Near net size sintering of porous cordierite ceramics with excellent properties

2020 ◽  
Vol 826 ◽  
pp. 154121
Author(s):  
Hao Li ◽  
Cuiwei Li ◽  
Linghao Wu ◽  
Han Wang ◽  
Junwen Li ◽  
...  
Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 496 ◽  
Author(s):  
Shaoxin Wang ◽  
Ziwei Chen ◽  
Beini He ◽  
Zheng Yan ◽  
Hao Wang ◽  
...  

A series of CeOx catalysts supported by commercial porous cordierite ceramics (CPCC) and synthesized porous cordierite ceramics (SPCC) from fly ash were prepared for selective catalytic reduction of NOx with ammonia (NH3-SCR). A greater than 90% NOx conversion rate was achieved by the SPCC supported catalyst at 250–300 °C when the concentration of loading precursor was 0.6 mol/L (denoted as 0.6Ce/SPCC), which is more advantageous than the CPCC supported ones. The EDS mapping results reveal the existence of evenly distributed impurities on the surface of SPCC, which hence might be able to provide more attachment sites for CeOx particles. Further measurements with temperature programmed reduction by hydrogen (H2-TPR) demonstrate more reducible species on the surface of 0.6Ce/SPCC, thus giving rise to better NH3-SCR performance at a low-temperature range. The X-ray photoelectron spectroscopy (XPS) analyses reveal that the Ce atom ratio is higher in 0.6Ce/SPCC, indicating that a higher concentration of catalytic active sites could be found on the surface of 0.6Ce/SPCC. The in situ diffused reflectance infrared fourier transform spectroscopy (DRIFTS) results indicate that the SCR reactions over 0.6Ce/SPCC follow both Eley-Rideal (E-R) and Langmuir-Hinshelwood (L-H) mechanisms. Hence, the SPCC might be a promising candidate to provide support for NH3-SCR catalysts, which also provide a valuable approach to recycling the fly ash.


2002 ◽  
Vol 50 (3) ◽  
pp. 597-604 ◽  
Author(s):  
K. Kaneko ◽  
N. Honbe ◽  
M. Matsumoto ◽  
Y. Yasutomi ◽  
T. Saitoh ◽  
...  

Author(s):  
T. A. Habas ◽  
T. V. Vakalova ◽  
K. S. Kamyshnaya ◽  
E. V. D'yakonova ◽  
A. L. Cherepanova ◽  
...  

The investigating results are given on the cordierite ceramic porous materials development. The wood waste and the crystalline carbamide were used as the pore-formers. The pore structure analysis showed that all samples had complex pore space composed of numerous elongated connected pores. The best pore formation factors were achieved when using the organic crystalline pore-former. It was demonstrated that nanodispersive metal alumina acted as the strengthening agent in course of the porous ceramics sintering. The organic clay suspension improves the cordierite powder's agglomeration capacity and gives rise to additional nano- and micro-pores.


1992 ◽  
Vol 100 (1157) ◽  
pp. 33-37 ◽  
Author(s):  
Hisao ABE ◽  
Hideya SEKI ◽  
Akio FUKUNAGA ◽  
Makoto EGASHIRA

2016 ◽  
Vol 42 (1) ◽  
pp. 734-742 ◽  
Author(s):  
Chuanbei Liu ◽  
Laibao Liu ◽  
Kefeng Tan ◽  
Lihua Zhang ◽  
Kaijing Tang ◽  
...  

2021 ◽  
Author(s):  
◽  
Māris Rundāns

This work is dedicated to the study of the development of porous cordierite ceramics using two types of illite clays as pore formers. The work has the structure of a classical scientific paper containing the following sections – introduction, literature review, description of materials and methods, presentation of results, and conclusions. The theoretical part of the Thesis describes cordierite as an important mineral phase, its polymorphism, as well as the production, properties and application of ceramics formed from this phase. The materials and methods section details the materials and methods used in the work. The practical part of the Thesis describes the production of cordierite ceramics and its physical-mechanical and thermal properties as well as the analysis of the structure of the obtained materials. It shows that by varying the technological parameters of synthesis different morphology porous cordierite ceramics can be obtained. The resulting materials are considered to be the most economically viable alternative to existing synthetic materials due to their improved material properties – bending and compression strength, thermal expansion coefficient and thermal conductivity.


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