Removal of basic dye (methylene blue) from aqueous solution using zeolite synthesized from electrolytic manganese residue

2015 ◽  
Vol 23 ◽  
pp. 344-352 ◽  
Author(s):  
Changxin Li ◽  
Hong Zhong ◽  
Shuai Wang ◽  
Jianrong Xue ◽  
Zhenyu Zhang
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Basic Dye ◽  
Electrolytic Manganese ◽  
Electrolytic Manganese Residue

scholarly journals Synthesis of Zeolite from Carbothermal Reduction Electrolytic Manganese Residue for the Removal of Macrolide Antibiotics from Aqueous Solution

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2133 ◽  
Author(s):  
Xuli Li ◽  
Yue Zeng ◽  
Fangyuan Chen ◽  
Teng Wang ◽  
Yixin Li ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Carbothermal Reduction ◽  
Adsorption Process ◽  
Hydroxyl Group ◽  
Macrolide Antibiotics ◽  
Adsorption Sites ◽  
Electrolytic Manganese ◽  
Electrolytic Manganese Residue ◽  
Pseudo Second Order ◽  
The Fourier Transform

Zeolite analcime (EMANA) was synthesized through the hydrothermal method by using carbothermal reduction electrolytic manganese residue (CR-EMR). The structural properties of EMANA and CR-EMR were studied using various characterization techniques. After hydrothermal synthesis, the CR-EMR became super-microporous, and the surface area increased by 4.76 times than before. Among the various synthesized zeolites, 6 h-synthesized EMANA was selected as the best adsorbent for macrolide antibiotics in aqueous solution. The adsorption performance of EMANA on the adsorption capacity was examined by using various experimental parameters, such as contact time (0–24 h), initial concentration (50–300 mg/L), temperature (30–50 °C) and pH (3–13). The experimental results were also analyzed by the Langmuir and Freundlich adsorption models, with the latter obtaining better representation. The adsorption process could be described well by the pseudo-second-order model, even under a low concentration (50 mg/L). This result suggests that the adsorption process of macrolide antibiotics is due to chemisorption. According to the Fourier Transform infrared spectroscopy (FT-IR) results, the adsorption of zeolite was mainly due to its hydroxyl group, which played an important role during the adsorption process. Moreover, EMANA is more suitable for treatment of roxithromycin (ROX) than azithromycin (AZM), because ROX has more adsorption sites for the hydroxyl group.

Application of annealed red mud to Mn2+ ion adsorption from aqueous solution

2016 ◽  
Vol 73 (11) ◽  
pp. 2761-2771 ◽  
Author(s):  
Hongliang Chen ◽  
Juan Zheng ◽  
Zhongqiong Zhang ◽  
Qian Long ◽  
Qiuyun Zhang
Keyword(s):  
Aqueous Solution ◽  
Red Mud ◽  
Freundlich Isotherm ◽  
Physicochemical Characteristics ◽  
Point Of Zero Charge ◽  
Maximum Adsorption Capacity ◽  
Adsorption Effect ◽  
Electrolytic Manganese ◽  
Electrolytic Manganese Residue ◽  
Initial Ph

Physicochemical characteristics and Mn2+ adsorption of annealed red mud were investigated in this study. The annealing temperature (105–900 °C) changed the mineralogical components and the point of zero charge of red mud. By comparison, annealed red mud at 700 °C (ARM700) had a better adsorption effect than other annealed samples, associated with the activated components of available Fe2O3, Al2O3, SiO2 and Na5Al3(SiO4)3CO3 (natrodavyne). The removal efficiency of Mn2+ by ARM700 was dependent on initial pH, contact time, and initial Mn2+ concentration of aqueous solution and was ∼56.5% with initial Mn2+ concentration 385 mg/L at initial pH > 5. The kinetics process was predicted better by the pseudo-second-order model. The Langmuir isotherm displayed a better fitting model than the Freundlich isotherm and the Mn2+ maximum adsorption capacity of ARM700 was 88.3 mg/g. The competing effects of Cu2+ and Zn2+ on Mn2+ removal were most obvious. There was efficient Mn2+ removal at the application of ARM700 to the leachate of electrolytic manganese residue.

scholarly journals Cauliflower Leave, an Agricultural Waste Biomass Adsorbent, and Its Application for the Removal of MB Dye from Aqueous Solution: Equilibrium, Kinetics, and Thermodynamic Studies

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Seraj Anwar Ansari ◽  
Fauzia Khan ◽  
Anees Ahmad
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Methylene Blue ◽  
Agricultural Waste ◽  
Second Order ◽  
Batch Adsorption ◽  
Agricultural Crop ◽  
Order Kinetic ◽  
Basic Dye ◽  
Pseudo Second Order

Cauliflower leaf powder (CLP), a biosorbent prepared from seasonal agricultural crop waste material, has been employed as a prospective adsorbent for the removal of a basic dye, methylene blue (MB) from aqueous solution by the batch adsorption method under varying conditions, namely, initial dye concentration, adsorbent dose, solution pH, and temperature. Characterization of the material by FTIR and SEM indicates the presence of functional groups and rough coarse surface suitable for the adsorption of methylene blue over it. Efforts were made to fit the isotherm data using Langmuir, Freundlich, and Temkin equation. The experimental data were best described by Freundlich isotherm model, with an adsorption capacity of 149.22 mg/g at room temperature. To evaluate the rate of methylene blue adsorption onto CLP, pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were employed. The experimental data were best described by the pseudo-second-order kinetic model. Evaluation of thermodynamic parameters such as changes in enthalpy, entropy, and Gibbs’ free energy showed the feasible, spontaneous, and exothermic nature of the adsorption process. On the basis of experimental results obtained, it may be concluded that the CLP prepared from agricultural waste has considerable potential as low-cost adsorbent in wastewater treatment for the removal of basic dye, MB.

Using of modified-bentonite as low-cost sorbent for removal of methylene blue dye from aqueous solution

2020 ◽  
Vol 27 (2) ◽  
pp. 45-54
Author(s):  
Saraa Muwafaq Ibrahim ◽  
Ziad T. Abd Ali
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Silanol Group ◽  
Infrared Spectrometry ◽  
Blue Dye ◽  
Ammonium Bromide ◽  
Vibration Band ◽  
Order Kinetic ◽  
Methylene Blue Dye ◽  
Modified Bentonite

Batch experiments have been studied to remove methylene blue dye (MB) from aqueous solution using modified bentonite. The modified bentonite was synthesized by replacing exchangeable calcium cations in natural bentonite with cationic surfactant cetyl trimethyl ammonium bromide (CTAB). The characteristics of modified bentonite were studied using different analysis such as Scanning electronic microscopy (SEM), Fourier transform infrared spectrometry (FTIR) and surface area. Where SEM shows the natural bentonite has a porous structure, a rough and uneven appearance with scattered and different block structure sizes, while the modified bentonite surface morphology was smooth and supplemented by a limited number of holes. On other hand, (FTIR) analysis that proved NH group aliphatic and aromatic group of MB and silanol group are responsible for the sorption of contaminate. The organic matter peaks at 2848 and 2930 cm-1 in the spectra of modified bentonite which are sharper than those of the natural bentonite were assigned to the CH2 scissor vibration band and the symmetrical CH3 stretching absorption band, respectively, also the 2930 cm-1 peak is assigned to CH stretching band. The batch study was provided the maximum removal efficiency (99.99 % MB) with a sorption capacity of 129.87 mg/g at specified conditions (100 mg/L, 25℃, pH 11 and 250rpm). The sorption isotherm data fitted well with the Freundlich isotherm model. The kinetic studies were revealed that the sorption follows a pseudo-second-order kinetic model which indicates chemisorption between sorbent and sorbate molecules.

Pattern Formation in the Methylene Blue-Fructose-Oxygen System in Aqueous Solution and in Gel Systems

2000 ◽  
Vol 65 (9) ◽  
pp. 1394-1402 ◽  
Author(s):  
Ľubica Adamčíková ◽  
Mária Hupková ◽  
Peter Ševčík
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Pattern Formation ◽  
Alkaline Ph ◽  
Initial Reactant ◽  
Nonlinear Reaction ◽  
Oxygen System ◽  
Hydrodynamic Processes ◽  
Liquid Layer Thickness ◽  
Catalyzed Oxidation

Spatial patterns in methylene blue-catalyzed oxidation of fructose at alkaline pH were found in aqueous solution and in gel systems. In a thin liquid layer (thickness >2.4 mm) a mixture of spots and stripes was formed by interaction of a nonlinear reaction and the Rayleigh or Maragoni instabilities. The pattern formation was affected by initial reactant concentrations and by the thickness of the reaction mixture layer. Long-lasting structures were formed in gel systems (polyacrylamide, agar, gelatin). These patterns also arise primarily from hydrodynamic processes.

Bioleaching behaviors of silicon and metals in electrolytic manganese residue using silicate bacteria

2019 ◽  
Vol 228 ◽  
pp. 901-909 ◽  
Author(s):  
Ying Lv ◽  
Jia Li ◽  
Hengpeng Ye ◽  
Dongyun Du ◽  
Jiaxin Li ◽  
...  
Keyword(s):  
Electrolytic Manganese ◽  
Electrolytic Manganese Residue ◽  
Silicate Bacteria

scholarly journals Sulfobetaine Cryogels for Preferential Adsorption of Methyl Orange from Mixed Dye Solutions

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 208
Author(s):  
Ramona B. J. Ihlenburg ◽  
Anne-Catherine Lehnen ◽  
Joachim Koetz ◽  
Andreas Taubert
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Methyl Orange ◽  
Dye Removal ◽  
Selective Adsorption ◽  
Water Soluble ◽  
Organic Substances ◽  
Preferential Adsorption ◽  
Dimethyl Ammonium ◽  
Dye Solutions

New cryogels for selective dye removal from aqueous solution were prepared by free radical polymerization from the highly water-soluble crosslinker N,N,N’,N’-tetramethyl-N,N’-bis(2-ethylmethacrylate)-propyl-1,3-diammonium dibromide and the sulfobetaine monomer 2-(N-3-sulfopropyl-N,N-dimethyl ammonium)ethyl methacrylate. The resulting white and opaque cryogels have micrometer sized pores with a smaller substructure. They adsorb methyl orange (MO) but not methylene blue (MB) from aqueous solution. Mixtures of MO and MB can be separated through selective adsorption of the MO to the cryogels while the MB remains in solution. The resulting cryogels are thus candidates for the removal of hazardous organic substances, as exemplified by MO and MB, from water. Clearly, it is possible that the cryogels are also potentially interesting for removal of other compounds such as pharmaceuticals or pesticides, but this must be investigated further.

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