Phase-engineering Strategy of ZrO2 for Enhancing the Mechanical Properties of Porous Cordierite Ceramics

2021 ◽  
pp. 103032
Author(s):  
Lulu Wang ◽  
Beiyue Ma ◽  
Xinming Ren ◽  
Chao Yu ◽  
Jialong Tian ◽  
...  
2018 ◽  
Vol 762 ◽  
pp. 300-305
Author(s):  
Maris Rundans ◽  
Gaida Sedmale ◽  
Aija Krūmiņa ◽  
Aiga Ivdre

Porous cordierite ceramic samples have been prepared by using 33% of two carbonate-containing illite clays as substitutes for the necessary synthetic ingredients. The changes of thermal (CTE) and mechanical properties (compressive strength, modulus of elasticity), as well as phase content, apparent porosity and bulk density have been investigated in regards to gradual changes in maximum sintering temperature. It can be affirmed that these properties strongly depend on the thermal parameters of sintering as well as slightly upon differences in chemical composition of composition substitutes.


2020 ◽  
Vol 826 ◽  
pp. 154121
Author(s):  
Hao Li ◽  
Cuiwei Li ◽  
Linghao Wu ◽  
Han Wang ◽  
Junwen Li ◽  
...  

2014 ◽  
Vol 40 (7) ◽  
pp. 8937-8944 ◽  
Author(s):  
A. Benhammou ◽  
Y. El Hafiane ◽  
A. Abourriche ◽  
Y. Abouliatim ◽  
L. Nibou ◽  
...  

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 496 ◽  
Author(s):  
Shaoxin Wang ◽  
Ziwei Chen ◽  
Beini He ◽  
Zheng Yan ◽  
Hao Wang ◽  
...  

A series of CeOx catalysts supported by commercial porous cordierite ceramics (CPCC) and synthesized porous cordierite ceramics (SPCC) from fly ash were prepared for selective catalytic reduction of NOx with ammonia (NH3-SCR). A greater than 90% NOx conversion rate was achieved by the SPCC supported catalyst at 250–300 °C when the concentration of loading precursor was 0.6 mol/L (denoted as 0.6Ce/SPCC), which is more advantageous than the CPCC supported ones. The EDS mapping results reveal the existence of evenly distributed impurities on the surface of SPCC, which hence might be able to provide more attachment sites for CeOx particles. Further measurements with temperature programmed reduction by hydrogen (H2-TPR) demonstrate more reducible species on the surface of 0.6Ce/SPCC, thus giving rise to better NH3-SCR performance at a low-temperature range. The X-ray photoelectron spectroscopy (XPS) analyses reveal that the Ce atom ratio is higher in 0.6Ce/SPCC, indicating that a higher concentration of catalytic active sites could be found on the surface of 0.6Ce/SPCC. The in situ diffused reflectance infrared fourier transform spectroscopy (DRIFTS) results indicate that the SCR reactions over 0.6Ce/SPCC follow both Eley-Rideal (E-R) and Langmuir-Hinshelwood (L-H) mechanisms. Hence, the SPCC might be a promising candidate to provide support for NH3-SCR catalysts, which also provide a valuable approach to recycling the fly ash.


2016 ◽  
Vol 690 ◽  
pp. 65-70 ◽  
Author(s):  
Santi Pongphot ◽  
Sakdiphon Thiansem

Mullite-cordierite ceramics was prepared by the three composition of talc, kaolin (kaolin from Naratiwas in Thailand) (NT) and alumina. The different amounts of alumina (5, 10, 15 and 20 wt%) were added to produce various mullite-cordierite alumina mixtures which are denoted as NA, NB, NC and ND, respectively. The mixtures were pressed into rectangular shapes by hydraulic press with the pressure of 150 kg/cm2 then sintered at temperature of 1300 °C and 1350 °C for 2 hours. The morphology of the synthesized mullite-cordierite samples were characterized by x-ray diffraction spectroscopy (XRD), and physical-mechanical properties were investigated. Mullite-cordierite was successfully synthesized. The XRD result was represented phases of mullite and cordierite. The NA samples sintered at temperature of 1300 °C indicated the best physical-mechanical properties including bulk density (2.23 g/cm3), flexural strength (44.4 MPa) and thermal expansion coefficients (5.00x10-6). The other NA samples sintered at temperature of 1350 °C exhibited the bulk density, flexural strength and thermal expansion coefficients are 2.21 g/cm3, 47.8 MPa and 4.99 x10-6, respectively. The thermal expansion coefficient of the NT sintered samples have been plotted the length change relative to measuring temperature ranging of 30-1200 °C. The suitable condition of the synthesized mullite-cordierite ceramics is finally obtained the NA samples with 5 percent weight of alumina composition sintered at the temperature of 1350 °C.


2018 ◽  
Vol 10 (446) ◽  
pp. eaaq1802 ◽  
Author(s):  
Natalia Vapniarsky ◽  
Le W. Huwe ◽  
Boaz Arzi ◽  
Meghan K. Houghton ◽  
Mark E. Wong ◽  
...  

Treatments for temporomandibular joint (TMJ) disc thinning and perforation, conditions prevalent in TMJ pathologies, are palliative but not reparative. To address this, scaffold-free tissue-engineered implants were created using allogeneic, passaged costal chondrocytes. A combination of compressive and bioactive stimulation regimens produced implants with mechanical properties akin to those of the native disc. Efficacy in repairing disc thinning was examined in minipigs. Compared to empty controls, treatment with tissue-engineered implants restored disc integrity by inducing 4.4 times more complete defect closure, formed 3.4-fold stiffer repair tissue, and promoted 3.2-fold stiffer intralaminar fusion. The osteoarthritis score (indicative of degenerative changes) of the untreated group was 3.0-fold of the implant-treated group. This tissue engineering strategy paves the way for developing tissue-engineered implants as clinical treatments for TMJ disc thinning.


2002 ◽  
Vol 50 (3) ◽  
pp. 597-604 ◽  
Author(s):  
K. Kaneko ◽  
N. Honbe ◽  
M. Matsumoto ◽  
Y. Yasutomi ◽  
T. Saitoh ◽  
...  

Author(s):  
T. A. Habas ◽  
T. V. Vakalova ◽  
K. S. Kamyshnaya ◽  
E. V. D'yakonova ◽  
A. L. Cherepanova ◽  
...  

The investigating results are given on the cordierite ceramic porous materials development. The wood waste and the crystalline carbamide were used as the pore-formers. The pore structure analysis showed that all samples had complex pore space composed of numerous elongated connected pores. The best pore formation factors were achieved when using the organic crystalline pore-former. It was demonstrated that nanodispersive metal alumina acted as the strengthening agent in course of the porous ceramics sintering. The organic clay suspension improves the cordierite powder's agglomeration capacity and gives rise to additional nano- and micro-pores.


1992 ◽  
Vol 100 (1157) ◽  
pp. 33-37 ◽  
Author(s):  
Hisao ABE ◽  
Hideya SEKI ◽  
Akio FUKUNAGA ◽  
Makoto EGASHIRA

Sign in / Sign up

Export Citation Format

Share Document