Impermeability characteristics of cementitious materials with self-healing based on epoxy/urea-formaldehyde microcapsules using an immersion test

2020 ◽  
Vol 259 ◽  
pp. 119782
Author(s):  
Tielin Han ◽  
Xianfeng Wang ◽  
Dawang Li ◽  
Dongfeng Li ◽  
Feng Xing ◽  
...  
Keyword(s):  
Urea Formaldehyde ◽  
Immersion Test ◽  
Cementitious Materials ◽  
Self Healing

scholarly journals Green synthesis of nanocapsules for self-healing anticorrosion coating using ultrasound-assisted approach

2018 ◽  
Vol 7 (2) ◽  
pp. 147-159 ◽  
Author(s):  
Uday D. Bagale ◽  
Shirish H. Sonawane ◽  
Bharat A. Bhanvase ◽  
Ravindra D. Kulkarni ◽  
Parag R. Gogate
Keyword(s):  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Immersion Test ◽  
Epoxy Coating ◽  
Self Healing ◽  
Actual Performance ◽  
Ultrasound Assisted

Abstract The present work deals with the production of nanocapsules containing a natural corrosion inhibition component. Azadirachta indica was encapsulated in urea-formaldehyde polymeric shell using ultrasound-assisted and conventional approaches of in situ polymerization. Subsequently nanocapsules were incorporated into clear epoxy polyamide to develop the green self-healing corrosion inhibition coating. The actual performance of the coating was evaluated based on the studies involving the repair of the crack of high solid surface coating. Corrosion inhibition of the healed area has been evaluated using the electrochemical impedance spectroscopy and immersion test based on the use of standard epoxy coating. The obtained results confirmed better corrosion protection in terms of the electrochemical impendence spectroscopy data and Tafel plot. It was found that current density decreases from 0.0011 A/cm2 (for standard epoxy coating) to 5.22 E−7 A/cm2 as 4 wt% nanocapsules incorporated in coating.

Mechanical Properties of Self-Healing System in Cementitious Material with Microcapsule

2018 ◽  
Vol 913 ◽  
pp. 1090-1096 ◽  
Author(s):  
Peng Liang ◽  
Qian Jin Mao ◽  
Zi Ming Wang ◽  
Su Ping Cui
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Strength Loss ◽  
Cementitious Materials ◽  
Self Healing ◽  
Healing System ◽  
The Matrix

In this paper, several urea–formaldehyde/epoxy microcapsules with different particle sizes were synthesized by in-situ polymerization. The chemical structure and compressive rupture load of microcapsule were characterized. The effect of microcapsule dosage, particle size and preload pressure on compressive strength of cementitious materials was studied. The result shows: when the particle size of microcapsule is 2 mm~2.5 mm, the rupture load of microcapsule is highest, more than 3N; When the microcapsule dosage is less than 2.5%, the strength loss of the matrix is relatively small; With the increase of the particle size of the capsule, the strength of the matrix decrease greatly; When the dosage of microcapsule is 2.5%, the particle size is 1.5 mm and the preload pressure is 30%~45%fmax, the compressive strength of the self-healing specimen is 8% higher than that of the non-preloaded specimens, which shows a certain self-healing performance.

scholarly journals Preparation and Properties of Melamine Urea-Formaldehyde Microcapsules for Self-Healing of Cementitious Materials

Materials ◽  
2016 ◽  
Vol 9 (3) ◽  
pp. 152 ◽  
Author(s):  
Wenting Li ◽  
Xujing Zhu ◽  
Nan Zhao ◽  
Zhengwu Jiang
Keyword(s):  
Urea Formaldehyde ◽  
Cementitious Materials ◽  
Self Healing

scholarly journals Self-Healing Coatings Based on Linseed-Oil-Loaded Microcapsules for Protection of Cementitious Materials

Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 404 ◽  
Author(s):  
Dong-Min Kim ◽  
In-Ho Song ◽  
Ju-Young Choi ◽  
Seung-Won Jin ◽  
Kyeong-Nam Nam ◽  
...  
Keyword(s):  
Protective Coating ◽  
Linseed Oil ◽  
Urea Formaldehyde ◽  
Cementitious Materials ◽  
The Self ◽  
Wall Material ◽  
Self Healing ◽  
Sorptivity Test ◽  
Coating Formulation ◽  
Coating Formulations

Linseed oil undergoes an oxidative drying reaction upon exposure to air, resulting in a soft film. The reaction conversion after 48 h reached 88% and 59% when it reacted at room temperature and −20 °C, respectively. Linseed-oil-loaded microcapsules were prepared using a urea-formaldehyde polymer as the shell wall material. The microcapsules were integrated into a commercially available protective coating formulation to prepare self-healing coating formulations with different capsule loadings. The coating formulations were applied on mortar specimens to prepare self-healing coatings. The effect of capsule loading on adhesion strength of the self-healing coating was studied. The self-healing function of the coating was investigated by SEM, a water sorptivity test and an accelerated carbonation test. Successful self-healing was demonstrated for both scratch and crack damage in the coatings. Low-temperature self-healing was demonstrated with a saline solution sorptivity test conducted at −20 °C. The linseed-oil-based microcapsule-type self-healing coating system is a promising candidate as a protective coating for cementitious materials.

scholarly journals Effect of fly ash on the self-healing capability of cementitious materials with crystalline admixture under different conditions

AIP Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 075018
Author(s):  
Xi Wang ◽  
Hao Qiao ◽  
Ziwei Zhang ◽  
Shiying Tang ◽  
Shengjun Liu ◽  
...  
Keyword(s):  
Fly Ash ◽  
Cementitious Materials ◽  
The Self ◽  
Self Healing

Performance of temperature adaptive microcapsules in self-healing cementitious materials under different mixing temperatures

2021 ◽  
Vol 299 ◽  
pp. 124254
Author(s):  
Jun Ren ◽  
Xianfeng Wang ◽  
Dongfeng Li ◽  
Shengye Xu ◽  
Biqin Dong ◽  
...  
Keyword(s):  
Cementitious Materials ◽  
Self Healing

ANTICORROSION PERFORMANCE OF SELF-HEALING POLYMERIC COATINGS ON LOW CARBON STEEL SUBSTRATES

2017 ◽  
Vol 79 (7-4) ◽  
Author(s):  
Muhammad Ashraff Ahmad Seri ◽  
Esah Hamzah ◽  
Abdelsalam Ahdash ◽  
Mohd Fauzi Mamat
Keyword(s):  
Steel Substrate ◽  
Salt Spray ◽  
Immersion Test ◽  
Salt Spray Test ◽  
Test Method ◽  
The Self ◽  
Self Healing ◽  
Pure Epoxy ◽  
Steel Substrates ◽  
Epoxy Paint

Recently, self-healing coating is classified as one of the smart coatings which has the ability to heal or repair damage of the coating to prevent further corrosion. The aim of this study is to synthesize the self-healing coatings from polymeric material and evaluate the performance and their corrosion behavior when coated on steel substrates. The corrosion tests were performed using immersion test and salt spray test method at room temperature. The immersion test shows that self-healing coating gives lower corrosion rate compared to pure epoxy paint, with a value of 0.02 and 0.05 mm/year respectively. Also, salt spray test shows similar trend as the immersion test, which is 0.11 and 0.19 mm/year for self-healing coating and pure epoxy paint respectively. While uncoated samples without any protection corroded at 0.89 mm/year. It was also found that the damage on self-healing coating was covered with zeolite from the microcapsules indicating that the self-healing agent was successfully synthesized and could function well. In other words, self-healing coating shows better corrosion resistance compared to the pure epoxy coating on steel substrate.

scholarly journals Numerical Studies of the Effects of Water Capsules on Self-Healing Efficiency and Mechanical Properties in Cementitious Materials

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Haoliang Huang ◽  
Guang Ye
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Cementitious Materials ◽  
Self Healing ◽  
Negative Effects ◽  
Numerical Studies ◽  
Healing Efficiency ◽  
The Impact ◽  
Positive Effect

In this research, self-healing due to further hydration of unhydrated cement particles is taken as an example for investigating the effects of capsules on the self-healing efficiency and mechanical properties of cementitious materials. The efficiency of supply of water by using capsules as a function of capsule dosages and sizes was determined numerically. By knowing the amount of water supplied via capsules, the efficiency of self-healing due to further hydration of unhydrated cement was quantified. In addition, the impact of capsules on mechanical properties was investigated numerically. The amount of released water increases with the dosage of capsules at different slops as the size of capsules varies. Concerning the best efficiency of self-healing, the optimizing size of capsules is 6.5 mm for capsule dosages of 3%, 5%, and 7%, respectively. Both elastic modulus and tensile strength of cementitious materials decrease with the increase of capsule. The decreasing tendency of tensile strength is larger than that of elastic modulus. However, it was found that the increase of positive effect (the capacity of inducing self-healing) of capsules is larger than that of negative effects (decreasing mechanical properties) when the dosage of capsules increases.

Self-healing in cementitious materials: Materials, methods and service conditions

2016 ◽  
Vol 92 ◽  
pp. 499-511 ◽  
Author(s):  
Haoliang Huang ◽  
Guang Ye ◽  
Chunxiang Qian ◽  
Erik Schlangen
Keyword(s):  
Cementitious Materials ◽  
Self Healing ◽  
Service Conditions
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