scholarly journals The effectiveness of four organic matter amendments for decreasing resin-extractable Cr(VI) in Cr(VI)-contaminated soils

2009 ◽  
Vol 161 (2-3) ◽  
pp. 1239-1244 ◽  
Author(s):  
Chien-Chih Chiu ◽  
Chia-Jung Cheng ◽  
Tzu-Huei Lin ◽  
Kai-Wei Juang ◽  
Dar-Yuan Lee
Keyword(s):  
Organic Matter ◽  
Contaminated Soils

scholarly journals Fractionation of Heavy Metals in Multi-Contaminated Soil Treated with Biochar Using the Sequential Extraction Procedure

Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 448
Author(s):  
Mahrous Awad ◽  
Zhongzhen Liu ◽  
Milan Skalicky ◽  
Eldessoky S. Dessoky ◽  
Marian Brestic ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Ph ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Extraction Procedure ◽  
Sequential Fractionation ◽  
Relationship Of ◽  
The Relationship

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.

scholarly journals Relationship of soil properties to fractionation, bioavailability and mobility of lead and zinc in soil

2008 ◽  
Vol 53 (No. 5) ◽  
pp. 225-238 ◽  
Author(s):  
N. Finžgar ◽  
P. Tlustoš ◽  
D. Leštan
Keyword(s):  
Organic Matter ◽  
Regression Analysis ◽  
Soil Organic Matter ◽  
Soil Properties ◽  
Multiple Regression ◽  
Contaminated Soils ◽  
Organic Matter Content ◽  
Clay Content ◽  
Exchange Capacity ◽  
Matter Content

Sequential extractions, metal uptake by <i>Taraxacum officinale</i>, Ruby&rsquo;s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and 2nd order polynomial models indicated relationships between Pb and Zn contamination and soil properties, although of small significance (<i>P</i> < 0.05). Statistically highly significant correlations (<i>P</i> < 0.001) were obtained using multiple regression analysis. A correlation between soil cation exchange capacity (CEC) and soil organic matter and clay content was expected. The proportion of Pb in the PBET intestinal phase correlated with total soil Pb and Pb bound to soil oxides and the organic matter fraction. The leachable Pb, extracted with TCLP, correlated with the Pb bound to carbonates and soil organic matter content (<i>R</i><sup>2</sup> = 69%). No highly significant correlations (<i>P</i> < 0.001) for Zn with soil properties or Zn fractionation were obtained using multiple regression.

scholarly journals Trace elements, pH and organic matter evolution in contaminated soils under assisted natural remediation: A 4-year field study

2009 ◽  
Vol 162 (2-3) ◽  
pp. 931-938 ◽  
Author(s):  
E. Madejón ◽  
P. Madejón ◽  
P. Burgos ◽  
A. Pérez de Mora ◽  
F. Cabrera
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Field Study ◽  
Contaminated Soils ◽  
Natural Remediation

In situ immobilization of metals in contaminated or naturally metal-rich soils

2001 ◽  
Vol 9 (2) ◽  
pp. 81-97 ◽  
Author(s):  
B R Singh ◽  
L Oste
Keyword(s):  
Organic Matter ◽  
Contaminated Soils ◽  
Plant Uptake ◽  
Binding Capacity ◽  
Peat Soil ◽  
Cadmium Concentration ◽  
In Situ Immobilization ◽  
Soil Matrix ◽  
Alum Shale

The chemical behaviour of metals is primarily governed by their retention and release reactions of solute with the soil matrix. Liming increased the soil pH, resulting in increased adsorption of Zn, Cu, and Cd in soils, which in consequence decreased the concentration of easily soluble Cd fraction in the soils and the uptake of this metal by wheat (Triticum aestivum) and carrots (Daucus carota). Metal adsorption also depended on the presence of clay and organic matter, and thus the soils having highest amounts of clay (e.g., alum shale) and (or) organic matter (e.g., peat soil) showed the highest adsorption for these metals. Among the materials (Fe and Mn oxides and aluminosilicates) having high binding capacity for metals, the immobilizing capacity of birnessite (MnO2) was higher than that of other materials. Addition of synthetic zeolites significantly reduced the metal uptake by plants. Application of zeolite to a soil resulted in increased dissolved organic carbon (DOC) concentration in the leachate, which in consequence increased the leaching of Cd and Zn. Addition of beringite (an aluminosilicate) to a Zn-contaminated soil resulted in increased shoot length and leaf area of bean (Phaseolus vulgaris) and a significant reduction in Zn concentration in leaves (from 350 to 146 mg kg-1). Cadmium concentration in ryegrass and the concentrations of diethylenetriaminepentaacetic acid (DTPA)- extractable Cd, Cu, Ni, and Zn in the soil decreased significantly (P < 0.05) with increasing amounts of organic matter (peat soil and cow manure) added to soils. These effects were assumed to be related to immobilization of metals due to formation of insoluble metal--organic complexes and increased cation exchange capacity (CEC). An overview of the results showed that the products tested (lime, Fe/Mn-containing compounds, aluminosilicates, and organic matter products) can reduce the solubility and the plant uptake of metals but their immobilizing capacity is limited (sometimes through their side effects). Key words: aluminosilicates, contaminated soils, in situ immobilization, leaching, metal oxides, organic matter, plant uptake.

scholarly journals Determination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatography

2012 ◽  
Vol 66 (8) ◽  
Author(s):  
Paula Paíga ◽  
Lurdes Mendes ◽  
José Albergaria ◽  
Cristina Delerue-Matos
Keyword(s):  
Gas Chromatography ◽  
Organic Matter ◽  
Analytical Methods ◽  
Contaminated Soils ◽  
Petroleum Hydrocarbons ◽  
Organic Matter Content ◽  
Matter Content ◽  
Total Petroleum Hydrocarbons ◽  
Infrared Spectrometry ◽  
Ir Analysis

AbstractTotal petroleum hydrocarbons (TPH) are important environmental contaminants which are toxic to human and environmental receptors. Several analytical methods have been used to quantify TPH levels in contaminated soils, specifically through infrared spectrometry (IR) and gas chromatography (GC). Despite being two of the most used techniques, some issues remain that have been inadequately studied: a) applicability of both techniques to soils contaminated with two distinct types of fuel (petrol and diesel), b) influence of the soil natural organic matter content on the results achieved by various analytical methods, and c) evaluation of the performance of both techniques in analyses of soils with different levels of contamination (presumably non-contaminated and potentially contaminated). The main objectives of this work were to answer these questions and to provide more complete information about the potentials and limitations of GC and IR techniques. The results led us to the following conclusions: a) IR analysis of soils contaminated with petrol is not suitable due to volatilisation losses, b) there is a significant influence of organic matter in IR analysis, and c) both techniques demonstrated the capacity to accurately quantify TPH in soils, irrespective of their contamination levels.

scholarly journals Uptake of thallium from artificially contaminated soils by kale (Brassica oleracea L., var. acephala)

2011 ◽  
Vol 52 (No. 12) ◽  
pp. 544-549 ◽  
Author(s):  
J. Pavlíčková ◽  
J. Zbíral ◽  
M. Smatanová ◽  
P. Habarta ◽  
P. Houserová ◽  
...  
Keyword(s):  
Organic Matter ◽  
Brassica Oleracea ◽  
Contaminated Soils ◽  
Acid Soil ◽  
Organic Matter Content ◽  
Matter Content ◽  
First Year ◽  
The Third ◽  
Very High ◽  
Brassica Oleracea L

A pot experiment focused on the study of factors influencing thallium transfer from contaminated soils into kale (green cabbage, Brassica oleracea L. var. acephala, variety Winterbor F1) was evaluated. Three different types of topsoils with naturally low content of thallium (heavy, medium and medium-light soil) were used for pot experiments. The soils were contaminated with thallium sulfate to achieve five levels of contamination (0, 0.52, 2.10, 4.20 and 5.88 mg/kg). There were six replicates for each combination (90 pots in the experiment). The first part of the experiment started in the year of contamination (2001) and continued in 2003. The soil samples and the samples of kale (leaves and stalks were sampled separately) were collected and analysed. Kale was found to be able to accumulate Tl without any influence on yield. The highest thallium concentration was found in the leaves of kale in the first year of the experiment and reached 326 mg/kg dry matter. Bioaccumulation factor (Biological Absorption Coefficient &ndash; BAC) was found to be over 80 during the first year of the experiment. In the third year the BAC was around 3 for the soil with the highest pH and the highest organic matter content but as high as 15 for an acid soil with the lowest content of organic matter and the lowest Cation Exchange Capacity (CEC) of soils. The content of thallium in the leaves of kale was found to be 7 to 10 times higher than in the stalks in the third year. In the first year this ratio was up to 18. From these findings it can be concluded that the ability of some plants of Brassicacea family, that are planted as common vegetables, to accumulate thallium is very high and can be a serious danger for food chains. Neutral soils high in CEC and organic matter are able to bind thallium more effectively than poor acid soils and the transfer of Tl into plants from these soils is substantially lower. The uptake of Tl from contaminated soils into kale can be very high and without any negative effect on the plant growth. The transfer of Tl into kale decreases with the time necessary to reach the equilibrium between the added Tl and the soil (ageing of a sample).

Retention and plant availability of chromium in soils as affected by lime and organic matter amendments

Soil Research ◽  
2001 ◽  
Vol 39 (5) ◽  
pp. 1091 ◽  
Author(s):  
N. S. Bolan ◽  
S. Thiagarajan
Keyword(s):  
Organic Matter ◽  
Pinus Radiata ◽  
Contaminated Soils ◽  
Opposite Effect ◽  
Organic Amendment ◽  
Column Experiments ◽  
Fluidised Bed ◽  
Tannery Industry ◽  
Cr Concentration ◽  
Pinus Radiata Bark

Chromium is used as Cr(III) in the tannery industry and as Cr(VI) in the timber treatment industry. In this experiment, the effect of 2 liming materials [fluidised bed boiler ash (FBA) and lime] and an organic amendment (Pinus radiata bark) on the retention of Cr by 2 soils (Egmont and Tokomaru) was examined using both ‘batch’ and ‘column’ experiments. The effect of these amendments on the uptake of Cr from the Egmont soil, treated with various levels of Cr (0–3200 mg Cr/kg soil), was examined using sunflower (Helianthus annuus) plants. The transformation of Cr was examined by fractionation of Cr in soils. Addition of FBA and lime increased the retention of Cr(III), but had the opposite effect on the retention of Cr(VI). Addition of bark did not affect the retention of Cr(III), but it increased the retention of Cr(VI). Increasing additions of Cr increased Cr concentration in plants, resulting in decreased plant growth. The liming materials were found to be effective in reducing the phytotoxicity of Cr(III) and the Pinus radiata bark was effective for Cr(VI). In both Cr(III)- and Cr(VI)-contaminated soils, the concentrations of Cr were higher in the organic-bound, oxide-bound, and residual fractions than in the soluble and the exchangeable fractions. The concentrations of Cr in the soluble and the exchangeable fractions were higher in the Cr(VI)-contaminated than the Cr(III)-contaminated soil. Addition of the liming materials decreased the concentration of the soluble Cr(III) and bark decreased soluble Cr(VI) in soil. There was evidence for the reduction of Cr(VI) to Cr(III) in the bark-treated soils.

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