Geochemical evaluation of volcanic rocks and soils around Meru volcanic complex, northern Tanzania: Implications for fluorine source, mobility and contamination of groundwater systems

Author(s):  
Edikafubeni Makoba
Author(s):  
T.V. Naber ◽  
S.E. Grasby ◽  
J.P. Cuthbertson ◽  
N. Rayner ◽  
C. Tegner

The High Arctic Large Igneous Province (HALIP) represents extensive Cretaceous magmatism throughout the circum-Arctic borderlands and within the Arctic Ocean (e.g., the Alpha-Mendeleev Ridge). Recent aeromagnetic data shows anomalies that extend from the Alpha Ridge onto the northern coast of Ellesmere Island, Nunavut, Canada. To test this linkage we present new bulk rock major and trace element geochemistry, and mineral compositions for clinopyroxene, plagioclase, and olivine of basaltic dykes and sheets and rhyolitic lavas for the stratotype section at Hansen Point, which coincides geographically with the magnetic anomaly at northern Ellesmere Island. New U-Pb chronology is also presented. The basaltic and basaltic-andesite dykes and sheets at Hansen Point are all evolved with 5.5−2.5 wt% MgO, 48.3−57.0 wt% SiO2, and have light rare-earth element enriched patterns. They classify as tholeiites and in Th/Yb vs. Nb/Yb space they define a trend extending from the mantle array toward upper continental crust. This trend, also including a rhyolite lava, can be modeled successfully by assimilation and fractional crystallization. The U-Pb data for a dacite sample, that is cut by basaltic dykes at Hansen Point, yields a crystallization age of 95.5 ± 1.0 Ma, and also shows crustal inheritance. The chronology and the geochemistry of the Hansen Point samples are correlative with the basaltic lavas, sills, and dykes of the Strand Fiord Formation on Axel Heiberg Island, Nunavut, Canada. In contrast, a new U-Pb age for an alkaline syenite at Audhild Bay is significantly younger at 79.5 ± 0.5 Ma, and correlative to alkaline basalts and rhyolites from other locations of northern Ellesmere Island (Audhild Bay, Philips Inlet, and Yelverton Bay West; 83−73 Ma). We propose these volcanic occurrences be referred to collectively as the Audhild Bay alkaline suite (ABAS). In this revised nomenclature, the rocks of Hansen Point stratotype and other tholeiitic rocks are ascribed to the Hansen Point tholeiitic suite (HPTS) that was emplaced at 97−93 Ma. We suggest this subdivision into suites replace the collective term Hansen Point volcanic complex. The few dredge samples of alkali basalt available from the top of the Alpha Ridge are akin to ABAS in terms of geochemistry. Our revised dates also suggest that the HPTS and Strand Fiord Formation volcanic rocks may be the hypothesized subaerial large igneous province eruption that drove the Cretaceous Ocean Anoxic Event 2.


2021 ◽  
Author(s):  
Simona Regenspurg ◽  
Lioba Virchow ◽  
Franziska Wilke ◽  
Martin Zimmer ◽  
Egbert Joilie ◽  
...  

1997 ◽  
Vol 61 (407) ◽  
pp. 499-513 ◽  
Author(s):  
Tom Andersen

AbstractThe Qassiarsuk (formerly spelled Qagssiarssuk) complex is located in a roughly E–W trending graben structure between Qassiarsuk village and Tasiusaq settlement in the northern part of the Precambrian Gardar rift, South Greenland. The complex comprises a sequence of alkaline silicate tuffs and extrusive carbonatites interlayered with sandstones, and their subvolcanic equivalents, which represent possible feeders for the extrusive rocks. The Rb-Sr, Sm-Nd and Pb isotopic characteristics of 65 samples of extrusive carbonatite- and silicate tuffs and carbonatite diatremes have been determined by mass spectrometry. The Qassiarsuk complex can be dated to c. 1.2 Ga by Rb-Sr and Pb-Pb isochrons on whole-rocks and mineral separates, agreeing with previous isotopic ages for the volcanic rocks of the Eriksfjord formation in the Eriksfjord area of the Gardar rift, but not with previous, indirect age estimates of >1.31 Ga for assumed Eriksfjord equivalents in the Motzfeldt area further east. Recalculated isotopic compositions at 1.2 Ga indicate that the Qassiarsuk carbonatite- and alkaline-silicate magmas were comagmatic and derived from a depleted mantle source (εNd>4, εSr<−13, time-integrated, single- stage 238U/204Pb ≤ 7.4). The mantle-derived magmas were contaminated with crustal material, equivalent to the local, pre-Gardar granites and gneisses and sediments derived from these. The crustal component has a depleted mantle Nd model age of 2.1-2.6 Ga; at 1.2 Ga it was characterized by εSr = +76, εNd = −8.4, time-integrated, single- stage 238U/204Pb = 8.2−8.3. Strong decoupling of the Pb from the Sr and Nd isotopic systems suggests that the contamination happened only after carbonatitic and alkaline-silicate magmas had evolved from a common parent, by processes such as liquid immisicibility and/or fractional crystallization. Post-magmatic hydrothermal alteration (oxidation, hydration of mafic silicates, carbonatization of melilite) may have contributed further to the contamination of the carbonatite and alkaline silicate rocks of the Qassiarsuk complex.


2010 ◽  
Vol 74 (2) ◽  
pp. 351-363 ◽  
Author(s):  
R. Macdonald ◽  
N. W. Rogers ◽  
B. Bagiński ◽  
P. Dzierżanowski

AbstractGallium abundances, determined by laser ablation-inductively coupled plasma-mass spectrometry, are presented for phenocrysts and glassy matrices from a metaluminous trachyte and five peralkaline rhyolites from the Greater Olkaria Volcanic Complex, Kenya Rift Valley. Abundances in the glasses range from 28.9 to 33.3 ppm, comparable with peralkaline rhyolites elsewhere. Phenocryst Ga abundances (in ppm) are: sanidine 31.5–45.3; fayalite 0.02–0.22; hedenbergite 3.3–6.3; amphibole 12; biotite 72; ilmenite 0.56–0.72; titanomagnetite 32; chevkinite-(Ce) 364. The mafic phases and chevkinite-(Ce) are enriched in Ga relative to Al, whereas Ga/Al ratios in sanidine are smaller than in coexisting glass. Apparent partition coefficients range from <0.01 in fayalite to 12 in chevkinite-(Ce). Coefficients for hedenbergite, ilmenite and titanomagnetite decrease as melts become peralkaline. The sharp increase in Ga/Al in the more fractionated members of alkaline magmatic suites probably results from alkali feldspar-dominated fractionation. Case studies are presented to show that the Ga/Al ratio may be a sensitive indicator of such petrogenetic processes as magma mixing, interaction of melts with F-rich volatile phases, mineral accumulation and volatile-induced crustal anatexis.


2017 ◽  
Vol 36 (2) ◽  
pp. 197-244 ◽  
Author(s):  
Laura C. Walkup ◽  
Thomas J. Casadevall ◽  
Vincent L. Santucci

ABSTRACT Geologic features, particularly volcanic features, have been protected by the National Park Service since its inception. Some volcanic areas were nationally protected even before the National Park Service was established. The first national park, Yellowstone National Park, is one of the most widely known geothermal and volcanic areas in the world. It contains the largest volcanic complex in North America and has experienced three eruptions which rate among the largest eruptions known to have occurred on Earth. Half of the twelve areas established as national parks before the 1916 Organic Act which created the National Park Service are centered on volcanic features. The National Park Service now manages lands that contain nearly every conceivable volcanic resource, with at least seventy-six managed lands that contain volcanoes or volcanic rocks. Given that so many lands managed by the National Park Service contain volcanoes and volcanic rocks, we cannot give an overview of the history of each one; rather we highlight four notable examples of parks that were established on account of their volcanic landscapes. These parks all helped to encourage the creation and success of the National Park Service by inspiring the imagination of the public. In addition to preserving and providing access to the nation's volcanic heritage, volcanic national parks are magnificent places to study and understand volcanoes and volcanic landscapes in general. Scientists from around the world study volcanic hazards, volcanic history, and the inner working of the Earth within U.S. national parks. Volcanic landscapes and associated biomes that have been relatively unchanged by human and economic activities provide unique natural laboratories for understanding how volcanoes work, how we might predict eruptions and hazards, and how these volcanoes affect surrounding watersheds, flora, fauna, atmosphere, and populated areas.


1979 ◽  
Vol 116 (3) ◽  
pp. 181-190 ◽  
Author(s):  
M. Suárez

SummaryThe Hardy Formation, a sequence of Upper Mesozoic volcanic rocks exposed in Peninsula Hardy (Isla Hoste) in the southernmost archipelago of Chile represents, at least in part, the island-arc assemblage of an island-arc-marginal-basin system related to an eastward dipping subduction zone. This island arc was founded on South American continental crust and is also represented in the island of South Georgia 2000 km to the E. The island-arc assemblage includes pyroclastic rocks, characterized by a high proportion of vitric material, and lava intercalations ranging in composition from rhyolite to basalt. These rocks underwent zeolite and prehnite-pumpellyite facies metamorphism and are gently folded, in contrast with the intense folding exhibited by the rocks exposed to the north of Peninsula Hardy. Silicic volcanics assigned to this assemblage underlie pillow lavas, and are intruded by dolerites and gabbros probably related to a Late Jurassic-Early Cretaceous ophiolite magmatism associated with the generation of a quasioceanic marginal basin. Volcanic turbidites (Yahgan Formation) were deposited into the marginal basin.It is suggested that in pre-marginal basin times the Hardy Formation interfingered towards the Atlantic with the silicic volcanics of the Tobifera Formation. However, recent geochemical work on the Tobifera Formation suggest an origin by continental crust anatexis in a volcano-tectonic rift zone related to upper mantle diapirism, whereas an island arc origin is favoured for at least the andesitic and basaltic components of the Hardy Formation. Therefore, the geology of Peninsula Hardy as presented here, confirms early assumptions of the splitting apart of a Middle–Upper Jurassic volcanic terrain along the Pacific margin of South America during the generation of a marginal basin. The spreading axis of the latter seems to have been located at the boundary of two somewhat overlapping petrotectonic assemblages: and island arc on the Pacific side and a silicic volcano-tectonic rift zone towards the Atlantic. A probably Cenozoic volcanic complex discordantly overlies the Yahgan and Hardy formations.


2005 ◽  
Vol 17 (2) ◽  
pp. 259-266 ◽  
Author(s):  
JON STEPHENSON ◽  
G.M. BUDD ◽  
J. MANNING ◽  
P. HANSBRO

The McDonald Islands (53°S, 73°E) originally comprised three small islands that lie on the Kerguelen Plateau, 44 km west of Heard Island. No volcanic activity was observed since their discovery in 1874 until 1997, when two passing ships recorded major changes and eruptive behaviour. A 2001 satellite image showed that the main island had doubled its area. This paper reports observations made from a cruise ship in November 2002, supplemented by a high-resolution satellite image acquired in March 2003. A new volcanic complex comprises lava domes, spines and flows, all assumed to be phonolitic, similar to the older volcanic rocks. The complex shows dormant volcanic activity, with numerous fumaroles, recent spine evolution and lava flows. Changes in relative sea level have connected Flat and McDonald Islands. A spit about 1km long with extensive shoals beyond, now extends eastward from McDonald Island and presents new hazards to shipping. Biological changes include colonization by king penguins (Aptenodytes patagonica), previously absent, and a large reduction in numbers of formerly widespread macaroni penguins (Eudyptes chrysolophus chrysolophus).


2011 ◽  
Vol 8 (5) ◽  
pp. 8255-8289 ◽  
Author(s):  
G. Ghiglieri ◽  
D. Pittalis ◽  
G. Cerri ◽  
G. Oggiano

Abstract. The objective of this study is to analyze the geochemical conditions associated with the presence of fluoride (F−) in the groundwater of an area of Northern Tanzania. The studied aquifers are composed of volcanic rocks such as phonolitic and nephelinitic lavas, basalts, lahars of various ages and mantling ash. Sedimentary rocks consisting of fine-grained alluvial and lacustrine deposits occur as well. Samples collected from springs, borehole and surface water, during two monitoring surveys, were analyzed for the various physico-chemical and isotopic parameters. The geochemical composition of water is typically sodium bicarbonate. High values of F− (up to 68 mg l−1) were recorded. The highest values of fluoride agreed with the highest values of pH, sodium and bicarbonate. Dissolution of major ions, exchange processes and precipitation of Ca2+ from super-saturated solutions joined with the local permeability and hydraulic gradients, control the fluoride mobilization and the contamination of the area.


2021 ◽  
Author(s):  
Elisabeth Schnepp ◽  
Patrick Arneitz ◽  
Morgan Ganerød ◽  
Robert Scholger ◽  
Ingomar Fritz ◽  
...  

Abstract Pliocene volcanic rocks from South-East-Austria were paleomagnetically investigated. Samples were taken from 28 sites located on eight different volcanoes. Rock magnetic investigations revealed that magnetic carriers are Ti-rich or Ti-poor titanomagnetites with mainly pseudo-single-domain grain size. Characteristic remanent magnetization directions were obtained from alternating field as well as from thermal demagnetization. Four localities give reversed directions agreeing with the expected direction from secular variation. Another four localities of the Klöch-Königsberg volcanic complex (3) and the Neuhaus volcano (1) have reversed directions with shallow inclinations and declinations of about 240° while the locality Steinberg yields a positive inclination of about 30° and 200° declination. These aberrant directions cannot be explained by local or regional tectonic movements. All virtual geomagnetic pole positions are located on the southern hemisphere. Four virtual geomagnetic poles lie close to the geographic pole, while all others are concentrated in a narrow longitude sector offshore South America (310° to 355°) with low virtual geomagnetic pole latitudes ranging from − 15° to -70°. The hypothesis that a transitional geomagnetic field configuration was recorded during the short volcanic activity of these five localities is supported by 9 paleointensity results and 39Ar/40Ar dating. Virtual geomagnetic dipole moments range from 1.1 to 2.9·1022 Am2 for sites with low VGP latitudes about 60° and from 3.0 to 9.3·1022 Am2 for sites with higher virtual geomagnetic pole latitudes. The new 39Ar/40Ar ages of 2.51 ± 0.27 Ma for Klöch and 2.39 ± 0.03 Ma for Steinberg allow for the correlation of the Styrian transitional directions with cryptochron C2r.2r-1 of the geomagnetic polarity time scale.


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