Central composite modeling for electrochemical degradation of paint manufacturing plant wastewater: One-step/two-response optimization

Author(s):  
Dilara Ozturk ◽  
Esra Dagdas ◽  
Baybars Ali Fil ◽  
Mohammed J.K. Bashir
Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6555
Author(s):  
Alice Nguvoko Kiyonga ◽  
Gyu Hwan Park ◽  
Hyun Su Kim ◽  
Young-Ger Suh ◽  
Tae Kon Kim ◽  
...  

Ionic liquids (ILs) have attracted significant interest because of their desirable properties. These characteristics have improved their application to overcome the shortcomings of conventional separation techniques for phytochemicals. In this study, several ILs were investigated for their capacity to extract isoimperatorin, a bioactive furanocoumarin, from the roots of Ostericum koreanum. Herein, 1-Butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF4]) was selected as a promising IL for separating isoimperatorin. A central composite design was applied to optimize the extraction conditions. Under the optimal conditions, the yield of isoimperatorin reached 97.17 ± 1.84%. Additionally, the recovery of isoimperatorin from the [Bmim][BF4] solution was successfully achieved (87.73 ± 2.37%) by crystallization using water as an antisolvent. The purity of the isoimperatorin was greatly enhanced, from 0.26 ± 0.28% in the raw material to 26.94 ± 1.26% in the product, in a one-step crystallization process. Namely, an enhancement of approximately 103-folds was reached. The developed approach overcomes the shortcomings of conventional separation methods applied for gaining isoimperatorin by significantly reducing the laboriousness of the process and the consumption of volatile organic solvents. Moreover, the simplicity and effectiveness of the method are assumed to be valuable for producing isoimperatorin-enriched products and for promoting its purification. This work also confirms the efficiency of ILs as a promising material for the separation of phytochemicals.


2019 ◽  
Vol 4 (9) ◽  
pp. 149-152
Author(s):  
Andrew Ozigagun ◽  
Raphael Biu

Welding is a multi-input multi-output fabrication process, which requires a multi-response optimization technique. In this present work, the effect of heat affected zone and percentage dilution on the quality of Tungsten Inert Gas welded joints was investigated using mild steel plates. The Central Composite Design matrix was adopted to perform the welding experiment and collect the data, thereafter Response Surface Methodology (RSM) models was employed to minimize heat affected zone and percentage dilution with very significant statistical results. The result shows that the quadratic model was the most suitable for the HAZ data and the percentage dilution data with a P-value < 0.05 and R2 value of 88% and 90% for the HAZ and percentage dilution respectively.


Author(s):  
Michael Sapanaro ◽  
Suhash Ghosh ◽  
Chittaranjan Sahay

The purpose of this project is to develop a motorcycle rear swing arm using finite element analysis and response optimization. This paper aims to discuss the specific features, benefits, and precautions when using design optimization to develop a specific project. Design Optimization has been an evolving process for many years. The latest versions of finite element software allow users to develop, analyze, and optimize structural designs within one program quickly and efficiently. A single shock absorber mounted close to the chassis and centrally located was the design selected to be analyzed. The design was selected for use in a variety of motorcycle types. This project consisted of a unique set of design attributes that were ideal to exemplify design optimization techniques. Static structural models were created to refine the design before using response optimization. These models finalized the material selection and initial sizes. A central composite design type was generated with selected boundary conditions for four parametric dimensions of the model. The ideal design of this component would include the resulting stress below a safe allowable value, minimal deflection, and the least amount of weight. It is evident that these three parameters will oppose one another as geometry is changed. Conceptually, an ideal candidate can be created that is a balance of the three parameters. Using the parameters of the selected candidate, a new model was generated for analysis. The final model was further refined by removing unnecessary material that was identified in the structural models. The first step in a thorough optimization is generating an appropriate amount of design parameter values that are an acceptable representation of all the possible outcomes, or design of experiments (DOE). The DOE tool used to generate the parameters in this project was central composite design (CCD), since it is the most appropriate for second order response models [1]. The second order relationship was confirmed using a trade-off plot. The two level, four input parameter DOE produces twenty five potential candidates that were refined using response surface. The response surface method used in this design process [2,3] to make judgement calls on the final design is examined during this development, and proves useful. Initial static structural models are created and used to set up the model for optimization. Material selection was also accomplished in this phase of development. This process aides in the overall design process by identifying areas of concern as well as the range of parameters that will be analyzed. Multiple acceptable candidates were selected through the use of the optimization tools and a final candidate was selected based on the output of the design attributes and the values of the corresponding parametric geometry. The final selection was also made with the consideration for cost, ease of fabrication, and standardization.


2020 ◽  
Vol 9 (4) ◽  
pp. e144942997
Author(s):  
Sayeny de Avila Gonçalves ◽  
Rafaela Cristina Sanfelice ◽  
Kassia Graciele dos Santos

Solidification/Stabilization (S/S) is an important technique used in waste treatment, due its low cost and easily processing. The aim of this study was to optimize and standardize the S/S process in a Brazilian company. The packing of the dangerous residue was done using a mixture of different solidifying agents, such as: clayey soil; superabsorbent polymer (SAP)/cellulose pulp (fluff) and sanding powder. It was evaluated the effect of different amount of solidifying agent over the volume of packed mixture, the final moisture and the cost of the S/S process, using a Central Composite Design.  The results showed a minimum cost for the S/S operation of R$ 192.89/ton of liquid waste, using about 71.69 tons of clay soil for each ton of untreated residue, allowing a highly packed residue with a moisture up to 20% (w.b.).


Author(s):  
R.P. Goehner ◽  
W.T. Hatfield ◽  
Prakash Rao

Computer programs are now available in various laboratories for the indexing and simulation of transmission electron diffraction patterns. Although these programs address themselves to the solution of various aspects of the indexing and simulation process, the ultimate goal is to perform real time diffraction pattern analysis directly off of the imaging screen of the transmission electron microscope. The program to be described in this paper represents one step prior to real time analysis. It involves the combination of two programs, described in an earlier paper(l), into a single program for use on an interactive basis with a minicomputer. In our case, the minicomputer is an INTERDATA 70 equipped with a Tektronix 4010-1 graphical display terminal and hard copy unit.A simplified flow diagram of the combined program, written in Fortran IV, is shown in Figure 1. It consists of two programs INDEX and TEDP which index and simulate electron diffraction patterns respectively. The user has the option of choosing either the indexing or simulating aspects of the combined program.


2006 ◽  
Vol 73 ◽  
pp. 85-96 ◽  
Author(s):  
Richard J. Reece ◽  
Laila Beynon ◽  
Stacey Holden ◽  
Amanda D. Hughes ◽  
Karine Rébora ◽  
...  

The recognition of changes in environmental conditions, and the ability to adapt to these changes, is essential for the viability of cells. There are numerous well characterized systems by which the presence or absence of an individual metabolite may be recognized by a cell. However, the recognition of a metabolite is just one step in a process that often results in changes in the expression of whole sets of genes required to respond to that metabolite. In higher eukaryotes, the signalling pathway between metabolite recognition and transcriptional control can be complex. Recent evidence from the relatively simple eukaryote yeast suggests that complex signalling pathways may be circumvented through the direct interaction between individual metabolites and regulators of RNA polymerase II-mediated transcription. Biochemical and structural analyses are beginning to unravel these elegant genetic control elements.


2010 ◽  
Vol 43 (18) ◽  
pp. 16
Author(s):  
MATTHEW R.G. TAYLOR
Keyword(s):  

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