Effect of reactive and non-reactive diluents on thermal and mechanical properties of epoxy resin

2017 ◽  
Vol 30 (10) ◽  
pp. 1159-1168 ◽  
Author(s):  
Animesh Sinha ◽  
Nazrul Islam Khan ◽  
Subhankar Das ◽  
Jiawei Zhang ◽  
Sudipta Halder
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Epoxy Resin ◽  
Mechanical Performance ◽  
Thermal And Mechanical Properties ◽  
Minor Variation ◽  
Reactive Diluents

The effect of reactive (polyethylene glycol) and non-reactive (toluene) diluents on thermal and mechanical properties (tensile strength, hardness and fracture toughness) of diglycidyl ether of bisphenol A epoxy resin (cured by triethylenetetramine) was investigated. The thermal stability and mechanical properties of the epoxy resin modified with reactive and non-reactive diluents at different wt% were investigated using thermo-gravimetric analyser, tensile test, hardness test and single-edge-notched bend test. A minor variation in thermal stability was observed for epoxy resin after addition of polyethylene glycol and toluene at 0.5 wt%; however, further addition of reactive and non-reactive diluents diminished the thermal stability. The addition of 10 wt% of polyethylene glycol in epoxy resin significantly enhances the tensile strength (∼12%), hardness (∼14%) and fracture toughness (∼24%) when compared to that of neat epoxy resin. In contrast, major drop in mechanical performance was observed after addition of toluene in epoxy. Furthermore, fracture surfaces were investigated under field emission scanning electron microscope to elucidate the failure mechanism.

scholarly journals Tailoring the Mechanical Performance of Epoxy Resin by Various Nanoparticles

2008 ◽  
Vol 16 (8) ◽  
pp. 527-533 ◽  
Author(s):  
Sheng Liu ◽  
Hui Zhang ◽  
Zhong Zhang ◽  
Taihua Zhang ◽  
Stephan Sprenger
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Epoxy Resin ◽  
Silica Nanoparticles ◽  
Mechanical Performance ◽  
Sol Gel ◽  
Nanoparticle Dispersion ◽  
Nanosilica Particles ◽  
The Cost

Flexible organic elastomeric nanoparticles (ENP) and two kinds of rigid inorganic silica nanoparticles were dispersed respectively into a bisphenol-A epoxy resin in order to tailor and compare the performance of mechanical properties. It was found that the well-dispersed flexible ENP greatly enhanced the toughness of the epoxy with the cost of modulus and strength. Comparatively, the rigid silica nanoparticles improved Young's modulus, tensile strength and fracture toughness simultaneously. Both fumed and sol-gel-formed nanosilica particles conducted similar results in reinforcing the epoxy resin, although the latter exhibited almost perfect nanoparticle dispersion in matrix. The toughening mechanisms of nanocomposites were further discussed based on fractographic analysis.

scholarly journals The Effects of Water and Seawater on the Mechanical Properties of Carbon Fibre Reinforced Epoxy Composite under Pre-Cure Curing Condition

1998 ◽  
Vol 7 (4) ◽  
pp. 096369359800700
Author(s):  
M. Zhang ◽  
S.E. Mason
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Carbon Fibre ◽  
Laminate Composite ◽  
Mechanical Performance ◽  
Epoxy Composite ◽  
Interlaminar Fracture Toughness ◽  
Curing Condition ◽  
Structural Carbon

The influences on the interlaminar fracture toughness (GIC) and ultimate tensile strength (UTS) of a cured structural carbon fibre reinforced epoxy composite of two contaminants, water and seawater, introduced prior to cure have been investigated. The results have demonstrated that the control of environmental factors such as water and seawater can have significant effects on the mechanical performance of laminate composite components during the manufacturing process.

Effect of Curing System on Morphological, Rheological, Thermal and Mechanical Properties of Thermoplastic Vulcanizates Based on Epoxidized Natural Rubber and Polypropylene

2012 ◽  
Vol 602-604 ◽  
pp. 690-695
Author(s):  
Hua Dong Wang ◽  
Rui Wang ◽  
Mao Fang Huang ◽  
Qi Yang
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Epoxidized Natural Rubber ◽  
Thermal And Mechanical Properties ◽  
Rheological Analysis ◽  
Elongation At Break ◽  
Thermoplastic Vulcanizates ◽  
Internal Mixer

Thermoplastic vulcanizates (TPVs) based on epoxidized natural rubber (ENR) and polypropylene (PP) were prepared in an internal mixer at 180°C. The effects of curing systems (i.e., sulfur and peroxide) on morphological, rheological, thermal and mechanical properties were studied. It is found that the sulfur cured TPVs show higher tensile strength, tear strength and elongation at break than those cured with the DCP systems. The rheological analysis indicates that TPVs cured with DCP system show lower apparent shear viscosity than those with sulfur system. SEM studies show that TPVs vulcanized with DCP system exhibit smaller and finely dispersed rubber domains, which provides it higher thermal stability than sulfur cured TPVs.

Thermomechanical Study and Thermal Behavior of Plasticized Poly(Lactic Acid) Nanocomposites

2021 ◽  
Vol 317 ◽  
pp. 333-340
Author(s):  
Mohammed Zorah ◽  
Izan Roshawaty Mustapa ◽  
Norlinda Daud ◽  
Nahida Jumah ◽  
Nur Ain Syafiqah Sudin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Lactic Acid ◽  
Thermal Behavior ◽  
Food Packaging ◽  
Mechanical Performance ◽  
Poly Lactic Acid ◽  
Solvent Casting ◽  
Thermal And Mechanical Properties ◽  
Hot Press

Poly (lactic acid) (PLA) is a useful alternative to petrochemical commodity material used in such as in food packaging industries. Due to its inherent brittleness, low thermal stability, and poor crystallization, it needs to improve its properties, namely in terms of thermal and mechanical performance. The plasticized PLA composites reinforced with nanofiller were prepared by solvent casting and hot press methods. Thermal and mechanical properties, as well as the crystallinity study of these nanocomposites, were investigated to study the effect of tributyl citrate (TBC) and TiO2 on the PLA composites. The addition of TBC improved the flexibility and crystallinity of the composites. Reinforcement of TiO2 was found as a practical approach to improve the mechanical properties, thermal stability, and enhanced crystalline ability for plasticized PLA nanocomposites. Based on the results achieved in this study, the composite with 3.5% nanofiller (pPLATi3.5) presented the optimum set of mechanical properties and improved thermal stability.

scholarly journals Correlation between Microstructure and Mechanical Properties of Heat-Treated Ti–6Al–4V with Fe Alloying

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 854 ◽  
Author(s):  
Yongwei Liu ◽  
Fuwen Chen ◽  
Guanglong Xu ◽  
Yuwen Cui ◽  
Hui Chang
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Mechanical Performance ◽  
Volume Fraction ◽  
Phase Interface ◽  
High Strength ◽  
High Plasticity ◽  
High Aging Temperature ◽  
Microstructure And Mechanical Properties

The microstructure and mechanical properties of a newly developed Fe-microalloyed Ti–6Al–4V titanium alloy were investigated after different heat treatments. The volume fraction and the morphological features of the lamellar α phase had significant effects on the alloy’s mechanical performance. A dataset showing the relationship between microstructural features and tensile strength, elongation, and fracture toughness was developed. A high aging temperature resulted in high plasticity and fracture toughness, but relatively low strength. The high strength favored the fine α and the slender β. The high aspect ratio of lamellar α led to high strength but low fracture toughness. The alloy with ~84 vol % α exhibited the highest strength and lowest fracture toughness because the area of its α/β-phase interface was the highest. Optimal comprehensive mechanical performance and heat-treatment procedures were thus obtained from the dataset. Optimal tensile strength, yield strength, elongation, and fracture toughness were 999 and 919 MPa, 10.4%, and 94.4 MPa·m1/2, respectively.

scholarly journals THE EFFECT OF FIBER CONTENT ON COTTON REINFORCED ALBUMEN COMPOSITES

2011 ◽  
Vol 12 (2) ◽  
pp. 131-144 ◽  
Author(s):  
Yusof Yusliza ◽  
Ahmad Zuraida
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Cotton Fiber ◽  
Mechanical Performance ◽  
Impact Resistance ◽  
Morphological Structure ◽  
Fiber Content ◽  
X Ray ◽  
Thermal Stability Of

ABSTRACT : The effect of fiber content on mechanical properties and thermal stability of the cotton/albumen composites (CAC) were investigated and presented in this paper. The composites having 0%, 3%, 6%, 10%, 13 %, and 16% w/w of cotton fiber were considered.  Hands lay-up technique was used to prepare the CAC specimens and dried for 24 hours before characterised and evaluated for their mechanical performance. The structure and thermal stability of the composites were characterized by using x-ray and thermogravimetry analysis, respectively. The tensile strength and impact resistance of CAC are found maximum with the value of 8.7 MPa and 19.0 kJ/m2, respectively. Analysis on the morphological structure by SEM revealed that the mechanical properties of the composites depend on good wettability and adhesion between fiber/matrix.

scholarly journals The Effect of Boron Nitride on the Thermal and Mechanical Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 940 ◽  
Author(s):  
Mualla Öner ◽  
Gülnur Kızıl ◽  
Gülşah Keskin ◽  
Celine Pochat-Bohatier ◽  
Mikhael Bechelany
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Boron Nitride ◽  
Young’S Modulus ◽  
Mechanical Performance ◽  
Young's Modulus ◽  
Filler Concentration ◽  
Gravimetric Analysis ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry

The thermal and mechanical properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate, PHBV) composites filled with boron nitride (BN) particles with two different sizes and shapes were studied by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), thermal gravimetric analysis (TGA) and mechanical testing. The biocomposites were produced by melt extrusion of PHBV with untreated BN and surface-treated BN particles. Thermogravimetric analysis (TGA) showed that the thermal stability of the composites was higher than that of neat PHBV while the effect of the different shapes and sizes of the particles on the thermal stability was insignificant. DSC analysis showed that the crystallinity of the PHBV was not affected significantly by the change in filler concentration and the type of the BN nanoparticle but decreasing of the crystallinity of PHBV/BN composites was observed at higher loadings. BN particles treated with silane coupling agent yielded nanocomposites characterized by good mechanical performance. The results demonstrate that mechanical properties of the composites were found to increase more for the silanized flake type BN (OSFBN) compared to silanized hexagonal disk type BN (OSBN). The highest Young’s modulus was obtained for the nanocomposite sample containing 1 wt.% OSFBN, for which increase of Young’s modulus up to 19% was observed in comparison to the neat PHBV. The Halpin–Tsai and Hui–Shia models were used to evaluate the effect of reinforcement by BN particles on the elastic modulus of the composites. Micromechanical models for initial composite stiffness showed good correlation with experimental values.

Effect of surface treatment on moisture absorption, thermal, and mechanical properties of sisal fiber

2020 ◽  
pp. 152808372092477 ◽  
Author(s):  
Adane Dagnaw Gudayu ◽  
Leif Steuernagel ◽  
Dieter Meiners ◽  
Rotich Gideon
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Moisture Absorption ◽  
Natural Fibers ◽  
Alkaline Treatment ◽  
Automotive Application ◽  
Sisal Fiber ◽  
Thermal And Mechanical Properties ◽  
The Impact

Natural fibers are increasingly being used as composite reinforcement for both thermoplastic and thermoset resin, mainly for automotive application. Due to their hydrophilic nature, natural fibers have certain limitations during composite manufacture especially owing to their poor resin wettability, weak fiber–polymer interface, high moisture absorption, and being affected by high temperature in case of thermoplastic resin. This work investigates the impact of sisal fiber modification techniques on moisture absorption, thermal, and mechanical properties of the fiber. Four sisal fiber samples were prepared; untreated, alkaline treated, acetylated, and a combined alkaline-treated/acetylation samples. The samples were evaluated for their hygroscopic nature, thermal stability, and tensile properties. It is found that acetylation resulted in a reduction of moisture absorption of sisal fiber as the acetylated and alkaline-treated/acetylated samples recorded a decrease of 42% and 28%, respectively. Alkaline treatment increased the absorbency owing to the removal of hemicellulose and lignin. The thermogravimetric result revealed that alkaline treatment improved the thermal stability as the alkali-treated and alkali-treated/acetylated samples showed improvement in thermal properties. The acetylated sample resulted in a significant reduction in tensile strength. But, the results from tensile tests of the alkaline-treated samples showed an insignificant decrease in tensile strength and improvement in the modulus for all treated samples. Fourier-transform infrared and scanning electron microscopic analysis were included in the study to supplement the results with structural and microstructural changes. The effect of those treatments on the sisal–PET composite properties was studied and will be submitted in part 2 of the study.

Morphology and Mechanical Properties of Epoxy/Alumina Nanocomposites

2006 ◽  
Vol 312 ◽  
pp. 233-236 ◽  
Author(s):  
Ke Wang ◽  
Pascal Ogier ◽  
Chauhari Wuiwui Tjiu ◽  
Chaobin He
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Epoxy Resin ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Fracture Mechanisms ◽  
Elongation At Break ◽  
Filler Dispersion ◽  
Morphology And Mechanical Properties

Alumina nano-crystals were dispersed in epoxy resin via different approaches. The effects of filler dispersion on the mechanical properties of the epoxy/alumina nanocomposites were studied. The fracture mechanisms are investigated using SEM. The results show that the Young’s modulus, tensile strength, elongation at break and fracture toughness of epoxy were improved dramatically with the incorporation of well-dispersed alumina nano-crystals. The poorly-dispersed nano-crystals, however, showed little effects on the mechanical properties.

scholarly journals HDPE/METHYLSILANE MODIFIED DIATOMITE COMPOSITES: ANALYSIS OF THERMAL AND MECHANICAL PROPERTIES

2019 ◽  
Vol 16 (31) ◽  
pp. 192-209
Author(s):  
C. R. FENSTERSEIFER ◽  
R. BRAMBILLA
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Composite Material ◽  
Impact Test ◽  
Methyl Groups ◽  
Thermal And Mechanical Properties ◽  
Phase Domain ◽  
Izod Impact ◽  
Modified Diatomite

According to IUPAC, the composites are multicomponent materials comprising multiple, different (nongaseous) phase domains in which at least one type of phase domain is a continuous phase.High density polyethylene (HDPE) reinforced with silica particles is an example of a composite material. Diatomite is a natural silica commonly used in filter media.In the present work, the diatomite was organofunctionalized with methyltriethoxysilane (C1) and then used in the preparation of HDPE/diatomite composites with diatomite content of 2.0 and 5.0 wt%. The composites were evaluated in terms of mechanical properties by dynamicmechanical analysis (DMTA), Izod impact test and flexural strength and tensile strength tests.TheFourier transform infrared spectrum (FTIR) of the organofunctionalized diatomite presented bands characteristic of methyl groups, proving the efficiency of the surface modification.The addition of 5.0% diatomite in HDPE resulted in an increase of 8.0 °C in thermal stability, crystallinity (72 to 78%) and in approximately 4.0% in the storage modulus (G '), compared to pure HDPE.SEM analyzes showed the presence of diatomite agglomerates in the HDPE matrix. The Izod impact strength of the composites for this composite was 50 J / m, half of that observed for pure HDPE. The properties of tensile strength were not influenced by the presence of diatomite in HDPE.

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