Modelling the Plant Uptake of Metals from Release Rates Obtained by the EUF Method

In this study, soil dissolution kinetics were evaluated to predict the metal uptake of lettuce plants under varying conditions of fertilisation and metal pollution. Velocities and time dependencies of soil dissolution obtained by electro-ultrafiltration (EUF), which prevents back reaction, were modelled in three ways, obtained from suspensions in 0.002 M DTPA at determined soil pH levels, for cases in which sampling versus time led to decreasing concentrations. The models yielded a maximum achievable concentration, a timespan needed for it to be reached, a slope, and an intercept of the respective fitted curves. Three geogenically metalliferous soil samples and one ambient soil sample, both as originals, fertilised with PK or soaked with a Cd-Ni-Pb solution, were used as solid samples. The resulting kinetic parameters were correlated with the amounts absorbed by lettuce plants grown with these substrates in pot experiments, which yielded fairly good correlations with Zn, but also with Li and Sr, as well as Ni and Pb, mainly because of differences due to the addition of a metallic salt solution. Plant growth was hardly influenced by the additions.

Spherical gravitational waves and quasi-spherical waves scattered from black string in massive gravity

Spherical gravitational wave is strictly forbidden in vacuum space in frame of general relativity by the Birkhoff theorem. We prove that spherical gravitational waves do exist in non-linear massive gravity, and find the exact solution with a special singular reference metric. Further more, we find exact gravitational wave solution with a singular string by meticulous studies of familiar equation, in which the horizon becomes non-compact. We analyze the properties of the congruence of graviton rays of these wave solution. We clarify subtle points of dispersion relation, velocity and mass of graviton in massive gravity with linear perturbations. We find that the graviton ray can be null in massive gravity by considering full back reaction of the massive gravitational waves to the metric. We demonstrate that massive gravity has deep and fundamental discrepancy from general relativity, for whatever a tiny mass of the graviton.

Kinetics of V5+/V4+ Redox Reaction – Butler-Volmer and Marcus Models

Kinetics of the V5+/V4+ redox reaction on Vulcan XC-72 modified glassy carbon disk electrode is investigated in a three-electrode configuration. Cyclic voltammograms of V5+/V4+ redox couple suggest that the overpotential range for the kinetic analysis is limited to ±300 mV, after excluding V4+/V3+ redox reaction at the negative overpotential and the oxygen evolution reaction at the positive overpotential. Therefore, the linear sweep-voltammograms (LSVs) are corrected for potential drop due to solution resistance (iRs), mass-transfer resistance, and most importantly, for the back reaction current. These corrections are imperative to estimate the Tafel slope in the limited range of overpotential for V5+/V4+ redox reaction. The charge-transfer coefficient (α) estimated from the Tafel slope deviates significantly from the expected value of 0.5 for the single electron-transfer reaction. Moreover, the instantaneous slope of the Tafel plot suggests that the α is overpotential dependent. Therefore, Marcus theory of electrochemical kinetics is applied to estimate the α. The reorganization energy (λ) calculated from the Arrhenius plots is in the range of values reported in the literature for the other redox couples.

Structural dynamics in the water and proton channels of photosystem II during the S2 to S3 transition

Light-driven oxidation of water to molecular oxygen is catalyzed by the oxygen-evolving complex (OEC) in Photosystem II (PS II). This multi-electron, multi-proton catalysis requires the transport of two water molecules to and four protons from the OEC. A high-resolution 1.89 Å structure obtained by averaging all the S states and refining the data of various time points during the S2 to S3 transition has provided better visualization of the potential pathways for substrate water insertion and proton release. Our results indicate that the O1 channel is the likely water intake pathway, and the Cl1 channel is the likely proton release pathway based on the structural rearrangements of water molecules and amino acid side chains along these channels. In particular in the Cl1 channel, we suggest that residue D1-E65 serves as a gate for proton transport by minimizing the back reaction. The results show that the water oxidation reaction at the OEC is well coordinated with the amino acid side chains and the H-bonding network over the entire length of the channels, which is essential in shuttling substrate waters and protons.

The solar corona as an active medium for magnetoacoustic waves

The presence and interplay of continuous cooling and heating processes maintaining the corona of the Sun at the observed one million K temperature were recently understood to have crucial effects on the dynamics and stability of magnetoacoustic waves. These essentially compressive waves perturb the coronal thermal equilibrium, leading to the phenomenon of a wave-induced thermal misbalance. Representing an additional natural mechanism for the exchange of energy between the plasma and the wave, thermal misbalance makes the corona an active medium for magnetoacoustic waves, so that the wave can not only lose but also gain energy from the coronal heating source (similarly to burning gases, lasers and masers). We review recent achievements in this newly emerging research field, focussing on the effects that slow-mode magnetoacoustic waves experience as a back-reaction of this perturbed coronal thermal equilibrium. The new effects include enhanced frequency-dependent damping or amplification of slow waves, and effective, not associated with the coronal plasma non-uniformity, dispersion. We also discuss the possibility to probe the unknown coronal heating function by observations of slow waves and linear theory of thermal instabilities. The manifold of the new properties that slow waves acquire from a thermodynamically active nature of the solar corona indicate a clear need for accounting for the effects of combined coronal heating/cooling processes not only for traditional problems of the formation and evolution of prominences and coronal rain, but also for an adequate modelling and interpretation of magnetohydrodynamic waves.

Time-independence of gravitational Rényi entropies and unitarity in quantum gravity

The Hubeny-Rangamani-Takayanagi surface γHRT computing the entropy S(D) of a domain of dependence D on an asymptotically AdS boundary is known to be causally inaccessible from D. We generalize this gravitational result to higher replica numbers n > 1 by considering the replica-invariant surfaces (aka ‘splitting surfaces’) γ of real-time replica-wormhole saddle-points computing Rényi entropies Sn(D) and showing that there is a sense in which D must again be causally inaccessible from γ when the saddle preserves both replica and conjugation symmetry. This property turns out to imply the Sn(D) to be independent of any choice of any Cauchy surface ΣD for D, and also that the Sn(D) are independent of the choice of boundary sources within D. This is a key hallmark of unitary evolution in any dual field theory. Furthermore, from the bulk point of view it adds to the evidence that time evolution of asymptotic observables in quantum gravity is implemented by a unitary operator in each baby universe superselection sector. Though we focus here on pure Einstein-Hilbert gravity and its Kaluza-Klein reductions, we expect the argument to extend to any two-derivative theory who satisfies the null convergence condition. We consider both classical saddles and the effect of back-reaction from quantum corrections.

Frequent, Short Physical Activity Breaks Reduce Prefrontal Cortex Activation but Preserve Working Memory in Middle-Aged Adults: ABBaH Study

Prolonged sitting is increasingly common and may possibly be unfavorable for cognitive function and mood. In this randomized crossover study, the effects of frequent, short physical activity breaks during prolonged sitting on cognitive task-related activation of the prefrontal cortex were investigated. The effects on working memory, psychological factors, and blood glucose were also examined, and whether arterial stiffness moderated prefrontal cortex activation. Thirteen subjects (mean age 50.5 years; eight men) underwent three 3-h sitting conditions, interrupted every 30-min by a different 3-min break on separate, randomized-ordered days: seated social interactions (SOCIAL), walking (WALK), or simple resistance activities (SRA). Arterial stiffness was assessed at baseline. Before and after each 3-h condition, psychological factors (stress, mood, sleepiness, and alertness) were assessed through questionnaires and functional near-infrared spectroscopy (fNIRS) was used to measure changes in prefrontal oxygenated hemoglobin (Oxy-Hb), indicative of cortical activation, while performing working memory tasks [1- (baseline), 2-, and 3-back]. Blood glucose levels were continuously measured throughout the conditions. Results revealed no significant changes in Oxy-Hb during the 2-back compared with the 1-back test in any condition, and no time-by-condition interactions. During the 3-back test, there was a significant decrease in Oxy-Hb compared with the 1-back after the WALK condition in the right prefrontal cortex, but there were no time-by-condition interactions, although 3-back reaction time improved only in the WALK condition. Mood and alertness improved after the WALK condition, which was significantly different from the SOCIAL condition. Arterial stiffness moderated the effects, such that changes in Oxy-Hb were significantly different between WALK and SOCIAL conditions only among those with low arterial stiffness. Blood glucose during the interventions did not differ between conditions. Thus, breaking up prolonged sitting with frequent, short physical activity breaks may reduce right prefrontal cortex activation, with improvements in some aspects of working memory, mood, and alertness.Clinical Trial Registration:www.ClinicalTrials.gov, identifier NCT04137211.

Comparison of the mean field and Bohmian semi-classical approximations to the Rabi model

Bohmian mechanics is an alternative to standard quantum mechanics that does not suffer from the measurement problem. While it agrees with standard quantum mechanics concerning its experimental predictions, it offers novel types of approximations not suggested by the latter. Of particular interest are semi-classical approximations, where part of the system is treated classically. Bohmian semi-classical approximations have been explored before for systems without electromagnetic interactions. Here, the Rabi model is considered as a simple model involving light-matter interaction. This model describes a single mode electromagnetic field interacting with a two-level atom. As is well-known, the quantum treatment and the semi-classical treatment (where the field is treated classically rather than quantum mechanically) give qualitatively different results. We analyze the Rabi model using a different semi-classical approximation based on Bohmian mechanics. In this approximation, the back-reaction from the two-level atom onto the classical field is mediated by the Bohmian configuration of the two-level atom. We find that the Bohmian semi-classical approximation gives results comparable to the usual mean field one for the transition between ground and first excited state. Both semi-classical approximations tend to reproduce the collapse of the population inversion, but fail to reproduce the revival, which is characteristic of the full quantum description. Also an example of a higher excited state is presented where the Bohmian approximation does not perform so well.

Hemodynamic Analysis of the Prefrontal Cortex to Verify the Relationship Between Athlete Performance Level and Auditory-Spatial Working Memory: A Functional Near-Infrared Spectroscopy Study

PURPOSE: The purpose of this study was to investigate the difference between the performance level and working memory of athletes through behavioral response measurements and hemodynamic measurements of the prefrontal cortex.METHODS: The study included 12 higher-level athletes, 12 athletes, and 12 non-athletes. The study task was to perform auditory-spatial working memory tasks according to difficulty (1 back, 2 back). Reaction times and hemodynamic changes in the cerebral prefrontal cortex were measured using the NIRSIT instrument during task performance.RESULTS: Behavioral response measurements of the superior players showed faster reaction times in the 1-back and 2-back tasks compared to the other two groups, and the functional connectivity of the cerebral prefrontal cortex showed strong activation in the 2-back task.CONCLUSIONS: In the case of higher-level athletes, it is suggested that working memory ability and motor performance are significant, and that working memory ability can be an important variable in sports situations.

Constraints in inflationary magnetogenesis

We discuss popular models of inflationary and early post-inflationary magnetogenesis and present model-independent upper bounds on the strength of the resulting magnetic fields imposed by the considerations of weak coupling, back-reaction and Schwinger effect.