scholarly journals Starch gelatinization temperature in sugar and polyol solutions explained by hydrogen bond density

2019 ◽  
Vol 94 ◽  
pp. 371-380 ◽  
Author(s):  
R.G.M. van der Sman ◽  
Lisa J. Mauer
2004 ◽  
Vol 62 (2) ◽  
pp. 113-120 ◽  
Author(s):  
Fa-De Li ◽  
Li-Te Li ◽  
Zaigui Li ◽  
Eizo Tatsumi

1998 ◽  
Vol 76 (11) ◽  
pp. 1491-1500
Author(s):  
Sonia Moffatt ◽  
Abdellah Ajji ◽  
Bernard Lotz ◽  
Josée Brisson

The effect of uniaxial drawing on orientation of the crystalline fraction of two polymers forming hydrogen bonds, nylon-6 and nylon-11, has been investigated using X-ray diffraction. These two polymers have similar crystal phases, although their hydrogen bond density differs. For both polymers, the deformation occurs in two steps, the first being a plastic deformation of the α-phase spherulites. This leads to two popul ations of crystals, one with the chain axis oriented parallel to the draw direction, the second with the a axis (hydrogen bond direction) aligned along the draw direction. In the second step, the a-axis aligned population gradually tilts, leading to a uniaxial orientation of the samples with chain axis aligned along the draw direction. For nylon-11, the onset of this step corresponds to the emergence of crystals of the γ phase, which rapidly becomes the major phase. It reaches a higher orientation than the α phase, and stems from crystallization upon tension of the polymer. For nylon-6, although the γ phase also appears during drawing, at the maximum draw ratio only a small fraction is present. This difference is attributed to the relative stability of the two phases, which is different for nylon-6 than for nylon-11.Key words: orientation, X-ray diffraction, nylon, hydrogen bonds.


2009 ◽  
Vol 74 (7) ◽  
pp. E382-E385 ◽  
Author(s):  
E. Morales-Sanchez ◽  
J.D.C. Figueroa ◽  
M. Gaytan-Martínez

1969 ◽  
Vol 17 (6) ◽  
pp. 1364-1369 ◽  
Author(s):  
Bienvenido O. Juliano ◽  
Myrna B. Nazareno ◽  
Natividad Ramos

1985 ◽  
Vol 37 (2) ◽  
pp. 40-50 ◽  
Author(s):  
B. O. Juliano ◽  
C. M. Perez ◽  
E. P. Alyoshin ◽  
V. B. Romanov ◽  
M. M. Bean ◽  
...  

2021 ◽  
Vol 9 (2) ◽  
pp. 166
Author(s):  
Ni Luh Feby Putri Pratami ◽  
Amna Hartiati ◽  
Bambang Admadi Harsojuwono

This study aims to determine the effect of variations in the ratio of gadung starch (Dioscorea hipida D.) - glucomannan and their interaction on the characteristics of bioplastic composites and to determine the ratio of gadung starch (Dioscorea hipida D.) - glucomannan and its gelatinization temperature which gives the best characteristics of bioplastic composites. This study used a factorial randomized block design (RBD) with two factors. The first factor is the variation in the ratio of the gadung tuber starch - glucomannan which consists of 3 levels, namely (60:40), (50:50), (40:60). The second factor is the gelatinization temperature which consists of 3 levels, namely 75 ± 1oC, 80 ± 1oC 85 ± 1oC. Each treatment was grouped into 2 based on the time of the manufacturing process so that 18 experimental units were obtained. The variables observed were tensile strength, elongation at break, elasticity, and biodegradation time. The data obtained were analyzed of variant and continued with the HSD Tukey. The results showed that the ratio of gadung - glucomannan starch, gelatinization temperature, and their interactions had a very significant effect on tensile strength, elongation at break, and elasticity but it did not significantly affect the biodegradation time. The ratio of gadung tuber starch - glucomannan (60:40) with a gelatinization temperature of 85 ± 1oC produced the best bioplastic characteristics with a tensile strength value of 4.4 MPa, an elongation at break of 9.5%, and elasticity value of 22.390 MPa and resulted in a degradation time of 7 days. 2 variables meet the standards, namely: the extension when the bioplastic composites have broken up has met the SNI plastic standards and biodegradation has met the international plastic standard ASTM 5336. Keywords: bioplastic, composite, gadung starch, gelatinization temperature, glucomannan,


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