Fabrication of a highly stretchable and electrically conductive silicone-embedded composite textile through optimization of the thermal curing process

Author(s):  
Jongil An ◽  
Soyern Kim ◽  
Jin-Wook Choi ◽  
Jisung Park ◽  
Seung-Rak Son ◽  
...  
1992 ◽  
Vol 264 ◽  
Author(s):  
Robert T. Roginski ◽  
Douglas E. Fjare

AbstractThe thermal curing chemistry of a fluorinated polyamic acid based on 6FDA (hexafluoroisopropylidene bis(phthalic anhydride)) and APBP (4,4′-bis(4-aminophenoxy)biphenyl) was studied by thermal-IR spectroscopy. Anhydride formation was observed at intermediate cure temperatures and maximized at approximately 220°C. The degree of anhydride formation was affected by the solvent, being least in 2-methoxyethyl ether and increasing in the solvent order: 2-methoxyethyl ether < NMP < 2-(2-ethoxy)ethoxyethanol. In addition to the back reaction of amic acid to anhydride and amine, at least one additional mechanism of anhydride formation is observed. The onset of the second mechanism of anhydride formation is coincident with the onset of imidization, which leads us to propose that water generated by imidization can react with anhydride during the curing process, before escaping from the film, to form diacid. Cyclization of diacid to anhydride is proposed as the second mechanism of anhydride formation.


2016 ◽  
Vol 29 (2) ◽  
pp. 187-196 ◽  
Author(s):  
Lang Ma ◽  
Guojian Wang ◽  
Jinfeng Dai

Graphene oxide/polyimide (GO/PI) composites with different loadings of GO were prepared by in situ polymerization and solution blending method. By adding GO, the mechanical, electrical, and thermal properties of composites could be improved. The tensile strength of GO/PI composite with 3.0 wt% GO loading was up to 137.8 MPa, 75.5% higher than that of a pure PI. Besides, the electrical and the thermal conductivities increased with the increase of GO contents. An electrical conductivity value of 5.38 × 10−5 S m−1 and a thermal conductivity value of 0.10 W m−1 K−1 for GO/PI composites prepared via in situ polymerization at GO content of 3.0 wt% were achieved. The results indicated that in situ polymerization was able to make GO a better dispersion in the polymer matrix. Furthermore, the behavior of GO under the thermal imidization temperature was also discussed. The experimental results showed that GO could be partially reduced to graphene during the thermal curing process. Above works are conducive to the understanding of the effect and transformation of GO in the preparation process of graphene-based composites.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 590
Author(s):  
Henriette Probst ◽  
Konrad Katzer ◽  
Andreas Nocke ◽  
Rico Hickmann ◽  
Martina Zimmermann ◽  
...  

Electrically conductive fibers are required for various applications in modern textile technology, e.g., the manufacturing of smart textiles and fiber composite systems with textile-based sensor and actuator systems. According to the state of the art, fine copper wires, carbon rovings, or metallized filament yarns, which offer very good electrical conductivity but low mechanical elongation capabilities, are primarily used for this purpose. However, for applications requiring highly flexible textile structures, as, for example, in the case of wearable smart textiles and fiber elastomer composites, the development of electrically conductive, elastic yarns is of great importance. Therefore, highly stretchable thermoplastic polyurethane (TPU) was compounded with electrically conductive carbon nanotubes (CNTs) and subsequently melt spun. The melt spinning technology had to be modified for the processing of highly viscous TPU–CNT compounds with fill levels of up to 6 wt.% CNT. The optimal configuration was achieved at a CNT content of 5 wt.%, providing an electrical resistance of 110 Ωcm and an elongation at break of 400%.


2018 ◽  
Vol 20 (26) ◽  
pp. 17999-18008
Author(s):  
Geoffrey Rivers ◽  
Pearl Lee-Sullivan ◽  
Boxin Zhao

Using silver nanobelts and microflakes in epoxy matrix, we sought to investigate the relationship between the evolving electrical resistivity of formulations of hybrid nanocomposites during the curing process, finding vitrification and interface compatibility play major roles.


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