scholarly journals Anodic formation of self-organized Ti(Nb,Sn) oxide nanotube arrays with tuneable aspect ratio and size distribution

2013 ◽  
Vol 33 ◽  
pp. 84-87 ◽  
Author(s):  
J. Fornell ◽  
N.T.C. Oliveira ◽  
E. Pellicer ◽  
N. Van Steenberge ◽  
M.D. Baró ◽  
...  
2008 ◽  
Vol 368-372 ◽  
pp. 529-531
Author(s):  
Jin Liang Tao ◽  
Jian Ling Zhao ◽  
Rong Qing Xu ◽  
Ying Juan Mi ◽  
Ying Ru Kang ◽  
...  

The self-organized nanotube arrays were fabricated in glycerol electrolyte containing different additives, such as deionized water or ethylene glycol. The effects of anodization conditions, including anodic voltage, electrolyte viscosity, additives and ion concentration on the pores size and morphology were studied. Combined with preoxidation process, high aspect ratio titania nanotube arrays were formed rapidly in glycerol and saturated NaF solutions at 60 V for 1 h. SEM observation showed that a film with the thickness of about 10μm was obtained. A possible mechanism of the nanotubes growth was presented.


2011 ◽  
Vol 2011 ◽  
pp. 1-7 ◽  
Author(s):  
Chin Wei Lai ◽  
Srimala Sreekantan

Self-organized TiO2nanotube arrays have been fabricated by anodization of Ti foil in an electrochemical bath consisting of 1 M of glycerol with 0.5 wt% of NH4F. The effects of applied potential on the resulting nanotubes were illustrated. Among all of the applied potentials, 30 V resulted in the highest uniformity and aspect ratio TiO2nanotube arrays with the tube's length approximately 1 μm and pore's size of 85 nm. TiO2nanotube arrays were amorphous in as-anodized condition. The anatase phase was observed after annealing at 400∘Cin air atmosphere. The effect of crystallization and effective surface area of TiO2nanotube arrays in connection with the photoelectrochemical response was reported. Photoelectrochemical response under illumination was enhanced by using the annealed TiO2nanotube arrays which have larger effective surface area to promote more photoinduced electrons.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 510
Author(s):  
Wangzhu Cao ◽  
Kunfeng Chen ◽  
Dongfeng Xue

Nanoscale engineering of regular structured materials is immensely demanded in various scientific areas. In this work, vertically oriented TiO2 nanotube arrays were grown by self-organizing electrochemical anodization. The effects of different fluoride ion concentrations (0.2 and 0.5 wt% NH4F) and different anodization times (2, 5, 10 and 20 h) on the morphology of nanotubes were systematically studied in an organic electrolyte (glycol). The growth mechanisms of amorphous and anatase TiO2 nanotubes were also studied. Under optimized conditions, we obtained TiO2 nanotubes with tube diameters of 70–160 nm and tube lengths of 6.5–45 μm. Serving as free-standing and binder-free electrodes, the kinetic, capacity, and stability performances of TiO2 nanotubes were tested as lithium-ion battery anodes. This work provides a facile strategy for constructing self-organized materials with optimized functionalities for applications.


2001 ◽  
Vol 707 ◽  
Author(s):  
Harumasa Yoshida ◽  
Tatsuhiro Urushido ◽  
Hideto Miyake ◽  
Kazumasa Hiramtsu

ABSTRACTWe have successfully fabricated self-organized GaN nanotips by reactive ion etching using chlorine plasma, and have revealed the formation mechanism. Nanotips with a high density and a high aspect ratio have been formed after the etching. We deduce from X-ray photoelectron spectroscopy (XPS) analysis that the nanotip formation is attributed to nanometer-scale masks of SiO2 on GaN. The structures calculated by Monte Carlo simulation of our formation mechanism are very similar to the experimental nanotip structures.


Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1051 ◽  
Author(s):  
Raitis Sondors ◽  
Jelena Kosmaca ◽  
Gunta Kunakova ◽  
Liga Jasulaneca ◽  
Matiss Martins Ramma ◽  
...  

Size distribution, Young’s moduli and electrical resistivity are investigated for CuO nanowires synthesized by different thermal oxidation methods. Oxidation in dry and wet air were applied for synthesis both with and without an external electrical field. An increased yield of high aspect ratio nanowires with diameters below 100 nm is achieved by combining applied electric field and growth conditions with additional water vapour at the first stage of synthesis. Young’s moduli determined from resonance and bending experiments show similar diameter dependencies and increase above 200 GPa for nanowires with diameters narrower than 50 nm. The nanowires synthesized by simple thermal oxidation possess electrical resistivities about one order of magnitude lower than the nanowires synthesized by electric field assisted approach in wet air. The high aspect ratio, mechanical strength and robust electrical properties suggest CuO nanowires as promising candidates for NEMS actuators.


Micromachines ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 378 ◽  
Author(s):  
Hailiang Li ◽  
Changqing Xie

We report a robust, sidewall transfer metal assistant chemical etching scheme for fabricating Al2O3 nanotube arrays with an ultra-high aspect ratio. Electron beam lithography followed by low-temperature Au metal assisted chemical etching (MacEtch) is used to pattern high resolution, high aspect ratio, and vertical silicon nanostructures, used as a template. This template is subsequently transferred by an atomic layer deposition of the Al2O3 layer, followed by an annealing process, anisotropic dry etching of the Al2O3 layer, and a sacrificial silicon template. The process and characterization of the Al2O3 nanotube arrays are discussed in detail. Vertical Al2O3 nanotube arrays with line widths as small as 50 nm, heights of up to 21 μm, and aspect ratios up to 420:1 are fabricated on top of a silicon substrate. More importantly, such a sidewall transfer MacEtch approach is compatible with well-established silicon planar processes, and has the benefits of having a fully controllable linewidth and height, high reproducibility, and flexible design, making it attractive for a broad range of practical applications.


Author(s):  
Rong Qing Xu ◽  
Jian Ling Zhao ◽  
Jin Liang Tao ◽  
Zun Ming Lu ◽  
Yang Xian Li

2012 ◽  
Vol 2 (3) ◽  
pp. 253-259 ◽  
Author(s):  
Balaji Padya ◽  
Dipankar Kalita ◽  
P. K. Jain ◽  
G. Padmanabham ◽  
M. Ravi ◽  
...  

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