On time dependency of interfacial tension through low salinity carbonated water injection

Fuel ◽  
2020 ◽  
Vol 280 ◽  
pp. 118492 ◽  
Author(s):  
Ali Rahimi ◽  
Mehdi Safari ◽  
Bizhan Honarvar ◽  
Hadi Chabook ◽  
Raoof Gholami
Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 748 ◽  
Author(s):  
Aly Hamouda ◽  
Nikhil Bagalkot

Carbonated water injection (CWI) is a promising enhanced oil recovery (EOR) and CO2 sequestration method, which overcomes the problems associated with CO2 EOR. CO2 mass transfer and interfacial tension (IFT) are important parameters that influence oil recovery efficiency. This study addresses the impact of MgCl2 and Na2SO4 in carbonated water (CW) on CW/hydrocarbon IFT and CO2 mass transfer. An axisymmetric drop shape analysis was used to estimate the IFT and the CO2 diffusion coefficient. It was found that CW+MgCl2 reduced both the CW/n-decane IFT (36.5%) and CO2 mass transfer, while CW+Na2SO4 increased both the IFT and CO2 mass transfer (57%). It is suggested that reduction in IFT for CW+MgCl2 brine is mainly due to the higher hydration energy of Mg2+. The Mg2+ ion forms a tight bond to the first hydration shell [Mg(H2O)6]2+, this increases the effective size at the interface, hence reduce IFT. Meanwhile, the SO42− outer hydration shell has free OH groups, which may locally promote CO2 mass transfer. The study illustrates the potential of combining salts and CW in enhancing CO2 mass transfer that can be the base for further investigations. Furthermore, the contribution and proposed mechanisms of the different ions (SO42− and Mg2+) to the physical process in carbonated water/hydrocarbon have been addressed, which forms one of primary bases of EOR.


2021 ◽  
Vol 61 (2) ◽  
pp. 575
Author(s):  
Ehsan Yazdani Sadati ◽  
Arman Siahvashi ◽  
Suzanne Hurter

Carbonated water injection (CWI) is described as a chemical-enhanced oil recovery method in which CO2-enriched water is injected into oil reservoirs as a displacing fluid. Although confirmed by many that a considerable amount of recovery improvement is attainable through CWI in both lab and field scales, the interaction of salinity on the performance of CWI and its potential fines migration is not very well understood. This study examines the efficiency of oil recovery improvement during low-salinity carbonated water injection (LSCWI) in a sandstone reservoir, while total dissolved salt concentration varies. To this end, a series of coreflooding experiments were performed on homogeneous sandstone cores at 80°C and 2000psi, and the amount of oil recovery was measured. From the experiments, it was observed that CWI could extract more crude oil than conventional water flooding in all salinities. In particular, the highest oil recovery was observed in the lowest salinity (61.2% in CWI and 42% during water flooding), indicating that by carbonating low-salinity water, oil recovery is enhanced by 20%. Moreover, the influence of salinity reduction on recovery enhancement was such that 9% of recovery improvement observed during conventional water flooding when salinity decreased from 40000 to 1000ppm. At the same time, this improvement was around 15% for CWI, suggesting that salinity reduction can be more effective in CWI rather than water flooding in recovery improvement. It was also found out that while recovery improvement and fines migration are both highly affected by water salinity, there is a synergy between the efficiency of CWI and onset of fines migration, which is one of the underlying mechanisms in oil recovery improvement during LSCWI into clay-containing sandstone reservoirs.


2014 ◽  
Vol 695 ◽  
pp. 499-502 ◽  
Author(s):  
Mohamad Faizul Mat Ali ◽  
Radzuan Junin ◽  
Nor Hidayah Md Aziz ◽  
Adibah Salleh

Malaysia oilfield especially in Malay basin has currently show sign of maturity phase which involving high water-cut and also pressure declining. In recent event, Malaysia through Petroliam Nasional Berhad (PETRONAS) will be first implemented an enhanced oil recovery (EOR) project at the Tapis oilfield and is scheduled to start operations in 2014. In this project, techniques utilizing water-alternating-gas (WAG) injection which is a type of gas flooding method in EOR are expected to improve oil recovery to the field. However, application of gas flooding in EOR process has a few flaws which including poor sweep efficiency due to high mobility ratio of oil and gas that promotes an early breakthrough. Therefore, a concept of carbonated water injection (CWI) in which utilizing CO2, has ability to dissolve in water prior to injection was applied. This study is carried out to assess the suitability of CWI to be implemented in improving oil recovery in simulated sandstone reservoir. A series of displacement test to investigate the range of recovery improvement at different CO2 concentrations was carried out with different recovery mode stages. Wettability alteration properties of CWI also become one of the focuses of the study. The outcome of this study has shown a promising result in recovered residual oil by alternating the wettability characteristic of porous media becomes more water-wet.


Fuel ◽  
2019 ◽  
Vol 237 ◽  
pp. 1086-1107 ◽  
Author(s):  
Cleverson Esene ◽  
Nima Rezaei ◽  
Amer Aborig ◽  
Sohrab Zendehboudi

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