Alkali Leaching and Mechanical Performance of Epoxy Resin-Reinforced Geopolymer Composite

2021 ◽  
pp. 130663
Author(s):  
Apriany Saludung ◽  
Takumu Azeyanagi ◽  
Yuko Ogawa ◽  
Kenji Kawai
2021 ◽  
Vol 5 (7) ◽  
pp. 191
Author(s):  
Yanshuai Wang ◽  
Siyao Guo ◽  
Biqin Dong ◽  
Feng Xing

The functionalization of graphene has been reported widely, showing special physical and chemical properties. However, due to the lack of surface functional groups, the poor dispersibility of graphene in solvents strongly limits its engineering applications. This paper develops a novel green “in-situ titania intercalation” method to prepare a highly dispersed graphene, which is enabled by the generation of the titania precursor between the layer of graphene at room temperature to yield titania-graphene nanocomposites (TiO2-RGO). The precursor of titania will produce amounts of nano titania between the graphene interlayers, which can effectively resist the interfacial van der Waals force of the interlamination in graphene for improved dispersion state. Such highly dispersed TiO2-RGO nanocomposites were used to modify epoxy resin. Surprisingly, significant enhancement of the mechanical performance of epoxy resin was observed when incorporating the titania-graphene nanocomposites, especially the improvements in tensile strength and elongation at break, with 75.54% and 176.61% increases at optimal usage compared to the pure epoxy, respectively. The approach presented herein is easy and economical for industry production, which can be potentially applied to the research of high mechanical property graphene/epoxy composite system.


2018 ◽  
Vol 33 ◽  
pp. 02075 ◽  
Author(s):  
Tatyana Matseevich

The theme of the research is important because it allows to use hybrid materials as finishing in the high-rise constructions. The aim of the study was the development of producing coloured hybrid materials based on liquid glass, a polyisocyanate, epoxy resin and 2.4-toluylenediisocyanate. The detailed study of the process of stress relaxation at different temperatures in the range of 20-100°C was provided. The study found that the obtained materials are subject to the simplified technology. The materials easy to turn different colors, and dyes (e.g. Sudan blue G) are the catalysts for the curing process of the polymeric precursors. The materials have improved mechanical relaxation properties, possess different color and presentable, can be easily combined with inorganic base (concrete, metal). The limit of compressive strength varies from 32 to 17.5 MPa at a temperature of 20 to 100°C. The values σ∞ are from 20.4 to 7.7 MPa within the temperature range from 20 to 100°C. The physical parameters of materials were evaluated basing on the data of stress relaxation: the initial stress σ0, which occurs at the end of the deformation to a predetermined value; quasi-equilibrium stress σ∞, which persists for a long time relaxation process. Obtained master curves provide prediction relaxation behavior for large durations of relaxation. The study obtained new results. So, the addition of epoxy resin in the composition of the precursor improves the properties of hybrid materials. By the method of IR spectroscopy identified chemical transformations in the course of obtaining the hybrid material. Evaluated mechanical performance of these materials is long-time. Applied modern physically-based memory functions, which perfectly describe the stress relaxation process.


2020 ◽  
pp. 073490412093408
Author(s):  
Wei Yan ◽  
Pu Xie ◽  
Zhengwei Yang ◽  
Guangjin Luo ◽  
Weijiang Huang ◽  
...  

Aluminum phosphates coated sepiolite nanocomposite was fabricated via a simple one-pot heterogeneous precipitation strategy, and the effects of aluminum phosphates on the morphology of aluminum phosphates coated sepiolite were investigated. Moreover, the effect of aluminum phosphates coated sepiolite on the flame-retardant behavior, mechanical properties, and thermal stability of epoxy resin have been discussed. The results indicated that the introduction of only 20 wt% aluminum phosphates coated sepiolite in epoxy resin increased the limited oxygen index from 21.8% to 30.1%, thus the material met the UL-94 V-0 rating. Thermogravimetric analyses revealed that char yield increased in the presence of aluminum phosphates coated sepiolite form thermally stable carbonaceous char. Aluminum phosphates–coated sepiolite could improve the mechanical performance, thermal stability of epoxy resin.


2018 ◽  
Vol 27 (2) ◽  
pp. 66-75 ◽  
Author(s):  
Francisco Maciel Monticeli ◽  
David Daou ◽  
Mirko Dinulović ◽  
Herman Jacobus Cornelis Voorwald ◽  
Maria Odila Hilário Cioffi

Considering aeronautics requirements, academies and industries are developing matrixes and reinforcements with higher mechanical performance. The same occurs with the process where new studies focus on obtaining composites with suitable matrix/reinforcement interface. The use of epoxy resin and carbon fiber with high mechanical performance does not guarantee a composite with high mechanical properties, considering imperfections and void formation along the laminate in case of inappropriate processing parameters. The aim of this article was to analyze and quantify the mechanical behavior of polymer composite reinforced with continuous fibers using finite element methodology and postprocessing software simulation. In addition, the classical laminate theory and finite elements were used to simulate flexural and tensile tests of composite specimens. Simulation results were compared with experimental test results using a carbon fiber noncrimp fabric quadriaxial/epoxy resin composite processed by resin transfer molding. Although void volume fraction for structural materials presenting results under aeronautics requirements regarding of 2%, imperfections like lack of resin and impregnation discontinuity showed an influence in tensile and flexural experimental results. Experimental mechanical behavior decreased 10% of strength, in comparison with simulation results due to imperfection on impregnation measured by C-Scan map. Improvement in processing procedures could able to provide greater impregnation continuity, reducing defect formation and ensuring better matrix/reinforcement interface. As a final conclusion, the process plays a role as important as the characteristics of reinforcement and matrix and, consequently, the mechanical properties.


2017 ◽  
Vol 30 (10) ◽  
pp. 1159-1168 ◽  
Author(s):  
Animesh Sinha ◽  
Nazrul Islam Khan ◽  
Subhankar Das ◽  
Jiawei Zhang ◽  
Sudipta Halder

The effect of reactive (polyethylene glycol) and non-reactive (toluene) diluents on thermal and mechanical properties (tensile strength, hardness and fracture toughness) of diglycidyl ether of bisphenol A epoxy resin (cured by triethylenetetramine) was investigated. The thermal stability and mechanical properties of the epoxy resin modified with reactive and non-reactive diluents at different wt% were investigated using thermo-gravimetric analyser, tensile test, hardness test and single-edge-notched bend test. A minor variation in thermal stability was observed for epoxy resin after addition of polyethylene glycol and toluene at 0.5 wt%; however, further addition of reactive and non-reactive diluents diminished the thermal stability. The addition of 10 wt% of polyethylene glycol in epoxy resin significantly enhances the tensile strength (∼12%), hardness (∼14%) and fracture toughness (∼24%) when compared to that of neat epoxy resin. In contrast, major drop in mechanical performance was observed after addition of toluene in epoxy. Furthermore, fracture surfaces were investigated under field emission scanning electron microscope to elucidate the failure mechanism.


RSC Advances ◽  
2017 ◽  
Vol 7 (58) ◽  
pp. 36460-36472 ◽  
Author(s):  
Jiapei Du ◽  
Yuhuan Bu ◽  
Shenglai Guo ◽  
Leiju Tian ◽  
Zhonghou Shen

In this study, an environmentally friendly epoxy resin is mixed with ground-granulated blast furnace slag (GGBS) for use as a stabilizer to enhance mechanical performance and leaching resistance properties of marine sediments.


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