg0 is first adsorbed on the surface of the adsorbent, and then oxidized to HgS by the active component FeS2 in pyrite-modified fly ash.


2019 ◽  
pp. 1-12 ◽  
Author(s):  
Mengting Shi ◽  
Guangqian Luo ◽  
Hailu Zhu ◽  
Renjie Zou ◽  
Jingyuan Hu ◽  
...  

Fuel ◽  
2019 ◽  
Vol 247 ◽  
pp. 179-186 ◽  
Author(s):  
Shumin Wang ◽  
Yongsheng Zhang ◽  
Yongzheng Gu ◽  
Jiawei Wang ◽  
Xuehai Yu ◽  
...  

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