Generation of synthesis gas by partial oxidation of natural gas in a gas turbine

Energy ◽  
2006 ◽  
Vol 31 (15) ◽  
pp. 3199-3207 ◽  
Author(s):  
R. Cornelissen ◽  
E. Tober ◽  
J. Kok ◽  
T. van de Meer
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Synthesis Gas

scholarly journals Air Separation Unit Integration for Alternative Fuel Projects

1998 ◽  
Author(s):  
Arthur R. Smith ◽  
Joseph Klosek ◽  
James C. Sorensen ◽  
Donald W. Woodward
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Gas Turbines ◽  
Low Cost ◽  
Alternative Fuel ◽  
Air Separation ◽  
Separation Unit ◽  
Integration Schemes

Alternative fuel projects often require substantial amounts of oxygen. World scale gas-to-liquids (GTL) processes based on the partial oxidation of natural gas, followed by Fischer-Tropsch chemistry and product upgrading, may require in excess of 10,000 tons per day of pressurized oxygen. The remote location of many of these proposed projects and the availability of low-cost natural gas and byproduct steam from the GTL process disadvantages the use of traditional, motor-driven air separation units in favor of steam or gas turbine drive facilities. Another process of current interest is the partial oxidation of waste materials in industrial areas to generate synthesis gas. Synthesis gas may be processed into fuels and chemicals, or combusted in gas turbines to produce electricity. A key to the economic viability of such oxygen-based processes is cost effective air separation units, and the manner in which they are integrated with the rest of the facility. Because the trade-off between capital and energy is different for the remote gas and the industrial locations, the optimum integration schemes can also differ significantly. This paper examines various methods of integrating unit operations to improve the economics of alternative fuel facilities. Integration concepts include heat recovery, as well as several uses of byproduct nitrogen to enhance gas turbine operation or power production. Start-up, control and operational aspects are presented to complete the review of integrated designs.

Experimental Study of a 200 kW Partial Oxidation Gas Turbine (POGT) for Co-Production of Power and Hydrogen-Enriched Fuel Gas

2009 ◽  
Author(s):  
Joseph Rabovitser ◽  
Stan Wohadlo ◽  
John M. Pratapas ◽  
Serguei Nester ◽  
Mehmet Tartan ◽  
...  
Keyword(s):  
Experimental Study ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Combustion Products ◽  
Working Fluid ◽  
Fuel Gas ◽  
Lean Combustion ◽  
Start Up ◽  
Oxidation Reactor

Paper presents the results from development and successful testing of a 200 kW POGT prototype. There are two major design features that distinguish POGT from a conventional gas turbine: a POGT utilizes a partial oxidation reactor (POR) in place of a conventional combustor which leads to a much smaller compressor requirement versus comparably rated conventional gas turbine. From a thermodynamic perspective, the working fluid provided by the POR has higher specific heat than lean combustion products enabling the POGT expander to extract more energy per unit mass of fluid. The POGT exhaust is actually a secondary fuel gas that can be combusted in different bottoming cycles or used as synthesis gas for hydrogen or other chemicals production. Conversion steps for modifying a 200 kW radial turbine to POGT duty are described including: utilization of the existing (unmodified) expander; replacement of the combustor with a POR unit; introduction of steam for cooling of the internal turbine structure; and installation of a bypass air port for bleeding excess air from the compressor discharge because of 45% reduction in combustion air requirements. The engine controls that were re-configured for start-up and operation are reviewed including automation of POGT start-up and loading during light-off at lean condition, transition from lean to rich combustion during acceleration, speed control and stabilization under rich operation. Changes were implemented in microprocessor-based controllers. The fully-integrated POGT unit was installed and operated in a dedicated test cell at GTI equipped with extensive process instrumentation and data acquisition systems. Results from a parametric experimental study of POGT operation for co-production of power and H2-enriched synthesis gas are provided.

Natural Gas Decarbonization to Reduce CO2 Emission From Combined Cycles—Part II: Steam-Methane Reforming

2000 ◽  
Vol 124 (1) ◽  
pp. 89-95 ◽  
Author(s):  
G. Lozza ◽  
P. Chiesa
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Partial Oxidation ◽  
Power Plants ◽  
Combined Cycle ◽  
Performance Estimation ◽  
Thermodynamic Efficiency ◽  
Methane Reforming ◽  
Operating Pressure ◽  
Carbon Conversion

This paper discusses novel schemes of combined cycle, where natural gas is chemically treated to remove carbon, rather than being directly used as fuel. Carbon conversion to CO2 is achieved before gas turbine combustion. The first part of the paper discussed plant configurations based on natural gas partial oxidation to produce carbon monoxide, converted to carbon dioxide by shift reaction and therefore separated from the fuel gas. The second part will address methane reforming as a starting reaction to achieve the same goal. Plant configuration and performance differs from the previous case because reforming is endothermic and requires high temperature heat and low operating pressure to obtain an elevated carbon conversion. The performance estimation shows that the reformer configuration has a lower efficiency and power output than the systems addressed in Part I. To improve the results, a reheat gas turbine can be used, with different characteristics from commercial machines. The thermodynamic efficiency of the systems of the two papers is compared by an exergetic analysis. The economic performance of natural gas fired power plants including CO2 sequestration is therefore addressed, finding a superiority of the partial oxidation system with chemical absorption. The additional cost of the kWh, due to the ability of CO2 capturing, can be estimated at about 13–14 mill$/kWh.

Synthesis Gas Production by Combined Reforming of CO2-Containing Natural Gas with Steam and Partial Oxidation in a Multistage Gliding Arc Discharge System

2014 ◽  
Vol 53 (30) ◽  
pp. 11891-11900 ◽  
Author(s):  
Krittiya Pornmai ◽  
Narissara Arthiwet ◽  
Nongnuch Rueangjitt ◽  
Hidetoshi Sekiguchi ◽  
Sumaeth Chavadej
Keyword(s):  
Natural Gas ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Arc Discharge ◽  
Gas Production ◽  
Gliding Arc Discharge ◽  
Discharge System ◽  
Gliding Arc

Analysis of a Micro Gas Turbine Fed by Natural Gas and Synthesis Gas: MGT Test Bench and Combustor CFD Analysis

2012 ◽  
Vol 134 (7) ◽  
Author(s):  
M. Cadorin ◽  
M. Pinelli ◽  
A. Vaccari ◽  
R. Calabria ◽  
F. Chiariello ◽  
...  
Keyword(s):  
Numerical Analysis ◽  
Natural Gas ◽  
Gas Turbine ◽  
Synthesis Gas ◽  
Distribution System ◽  
Operating Conditions ◽  
Outlet Temperature ◽  
Monitoring And Control ◽  
Micro Gas Turbine ◽  
Gaseous Fuels

In recent years, the interest in the research on energy production systems fed by biofuels has increased. Gaseous fuels obtained through biomass conversion processes such as gasification, pyrolysis and pyrogasification are generally defined as synthesis gas (syngas). The use of synthesis gas in small-size energy systems, such as those used for distributed micro-cogeneration, has not yet reached a level of technological maturity that could allow a large market diffusion. For this reason, further analyses (both experimental and numerical) have to be carried out to allow these technologies to achieve performance and reliability typical of established technologies based on traditional fuels. In this paper, a numerical analysis of a combustor of a 100-kW micro gas turbine fed by natural gas and biomass-derived synthesis gas is presented. The work has been developed in the framework of a collaboration between the Engineering Department of the University of Ferrara, the Istituto Motori - CNR (Napoli), and Turbec S.p A. of Corporeno di Cento (FE). The main features of the micro gas turbine Turbec T100, located at the Istituto Motori - CNR, are firstly described. A decompression and distribution system allows the feeding of the micro gas turbine with gaseous fuels characterized by different compositions. Moreover, a system of remote monitoring and control together with a data transfer system has been developed in order to set the operative parameters of the machine. The results of the tests performed under different operating conditions are then presented. Subsequently, the paper presents the numerical analysis of a model of the micro gas turbine combustor. The combustor model is validated against manufacturer performance data and experimental data with respect to steady state performance, i.e., average outlet temperature and emission levels. A sensitivity analysis on the model capability to simulate different operating conditions is then performed. The combustor model is used to simulate the combustion of a syngas, composed of different ratios of hydrogen, carbon monoxide, methane, carbon dioxide and water. The results in terms of flame displacement, temperature and emission distribution and values are analyzed and compared to the natural gas simulations. Finally, some simple modifications to the combustion chamber are proposed and simulated both with natural gas and syngas feeding.

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