MD simulations of oil-in-water/water-in-oil emulsions during surfactant-steam co-injection in bitumen recovery

Fuel ◽  
2021 ◽  
pp. 122718
Author(s):  
Mohammadali Ahmadi ◽  
Zhangxin Chen
2021 ◽  
Vol 9 (1) ◽  
pp. 97
Author(s):  
Merv Fingas

The visual appearance of oil spills at sea is often used as an indicator of spilled oil properties, state and slick thickness. These appearances and the oil properties that are associated with them are reviewed in this paper. The appearance of oil spills is an estimator of thickness of thin oil slicks, thinner than a rainbow sheen (<3 µm). Rainbow sheens have a strong physical explanation. Thicker oil slicks (e.g., >3 µm) are not correlated with a given oil appearance. At one time, the appearance of surface discharges from ships was thought to be correlated with discharge rate and vessel speed; however, this approach is now known to be incorrect. Oil on the sea can sometimes form water-in-oil emulsions, dependent on the properties of the oil, and these are often reddish in color. These can be detected visually, providing useful information on the state of the oil. Oil-in-water emulsions can be seen as a coffee-colored cloud below the water surface. Other information gleaned from the oil appearance includes coverage and distribution on the surface.


Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1071 ◽  
Author(s):  
Yu-Jin Cho ◽  
Dong-Min Kim ◽  
In-Ho Song ◽  
Ju-Young Choi ◽  
Seung-Won Jin ◽  
...  

A pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA)-based oligoimide (PMDA-ODA) was synthesized by a one-step procedure using water as a solvent. The PMDA-ODA particles showed excellent partial wetting properties and were stably dispersed in both water and oil phases. A stable dispersion was not obtained with comparison PMDA-ODA particles that were synthesized by a conventional two-step method using an organic solvent. Both oil-in-water and water-in-oil Pickering emulsions were prepared using the oligoimide particles synthesized in water, and the size of the emulsion droplet was controlled based on the oligoimide particle concentration. The oligoimide particles were tested to prepare Pickering emulsions using various kinds of oils. The oil-in-water Pickering emulsions were successfully applied to prepare microcapsules of the emulsion droplets. Our new Pickering emulsion stabilizer has the advantages of easy synthesis, no need for surface modification, and the capability of stabilizing both oil-in-water and water-in-oil emulsions.


2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Roselaine Facanali ◽  
Nathália de A. Porto ◽  
Juliana Crucello ◽  
Rogerio M. Carvalho ◽  
Boniek G. Vaz ◽  
...  

Naphthenic acids (NAs) are compounds naturally present in most petroleum sources comprised of complex mixtures with a highly variable composition depending on their origin. Their occurrence in crude oil can cause severe corrosion problems and catalysts deactivation, decreasing oil quality and consequently impacting its productivity and economic value. NAs structures also allow them to behave as surfactants, causing the formation and stabilization of emulsions. In face of the ongoing challenge of treatment of water-in-oil (W/O) or oil-in-water (O/W) emulsions in the oil and gas industry, it is important to understand how NAs act in emulsified systems and which acids are present in the interface. Considering that, this review describes the properties of NAs, their role in the formation and stability of oil emulsions, and the modern analytical methods used for the qualitative analysis of such acids.


2000 ◽  
Vol 48 (10) ◽  
pp. 4874-4882 ◽  
Author(s):  
Karin Schwarz ◽  
Shu-Wen Huang ◽  
J. Bruce German ◽  
Brigitte Tiersch ◽  
Jürgen Hartmann ◽  
...  

1993 ◽  
Vol 115 (3) ◽  
pp. 515-522 ◽  
Author(s):  
S. H. Wang ◽  
A. Al-Sharif ◽  
K. R. Rajagopal ◽  
A. Z. Szeri

Oil-in-water and water-in-oil emulsions are often employed as lubricants. In many applications of emulsion lubricants both the deformation of the bounding solid surfaces and the pressure dependence of the viscosity of the lubricant contribute essentially to performance, thus defining lubrication in the elastohydrodynamic (EHD) mode. In this paper we investigate lubrication with liquid-liquid binary mixtures of two Newtonian fluids in an EHD conjunction, and discuss the effect of varying the parameters of the problem on pressure, film thickness and volume fraction distribution. The basic theory of lubrication with liquid-liquid mixtures is contained in an earlier publication (Al-Sharif et al., 1992), here we use the theory to study an important application.


Author(s):  
Дарья Алексеевна Портнова ◽  
Виолетта Андреевна Веролайнен ◽  
Светлана Анатольевна Темникова

Методом определения температуры инверсии фаз (ТИФ) получены и исследованы обратные эмульсии оливкового масла в воде с применением в качестве стабилизаторов неионогенных поверхностноактивных веществ синтанола OC-20, сорбитана моностеарата Span 60 и их смесей. Reverse emulsions of olive oil in water with the use of non-ionic surfactants syntanol OC-20, sorbitan monostearate Span 60 and their mixtures as stabilizers were obtained and studied by the method of determining the temperature of phase inversion (TIF).


2020 ◽  
Vol 44 (32) ◽  
pp. 13534-13541
Author(s):  
Xin Gao ◽  
Qiang Ma ◽  
Zhengwei Jin ◽  
Pei Nian ◽  
Zheng Wang

A switchable superlyophobic ZIF-8 membrane can selectively remove oil droplets in oil-in-water emulsions via superoleophobicity and water droplets in water-in-oil emulsions via superhydrophobicity.


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