Influence of laser cladding parameters on distortion, thermal history and melt pool behaviour in multi-layer deposition of stellite 6: In-situ measurement

2020 ◽  
pp. 157894
Author(s):  
Nikhil Thawari ◽  
Chaitanya Gullipalli ◽  
Aayush Chandak ◽  
T.V.K. Gupta
Author(s):  
Ashish Kumar Nath ◽  
Muvvala Gopinath

Abstract Monitoring and controlling the microstructure, phases, and thermal stresses in laser cladding of materials which determine their mechanical properties is essential for ensuring repeatability and reproducibility in refurbishing engineering parts and building functional parts by layer-by-layer deposition in additive manufacturing process. Several studies have been reported on on-line monitoring of temperature, melt-pool geometry, and porosity etc. in laser powder deposition process, but only a few on the assessment of solidification morphology, microstructure, and thermal stresses. Since these features are dictated by the melt-pool lifetime, cooling and solidification rates, their effects on the evolution of microstructure and the state of ceramic particles in laser deposition of Ni-super alloy and metal matrix composites of WC and TiC are investigated in the current study. Good correlation exists between the thermal history monitored online and the solidification characteristics. Process maps based on the melt-pool lifetime as a function of laser cladding parameters for these materials are developed. On-line monitoring of thermal cycle is extended to laser welding of stainless steel and titanium which are difficult to join together due to the formation of brittle intermetallic phases, and laser polishing of thermal sprayed ceramic coating to develop a better understanding and control of these processes. Melt-pool lifetime is found to have significant effect on the crack growth in fusion welding and by optimizing the former the later could be mitigated. Similarly, the cooling rate in laser polishing of thermal sprayed ceramic coating is found to have significant influence on the surface roughness and residual stress. These studies show that the online monitoring of thermal history can be exploited for controlling the process quality and ensuring the repeatability and reproducibility in different laser material processing modalities.


2008 ◽  
Author(s):  
Ruiquan Kang ◽  
Mingxing Ma ◽  
Wenjin Liu ◽  
Minlin Zhong ◽  
Yide Kan ◽  
...  

2017 ◽  
Author(s):  
Younghee Lee ◽  
Daniela M. Piper ◽  
Andrew S. Cavanagh ◽  
Matthias J. Young ◽  
Se-Hee Lee ◽  
...  

<div>Atomic layer deposition (ALD) of LiF and lithium ion conducting (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloys was developed using trimethylaluminum, lithium hexamethyldisilazide (LiHMDS) and hydrogen fluoride derived from HF-pyridine solution. ALD of LiF was studied using in situ quartz crystal microbalance (QCM) and in situ quadrupole mass spectrometer (QMS) at reaction temperatures between 125°C and 250°C. A mass gain per cycle of 12 ng/(cm<sup>2</sup> cycle) was obtained from QCM measurements at 150°C and decreased at higher temperatures. QMS detected FSi(CH<sub>3</sub>)<sub>3</sub> as a reaction byproduct instead of HMDS at 150°C. LiF ALD showed self-limiting behavior. Ex situ measurements using X-ray reflectivity (XRR) and spectroscopic ellipsometry (SE) showed a growth rate of 0.5-0.6 Å/cycle, in good agreement with the in situ QCM measurements.</div><div>ALD of lithium ion conducting (AlF3)(LiF)x alloys was also demonstrated using in situ QCM and in situ QMS at reaction temperatures at 150°C A mass gain per sequence of 22 ng/(cm<sup>2</sup> cycle) was obtained from QCM measurements at 150°C. Ex situ measurements using XRR and SE showed a linear growth rate of 0.9 Å/sequence, in good agreement with the in situ QCM measurements. Stoichiometry between AlF<sub>3</sub> and LiF by QCM experiment was calculated to 1:2.8. XPS showed LiF film consist of lithium and fluorine. XPS also showed (AlF<sub>3</sub>)(LiF)x alloy consists of aluminum, lithium and fluorine. Carbon, oxygen, and nitrogen impurities were both below the detection limit of XPS. Grazing incidence X-ray diffraction (GIXRD) observed that LiF and (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film have crystalline structures. Inductively coupled plasma mass spectrometry (ICP-MS) and ionic chromatography revealed atomic ratio of Li:F=1:1.1 and Al:Li:F=1:2.7: 5.4 for (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film. These atomic ratios were consistent with the calculation from QCM experiments. Finally, lithium ion conductivity (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film was measured as σ = 7.5 × 10<sup>-6</sup> S/cm.</div>


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