scholarly journals Cellulose nanofiber/elastomer composites with high tensile strength, modulus, toughness, and thermal stability prepared by high-shear kneading

2020 ◽  
Vol 188 ◽  
pp. 108005 ◽  
Author(s):  
Toru Noguchi ◽  
Morinobu Endo ◽  
Kenichi Niihara ◽  
Hiroshi Jinnai ◽  
Akira Isogai
Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1064
Author(s):  
Mohd Nor Faiz Norrrahim ◽  
Hidayah Ariffin ◽  
Tengku Arisyah Tengku Yasim-Anuar ◽  
Mohd Ali Hassan ◽  
Nor Azowa Ibrahim ◽  
...  

Residual hemicellulose could enhance cellulose nanofiber (CNF) processing as it impedes the agglomeration of the nanocellulose fibrils and contributes to complete nanofibrillation within a shorter period of time. Its effect on CNF performance as a reinforcement material is unclear, and hence this study seeks to evaluate the performance of CNF in the presence of amorphous hemicellulose as a reinforcement material in a polypropylene (PP) nanocomposite. Two types of CNF were prepared: SHS-CNF, which contained about 11% hemicellulose, and KOH-CNF, with complete hemicellulose removal. Mechanical properties of the PP/SHS-CNF and PP/KOH-CNF showed an almost similar increment in tensile strength (31% and 32%) and flexural strength (28% and 29%) when 3 wt.% of CNF was incorporated in PP, indicating that hemicellulose in SHS-CNF did not affect the mechanical properties of the PP nanocomposite. The crystallinity of both PP/SHS-CNF and PP/KOH-CNF nanocomposites showed an almost similar value at 55–56%. A slight decrement in thermal stability was seen, whereby the decomposition temperature at 10% weight loss (Td10%) of PP/SHS-CNF was 6 °C lower at 381 °C compared to 387 °C for PP/KOH-CNF, which can be explained by the degradation of thermally unstable hemicellulose. The results from this study showed that the presence of some portion of hemicellulose in CNF did not affect the CNF properties, suggesting that complete hemicellulose removal may not be necessary for the preparation of CNF to be used as a reinforcement material in nanocomposites. This will lead to less harsh pretreatment for CNF preparation and, hence, a more sustainable nanocomposite can be produced.


RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 40383-40388 ◽  
Author(s):  
Hoik Lee ◽  
Jun Mo Koo ◽  
Daewon Sohn ◽  
Ick-Soo Kim ◽  
Seung Soon Im

Novel nanofibers of a highly heat-resistive biobased terpolyester of isosorbide (ISB), ethylene glycol, 1,4-cyclohexane dimethanol and terephthalic acid (PEICT) were fabricated using electrospinning and their properties were characterized.


2006 ◽  
Vol 50 ◽  
pp. 17-23 ◽  
Author(s):  
Hiroshi Ichikawa

The oxygen free SiC fiber (Hi-Nicalon) has been commercially produced by an electron beam curing process. And then the SiC fiber (Hi-Nicalon Type S) having stoichiometric SiC composition and high crystallinity has been developed. Hi-Nicalon fiber has higher elastic modulus and thermal stability than Nicalon fiber. The Type S fiber has the highest elastic modulus and thermal stability and excellent creep resistance in three types of Nicalon fibers. Recently,Type S fibers as industrial products have been developed and put on the market. The Type S fibers have a high tensile strength of 2.8 GPa, a high elastic modulus of 390 GPa. Against thermal exposure, Type S retains a tensile strength of 2.3 GPa and hardly changes its elastic modulus even at 1873K. Moreover, Type S has outstanding creep resistance. Type S shows higher stress relaxation ratio than many other ceramic fibers after thermal exposure over 1673K. Now, Hi-Nicalon Type S fiber/BN/SiC composites are being developed as the components of gas turbine for aerospace and land based power generation such as shrouds and combustors. Type Hi-Nicalon S can be supplied about 30 kg per a month at present.


Alloy Digest ◽  
2020 ◽  
Vol 69 (9) ◽  

Abstract Lucefin Group C30, C30E, and C30R are medium-carbon, non-alloy steels that are used in the normalized, cold worked, or quenched and tempered condition. C30E and C30R may also be flame or induction hardened. C30, C30E, and C30R are widely used for small, moderately stressed parts, where higher strength levels are needed than can be achieved in the lower carbon grades, and also where toughness is more important than high tensile strength. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on forming, heat treating, machining, and joining. Filing Code: CS-206. Producer or source: Lucefin S.p.A.


Alloy Digest ◽  
1997 ◽  
Vol 46 (10) ◽  

Abstract Vasco 9-4-20 (0.20 wt% C) is a premium quality aircraft steel that combines high tensile strength with good fracture toughness. It is a heat-treatable alloy capable of developing an ultimate tensile strength greater than 190 ksi. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance as well as heat treating, machining, and joining. Filing Code: SA-489. Producer or source: Vasco, An Allegheny Teledyne Company.


Alloy Digest ◽  
1976 ◽  
Vol 25 (12) ◽  

Abstract NJZ Alloy No. 55 is a zinc-cadmium alloy characterized by high tensile strength and hardness but low ductility. It has high stiffness and resiliency but low drawing and forming characteristics. Its applications include hardware and medallions. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as creep and fatigue. It also includes information on corrosion resistance as well as casting, forming, heat treating, machining, and joining. Filing Code: Zn-30. Producer or source: New Jersey Zinc Company.


ACS Omega ◽  
2021 ◽  
Vol 6 (4) ◽  
pp. 2890-2898
Author(s):  
Xiaojiao Jiao ◽  
Jiangling Liu ◽  
Jing Jin ◽  
Fei Cheng ◽  
Yunxin Fan ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 404
Author(s):  
Nur Sharmila Sharip ◽  
Hidayah Ariffin ◽  
Tengku Arisyah Tengku Yasim-Anuar ◽  
Yoshito Andou ◽  
Yuki Shirosaki ◽  
...  

The major hurdle in melt-processing of ultra-high molecular weight polyethylene (UHMWPE) nanocomposite lies on the high melt viscosity of the UHMWPE, which may contribute to poor dispersion and distribution of the nanofiller. In this study, UHMWPE/cellulose nanofiber (UHMWPE/CNF) bionanocomposites were prepared by two different blending methods: (i) melt blending at 150 °C in a triple screw kneading extruder, and (ii) non-melt blending by ethanol mixing at room temperature. Results showed that melt-processing of UHMWPE without CNF (MB-UHMWPE/0) exhibited an increment in yield strength and Young’s modulus by 15% and 25%, respectively, compared to the Neat-UHMWPE. Tensile strength was however reduced by almost half. Ethanol mixed sample without CNF (EM-UHMWPE/0) on the other hand showed slight decrement in all mechanical properties tested. At 0.5% CNF inclusion, the mechanical properties of melt-blended bionanocomposites (MB-UHMWPE/0.5) were improved as compared to Neat-UHMWPE. It was also found that the yield strength, elongation at break, Young’s modulus, toughness and crystallinity of MB-UHMWPE/0.5 were higher by 28%, 61%, 47%, 45% and 11%, respectively, as compared to the ethanol mixing sample (EM-UHMWPE/0.5). Despite the reduction in tensile strength of MB-UHMWPE/0.5, the value i.e., 28.4 ± 1.0 MPa surpassed the minimum requirement of standard specification for fabricated UHMWPE in surgical implant application. Overall, melt-blending processing is more suitable for the preparation of UHMWPE/CNF bionanocomposites as exhibited by their characteristics presented herein. A better mechanical interlocking between UHMWPE and CNF at high temperature mixing with kneading was evident through FE-SEM observation, explains the higher mechanical properties of MB-UHMWPE/0.5 as compared to EM-UHMWPE/0.5.


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