Studies on mechanical properties of dispersing intercalated silane montmorillonite in low density polyethylene matrix

Author(s):  
Sung-Po Liu ◽  
Liang-Chun Tu
2020 ◽  
pp. 152808372092936
Author(s):  
SS Abhilash ◽  
D Lenin Singaravelu

Natural fibres find their application as a reinforcing agent for polymer composites to obtain parts with improved mechanical properties. Manufacturing of non-metallic products is incorporated with natural fibres for better strength and to reduce cost. Rotational moulding is a process used for the manufacturing of hollow plastic products, especially water tanks, plastic fuel tanks, barrels, kayaks, refrigerated panels, etc. Incorporation of natural fibres to reinforce polymers in rotational moulding process is a tedious task; since there is no control over fibre and polymer powder mixture, which is rotating bi-axially, it may lead to fibre agglomeration. The present work investigates the mouldability of linear low density polyethylene composites with tampico and coir fibre as the reinforcement agents using a bi-axial rotomoulding machine. NaOH-treated fibres with 5, 10 and 15% by weight have been added to the linear low density polyethylene matrix, and the composites were prepared by rotational moulding process. Mechanical properties such as tensile strength, flexural strength, impact strength and hardness have been investigated. Dynamic mechanical behaviour such as storage modulus, loss modulus and tan  δ of the different composites has been investigated with dynamic mechanical analyser. Fractured surfaces were examined qualitatively with the help of a scanning electron microscope for determining the interfacial properties and fibre adhesion between the fibres and the linear low density polyethylene matrix.


Author(s):  
Akinlabi O. David ◽  
Ibeh Stanley Chukwuemeka ◽  
Enegide E. Osther ◽  
Garba N. Salihu

The EU's End of Life Vehicles (ELV) regulations are forcing car manufacturers to consider the environmental impact of their production and possibly shift from the use of synthetic materials to the use of agro-based materials. However, poor mechanical properties and certain manufacturing limitations currently limit the use of agro-based materials to non-structural and semi-structural automotive components. This research is focused on a composite of hybrid coconut/glass fiber as reinforcement in recycled low density polyethylene matrix alone to enhance the desired mechanical properties for car bumper as automotive structural components. X-ray fluorescence analysis conducted on coconut fiber showed the presence of silica and alumina materials make coconut fibre a choice one. Morphology analysis was performed using scanning electron microscopy (SEM), which reveals that there are small discontinuities and reasonably uniform distribution of the reinforcement fibers and the reinforced low density polyethylene (RLDPE) binder resulting to better mechanical properties. Physic-chemical properties that directly affect developed composite such as variation of Density, Water Absorption, Tensile Strength, Bending strength, Modulus of rupture, Impact Strength and Hardness Values were investigated for both unhybridized and hybridized developed composite. The study shows the successful development of composites of coconut fiber (CF) hybridized with glass fiber (GF) and reinforced low density polyethylene (RLDPE) binder using a simple molding technique. Hybridized samples (CF-GF/RLDPE) showed higher strength when compared to un-hybridized (CF/RLDPE) composites. Better microstructural bonding exists with 25% and 30% wt CF-GF composite resulting in good mechanical properties for the hybridized composites. The grades of composites obtained in the course of this study are applicable in the production of low strength car bumpers.


Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1821
Author(s):  
Ildar I. Salakhov ◽  
Nadim M. Shaidullin ◽  
Anatoly E. Chalykh ◽  
Mikhail A. Matsko ◽  
Alexey V. Shapagin ◽  
...  

Low-temperature properties of high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and their blends were studied. The analyzed low-temperature mechanical properties involve the deformation resistance and impact strength characteristics. HDPE is a bimodal ethylene/1-hexene copolymer; LDPE is a branched ethylene homopolymer containing short-chain branches of different length; LLDPE is a binary ethylene/1-butene copolymer and an ethylene/1-butene/1-hexene terpolymer. The samples of copolymers and their blends were studied by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), 13С NMR spectroscopy, and dynamic mechanical analysis (DMA) using testing machines equipped with a cryochamber. It is proposed that such parameters as “relative elongation at break at −45 °C” and “Izod impact strength at −40 °C” are used instead of the ductile-to-brittle transition temperature to assess frost resistance properties because these parameters are more sensitive to deformation and impact at subzero temperatures for HDPE. LLDPE is shown to exhibit higher relative elongation at break at −45 °C and Izod impact strength at −20 ÷ 60 °C compared to those of LDPE. LLDPE terpolymer added to HDPE (at a content ≥ 25 wt.%) simultaneously increases flow properties and improves tensile properties of the blend at −45 °C. Changes in low-temperature properties as a function of molecular weight, MWD, crystallinity, and branch content were determined for HDPE, LLDPE, and their blends. The DMA data prove the resulting dependences. The reported findings allow one to understand and predict mechanical properties in the HDPE–LLDPE systems at subzero temperatures.


2015 ◽  
Vol 37 (11) ◽  
pp. 3167-3174 ◽  
Author(s):  
S. Sánchez-Valdes ◽  
E. Ramírez-Vargas ◽  
L.F. Ramos de Valle ◽  
J.G. Martinez-Colunga ◽  
J. Romero-Garcia ◽  
...  

2020 ◽  
Vol 15 (3) ◽  
pp. 44-49
Author(s):  
Ibiyemi A. Idowu ◽  
Olutosin O. Ilori

The study examined the effect of fillers on the mechanical properties of the recycled low density polyethylene composites under weathered condition with a view of managing the generation and disposal of plastic wastes. Discarded pure water sachets and fillers (glass and talc) were sourced and recycled. Recycled low density polyethylene (RLDPE) and preparation of RLDPE/glass, RLDPE/talc and RLDPE/glass/talc composites were carried out using a furnace at compositions of 0 – 40% in steps of 10% by weight. The mixtures were poured into hand-laid mould. The samples produced were exposed to sunlight for eight (8) weeks and their mechanical properties were studied. The results of mechanical tests revealed that tensile strength decreased with increasing filler loading while impact strength and hardness property increased marginally and considerably with increasing filler loading for all the composites respectively. The study concluded that glass and talc were able to reinforce recycled low density polyethylene under weathered condition. Keywords: Recycled Low Density Polyethylene (RLDPE); Fillers; Glass, Talc; Weathering condition; Sunlight; and Mechanical properties; Tensile strength, Impact and hardness


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