Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites

2016 ◽  
Vol 93 ◽  
pp. 153-162 ◽  
Author(s):  
Lidija Mancic ◽  
Patricia I. Pontón ◽  
Sonia Letichevsky ◽  
Antonio M. Costa ◽  
Bojan A. Marinkovic ◽  
...  
2021 ◽  
pp. 089270572110133
Author(s):  
Ayrton Alef Castanheira Pereira ◽  
José Roberto Moraes d’Almeida

Besides polyamide 11 (PA 11) outstanding properties, wear performance is considered a key factor for its continued widespread use. TiTanate NanoTubes (TTNT) have a huge potential as reinforcement in polymer matrix nanocomposites, and although nanotubes reinforcement capacity is well understood, its effect on tribological characteristics is still an open question. Thus, the present work has as objective to study the wear behavior of PA 11 and its nanocomposites, highlighting TTNT loading, functionalization and sodium content effects. Seeking the possibility to tailor properties, surface topography is investigated. Based on parameter classification, correlation and functional sense, an ideal roughness parameter set is defined. By taking measurements in X- and Y-axis, parameter variations and sensibility are also analyzed. From the results, maximum wear resistance can be reached in functionalized samples with low TTNT loading and high sodium content. Some roughness parameters demonstrate a moderate to strong correlation with wear performance. Parameter variations are mainly attributed to the non-stationarity of the surface.


2015 ◽  
Vol 83 ◽  
pp. 459-467 ◽  
Author(s):  
Lidija Mancic ◽  
Renata F.M. Osman ◽  
Antonio M.L.M. Costa ◽  
Jose R.M. d’Almeida ◽  
Bojan A. Marinkovic ◽  
...  

2018 ◽  
Vol 68 ◽  
pp. 238-247 ◽  
Author(s):  
Ayrton Alef Castanheira Pereira ◽  
Rafael Rosenberg Santos ◽  
José Roberto Moraes d’Almeida

Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.


Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2139
Author(s):  
Wei Shian Tey ◽  
Chao Cai ◽  
Kun Zhou

Multi Jet Fusion (MJF) is a recently developed polymeric powder bed fusion (PBF) additive manufacturing technique that has received considerable attention in the industrial and scientific community due to its ability to fabricate functional and complex polymeric parts efficiently. In this work, a systematic characterization of the physicochemical properties of MJF-certified polyamide 11 (PA11) and thermoplastic polyurethane (TPU) powder was conducted. The mechanical performance and print quality of the specimens printed using both powders were then evaluated. Both PA11 and TPU powders showed irregular morphology with sharp features and had broad particle size distribution, but such features did not impair their printability significantly. According to the DSC scans, the PA11 specimen exhibited two endothermic peaks, while the TPU specimen exhibited a broad endothermic peak (116–150 °C). The PA11 specimens possessed the highest tensile strength in the Z orientation, as opposed to the TPU specimens which possessed the lowest tensile strength along the same orientation. The flexural properties of the PA11 and TPU specimens displayed a similar anisotropy where the flexural strength was highest in the Z orientation and lowest in the X orientation. The porosity values of both the PA11 and the TPU specimens were observed to be the lowest in the Z orientation and highest in the X orientation, which was the opposite of the trend observed for the flexural strength of the specimens. The PA11 specimen possessed a low coefficient of friction (COF) of 0.13 and wear rate of 8.68 × 10−5 mm3/Nm as compared to the TPU specimen, which had a COF of 0.55 and wear rate of 0.012 mm3/Nm. The PA11 specimens generally had lower roughness values on their surfaces (Ra < 25 μm), while the TPU specimens had much rougher surfaces (Ra > 40 μm). This investigation aims to uncover and explain phenomena that are unique to the MJF process of PA11 and TPU while also serving as a benchmark against similar polymeric parts printed using other PBF processes.


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