Dewatering of Chlorella pyrenoidosa using diatomite dynamic membrane: Filtration performance, membrane fouling and cake behavior

2014 ◽  
Vol 113 ◽  
pp. 458-466 ◽  
Author(s):  
Yalei Zhang ◽  
Yangying Zhao ◽  
Huaqiang Chu ◽  
Xuefei Zhou ◽  
Bingzhi Dong
Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 945
Author(s):  
Weiwei Huang ◽  
Weiguang Lv ◽  
Huaqiang Chu ◽  
Weiwei Lv ◽  
Wenzong Zhou ◽  
...  

Combined microalgal and membrane filtration could effectively treat aquaculture wastewater; however, the membrane fouling induced by extracellular organic matter (EOM) during the dewatering process is an issue. This study investigated diatomite dynamic membrane (DDM) fouling behaviour during the dewatering of Chlorella pyrenoidosa under the influence of copper ions. The results indicate that copper ion heavy metals in aquaculture wastewater significantly affected purification and algae dewatering by DDM. Aquaculture wastewater with a high copper concentration (1 and 0.5 mg/L) could induce serious DDM fluxes and cake layer filtration resistance (Rc), whereas fewer filtration fluxes were induced when aquaculture wastewater had a low copper concentration, particularly that of 0.1 mg/L, at which the Rc was lowest and the concentration effect was highest. Macromolecular organics of EOM, such as biopolymers, polysaccharides, and proteins, were responsible for DDM fouling and accumulated mostly in the slime layer, whereas only a small amount of them accumulated in the diatomite layer. The DDM rejected more protein-like organics of EOM in the slime layer when dewatering algae at low copper concentrations (<0.1 mg/L); however, when using the DDM to dewater algae at high copper concentrations, more polysaccharides of EOM were rejected (0.5 < Cu2+ < 5 mg/L). This result has significant ramifications for aquaculture wastewater treatment as well as algae separation and concentration by the DDM.


2021 ◽  
Vol 43 (6) ◽  
pp. 428-438
Author(s):  
Kyeong-Rae Kim ◽  
In-Soung Chang

Objectives : The effect of current density and contact time of electro-coagulation on membrane fouling was investigated. In order to elucidate the reason why the membrane fouling was reduced by electro-coagulation, the changes in the characteristics of activated sludge were examined before and after electro-coagulation.Methods : A series of electro-coagulation of activated sludge suspensions was carried out with current density of 2.5, 6, 12, 24 A/m2 for 0, 2, 6, 12 hours. After membrane filtrations of the activated sludge suspensions, the membrane fouling was compared before and after the electro-coagulation. Characteristic changes in the activated sludge were also analyzed quantitatively.Results and Discussion : Total fouling resistances (Rt) of the electro-coagulated activated sludge decreased as current density and contact time increased. For example, Rt decreased 15%, 63% and 86% under the condition of current density of 24 A/m2 and 2, 6, 12 hours of contact time. Particularly, three activated sludge suspensions having very different initial MLSS concentrations showed a similar reduction of Rt, indicating that the membrane fouling was reduced not dominantly by particulates but by soluble foulants. The MLSS increased as current density increased, but MLVSS had not changed accordingly, which means that inorganic solids such as Al(OH)3 and AlPO4 produced during electro-coagulation were the main reasons for the increased MLSS concentration. These solids could play a key role in the reduction of membrane fouling by means of a dynamic membrane. As current density increased, the EPS (extracellular polymeric substances) and soluble COD concentration were reduced, which led to the reduction of membrane fouling. Soluble TN and TP were not significantly changed after electro-coagulation.Conclusions : The fouling materials, particularly, EPS and soluble COD decreased as current density and contact time increased, which played a key role in the reduction of membrane fouling. In addition, the insoluble solids produced during the electro-coagulation would act as a dynamic membrane, which led to fouling reduction.


2019 ◽  
Vol 56 (6) ◽  
pp. 54-56
Author(s):  
E.Yu. Agarkova ◽  
◽  
A.G. Kruchinin ◽  
A.A. Agarkov ◽  
V.D. Haritonov

2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 460
Author(s):  
Bastiaan Blankert ◽  
Bart Van der Bruggen ◽  
Amy E. Childress ◽  
Noreddine Ghaffour ◽  
Johannes S. Vrouwenvelder

The manner in which membrane-fouling experiments are conducted and how fouling performance data are represented have a strong impact on both how the data are interpreted and on the conclusions that may be drawn. We provide a couple of examples to prove that it is possible to obtain misleading conclusions from commonly used representations of fouling data. Although the illustrative example revolves around dead-end ultrafiltration, the underlying principles are applicable to a wider range of membrane processes. When choosing the experimental conditions and how to represent fouling data, there are three main factors that should be considered: (I) the foulant mass is principally related to the filtered volume; (II) the filtration flux can exacerbate fouling effects (e.g., concentration polarization and cake compression); and (III) the practice of normalization, as in dividing by an initial value, disregards the difference in driving force and divides the fouling effect by different numbers. Thus, a bias may occur that favors the experimental condition with the lower filtration flux and the less-permeable membrane. It is recommended to: (I) avoid relative fouling performance indicators, such as relative flux decline (J/J0); (II) use resistance vs. specific volume; and (III) use flux-controlled experiments for fouling performance evaluation.


Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 369
Author(s):  
Shengji Xia ◽  
Xinran Zhang ◽  
Yuanchen Zhao ◽  
Fibor J. Tan ◽  
Pan Li ◽  
...  

The membrane separation process is being widely used in water treatment. It is very important to control membrane fouling in the process of water treatment. This study was conducted to evaluate the efficiency of a pre-oxidation-coagulation flat ceramic membrane filtration process using different oxidant types and dosages in water treatment and membrane fouling control. The results showed that under suitable concentration conditions, the effect on membrane fouling control of a NaClO pre-oxidation combined with a coagulation/ceramic membrane system was better than that of an O3 system. The oxidation process changed the structure of pollutants, reduced the pollution load and enhanced the coagulation process in a pre-oxidation-coagulation system as well. The influence of the oxidant on the filtration system was related to its oxidizability and other characteristics. NaClO and O3 performed more efficiently than KMnO4. NaClO was more conducive to the removal of DOC, and O3 was more conducive to the removal of UV254.


2012 ◽  
Vol 66 (1) ◽  
pp. 9-14 ◽  
Author(s):  
C. Thiemig

Sludge properties have a strong impact on the operational aspects of membrane bioreactors (MBRs). Poor sludge properties cause stronger membrane fouling and reduce the filtration performance of MBRs. Up to now there is no general method used to measure the fouling or filtration relevant sludge properties in MBRs. The aim of this work was to develop a simple but reliable method to supply operators a tool to monitor the important sludge properties for their application and to compare this method with existing techniques. Through extensive research a new method called the sludge filtration index (SFI) has been developed to indicate the appropriate sludge parameters for MBR systems in a cheap and easy manner. The SFI can be measured with simple laboratory equipment and offers operators a powerful tool to monitor the conditions of their sludge, independent of the membrane conditions.


Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 553
Author(s):  
Dimitra C. Banti ◽  
Manassis Mitrakas ◽  
Petros Samaras

A promising solution for membrane fouling reduction in membrane bioreactors (MBRs) could be the adjustment of operating parameters of the MBR, such as hydraulic retention time (HRT), food/microorganisms (F/M) loading and dissolved oxygen (DO) concentration, aiming to modify the sludge morphology to the direction of improvement of the membrane filtration. In this work, these parameters were investigated in a step-aerating pilot MBR that treated municipal wastewater, in order to control the filamentous population. When F/M loading in the first aeration tank (AT1) was ≤0.65 ± 0.2 g COD/g MLSS/d at 20 ± 3 °C, DO = 2.5 ± 0.1 mg/L and HRT = 1.6 h, the filamentous bacteria were controlled effectively at a moderate filament index of 1.5–3. The moderate population of filamentous bacteria improved the membrane performance, leading to low transmembrane pressure (TMP) at values ≤2 kPa for a great period, while at the control MBR the TMP gradually increased reaching 14 kPa. Soluble microbial products (SMP), were also maintained at low concentrations, contributing additionally to the reduction of ΤΜP. Finally, the step-aerating MBR process and the selected imposed operating conditions of HRT, F/M and DO improved the MBR performance in terms of fouling control, facilitating its future wider application.


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