Coalbed methane sorption related to coal deformation structures at different temperatures and pressures

Fuel ◽  
2012 ◽  
Vol 102 ◽  
pp. 760-765 ◽  
Author(s):  
Jienan Pan ◽  
Quanlin Hou ◽  
Yiwen Ju ◽  
Heling Bai ◽  
Yanqing Zhao
2014 ◽  
Vol 59 (2) ◽  
pp. 509-516
Author(s):  
Andrzej Olajossy

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.


2021 ◽  
Author(s):  
Wai Li ◽  
Jishan Liu ◽  
Jie Zeng ◽  
Yee-Kwong Leong ◽  
Derek Elsworth ◽  
...  

Abstract The process of extracting coalbed methane (CBM) is not only of significance for unconventional energy supply but also important in mine safety. The recent advance in fracking techniques, such as carbon dioxide (CO2) fracking, intensifies the complexity of stimulated coalbeds. This work focuses on developing a fully coupled multidomain model to describe and get insight into the process of CBM extraction, particularly from those compound-fractured coalbeds. A group of partial differential equations (PDEs) are derived to characterize gas transport from matrix to fractures and borehole. A stimulated coalbed is defined as an assembly of three interacting porous media: matrix, continuous fractures (CF) and radial primary hydraulic fracture (RF). Matrix and CF constitute a dual-porosity-dual-permeability system, while RF is simplified as an 1-D cracked medium. These media further form three distinct domains: non-stimulated reservoir domain (NSRD), stimulated reservoir domain (SRD) and RF. The effects of coal deformation, heat transfer, and non-thermal sorption are coupled into the model to reflect the multiple processes in CBM extraction. The finite element method is employed to numerically solve the PDEs. The proposed model is verified by comparing its simulation results to a set of well production data from Southern Qinshui Basin in Shanxi Province, China. Great consistency is observed, showing the satisfactory accuracy of the model for CBM extraction. After that, the difference between various stimulation patterns is presented by simulating the CBM extraction process with different stimulation patterns including (1) unstimulated coalbed; (2) double-wing fracture + NSRD; (3) multiple RFs + NSRD; (4) SRD + NSRD and (5) multiple RFs + SRD + NSRD. The results suggest that Pattern (5) (often formed by CO2 fracking) boosts the efficiency of CBM extraction because it generates a complex fracture network at various scales by both increasing the number of radial fractures and activating the micro-fractures in coal blocks. Sensitivity analysis is also performed to understand the influences of key factors on gas extraction from a stimulated coalbed with multiple domains. It is found that the distinct properties of different domains originate various evolutions, which in turn influences the CBM production. Ignoring thermal effects in CBM extraction will either overestimate or underestimate the production, which is the net effect of thermal strain and non-isothermal sorption. The proposed model provides a useful approach to accurately evaluate CBM extraction by taking the complex evolutions of coalbed properties and the interactions between different components and domains into account. The importance of multidomain and thermal effects for CBM reservoir simulation is also highlighted.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-13 ◽  
Author(s):  
Guannan Liu ◽  
Dayu Ye ◽  
Feng Gao ◽  
Jishan Liu

In the process of coalbed methane exploitation, the fracture and pore structure is the key problem that affects the permeability of coalbed. At present, the coupling effect of fracture and pore structure and in situ stress is seldom considered in the study of coal seam permeability. In this paper, the fractal seepage model is coupled with coal deformation, and the adsorption expansion effect is considered. A multifield coupling model considering the influence of matrix and fracture structure is established. Then, the influence of pore structure parameters of main fracture on macropermeability is analyzed, including (1) fractal dimension of fracture length, (2) maximum fracture length, (3) fractal dimension of throat diameter, and (4) fractal dimension of throat bending. At the same time, the simulation results are compared with the results of Darcy’s uniform permeability model. The results show that the permeability calculated by the proposed model is significantly different from that calculated by the traditional cubic model. Under the action of in situ stress, when the porosity and other parameters remain unchanged, the macropermeability of coal is in direct proportion to the fractal dimension of coal fracture length, the fractal dimension of throat diameter, and the maximum fracture length and in inverse proportion to the fractal dimension of coal throat curvature.


Author(s):  
Chen Hao ◽  
Qin Yong ◽  
Zhou Shangwen ◽  
Wang Hongyan ◽  
Chen Zhenhong ◽  
...  

Coalbed Methane(CBM) production enhancement for single wells is a big problem to CBM industrialization. Low production is due to insufficient gas generation by thermogenic. Luckily, Biogenic gas was found in many areas and its supply is assumed to improve coalbed methane production. Therefore, microbial simulation experiment will demonstrate the effectiveness of the assumption. From microbial simulation experiment on different coal ranks, it is found that microbes can use coals to produce biogas under laboratory conditions. With different temperatures for different experiments, it turns out that the gas production at 35 ℃ is greater than that at 15℃,indicating that 35℃ is more suitable for microbes to produce gas. According to quantitative experiments, adding exogenous nutrients or exogenous bacteria can improve CBM production. Moreover, the production enhancement ratio can reach up to 115% under the condition of adding exogenous bacterial species, while the ratio for adding nutrients can be up to 144%.


Author(s):  
Zhihang Li ◽  
Xiong Hu

AbstractShanxi Debao has affluent coalbed methane (CBM) reservoir in China. Understanding its characteristics, especially the diffusion characteristics of natural gas in the coal seam, is the key data of CBM development in this block. In this paper, a method of measuring the gas diffusion coefficient of coal and rock by the adsorption method is proposed by using the experimental method. The calculation model for calculating the gas diffusion coefficient of coal and rock is established according to the adsorption amount, and the diffusion correlation coefficient under different pressures, different water saturation and the different temperatures is established. The results show that it is feasible to calculate the diffusion coefficient of the gas in coal and rock according to the adsorption capacity of coal and rock. With the increase in the pressure, the diffusion coefficient increases, the water saturation increases. While the diffusion coefficient decreases, the temperature increases, and the diffusion coefficient increases. The results calculated by the model could provide guidance for the future development of Debao coalbed methane reservoir in Shanxi Province, China.


1998 ◽  
Vol 35 (1-4) ◽  
pp. 147-158 ◽  
Author(s):  
Peter J Crosdale ◽  
B.Basil Beamish ◽  
Marjorie Valix

2012 ◽  
Vol 52 (1) ◽  
pp. 291 ◽  
Author(s):  
Alireza Salmachi ◽  
Manouchehr Haghighi

Investigating the effects of in situ thermal treatment on coal seams requires adequate knowledge of gas sorption and its kinetics in coal at various temperatures. Methane sorption onto two Australian coal samples (high-volatile bituminous) at dry state and different temperatures was measured. Methane adsorption isotherms were measured at pressures up to 7 MPa by the gas adsorption manometric method. Adsorption isotherms data at two temperatures were used to investigate the effects of in situ thermal treatment on critical desorption pressure, ultimate gas recovery and the diffusion coefficient in coal. An increase of experimental temperature from 308 to 348 K resulted in a 50% reduction in the adsorption affinity of the coal sample and an insignificant reduction in the saturation capacity of the isotherms. At higher experimental temperatures, Langmuir isotherms exhibit downward shift with the initial gas content of the coal seam being constant, resulting in critical gas desorption pressure increase. According to the measured Langmuir isotherms at different temperatures, an increase in reservoir temperature by 1 K leads to a 2% and 1.2% increase in total recovery for the tested coal seams. Gas left in the coal seam at the abandonment pressure can only be recovered at a higher reservoir temperature. Diffusion coefficients of coal seam samples were calculated for different experimental temperatures. Fractional uptakes of the first coal sample show a good agreement with the results obtained using the unipore diffusion model with the diffusion coefficient to be 4.7 × 10–12 m2/s at 348 K. For the second coal sample, the unipore diffusion model fairly matches the uptake data. A bidisperse diffusion model was also applied to measure the adsorption kinetics of the second coal sample, resulting in an improved agreement with the experimental uptake data. Both coal samples exhibited a reduction of the diffusion coefficient with an increase in equilibrium pressure; this effect was more pronounced at equilibrium pressures below 0.045 MPa. It was observed that the diffusion coefficient change with pressure becomes flat at high pressures, with the pressure effect diminishing much faster at lower temperatures.


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