scholarly journals Metal mobility during hydrothermal breakdown of Fe-Ti oxides: Insights from Sb-Au mineralizing event (Variscan Armorican Massif, France)

2017 ◽  
Vol 91 ◽  
pp. 66-99 ◽  
Author(s):  
Anthony Pochon ◽  
Georges Beaudoin ◽  
Yannick Branquet ◽  
Philippe Boulvais ◽  
Eric Gloaguen ◽  
...  
1995 ◽  
Vol 32 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Valérie Colandini ◽  
Michel Legret ◽  
Yves Brosseaud ◽  
Jean-Daniel Baladès

Porous pavements infiltrated with stormwater are faced with clogging problems: runoff particles seep and clog the pervious surface layer of these structures. Clogging material samples (in the form of sludge) have been collected in cleaning operations on the pervious asphalt. This study aims at characterizing these materials, particle size distribution, heavy metal contents by particle size, and studying interactions between metals and particles. A sequential extraction procedure proposed by the experts of the Community Bureau of Reference (B.C.R.) was applied to provide information about heavy metal distribution on particles and to evaluate interaction strength, and consequently potential metal mobility when chemical variations occurred in the environment. Mainly made up of sand, the materials are polluted with lead, copper, zinc and cadmium. The concentrations appeared to be linked with road traffic intensity. The heavy metal contents by particle size showed that the finer are the particles, the higher are the heavy metal concentrations. Heavy metals were found potentially labile; metals contents in the residual fraction (mineral fraction) represented less than 20 % of the total concentration. Cadmium and zinc were apparently more labile than lead and copper.


Author(s):  
S. Aspiotis ◽  
S. Jung ◽  
F. Hauff ◽  
R. L. Romer

AbstractThe late-tectonic 511.4 ± 0.6 Ma-old Nomatsaus intrusion (Donkerhoek batholith, Damara orogen, Namibia) consists of moderately peraluminous, magnesian, calc-alkalic to calcic granites similar to I-type granites worldwide. Major and trace-element variations and LREE and HREE concentrations in evolved rocks imply that the fractionated mineral assemblage includes biotite, Fe–Ti oxides, zircon, plagioclase and monazite. Increasing K2O abundance with increasing SiO2 suggests accumulation of K-feldspar; compatible with a small positive Eu anomaly in the most evolved rocks. In comparison with experimental data, the Nomatsaus granite was likely generated from meta-igneous sources of possibly dacitic composition that melted under water-undersaturated conditions (X H2O: 0.25–0.50) and at temperatures between 800 and 850 °C, compatible with the zircon and monazite saturation temperatures of 812 and 852 °C, respectively. The Nomatsaus granite has moderately radiogenic initial 87Sr/86Sr ratios (0.7067–0.7082), relatively radiogenic initial εNd values (− 2.9 to − 4.8) and moderately evolved Pb isotope ratios. Although initial Sr and Nd isotopic compositions of the granite do not vary with SiO2 or MgO contents, fSm/Nd and initial εNd values are negatively correlated indicating limited assimilation of crustal components during monazite-dominated fractional crystallization. The preferred petrogenetic model for the generation of the Nomatsaus granite involves a continent–continent collisional setting with stacking of crustal slices that in combination with high radioactive heat production rates heated the thickened crust, leading to the medium-P/high-T environment characteristic of the southern Central Zone of the Damara orogen. Such a setting promoted partial melting of metasedimentary sources during the initial stages of crustal heating, followed by the partial melting of meta-igneous rocks at mid-crustal levels at higher P–T conditions and relatively late in the orogenic evolution.


2019 ◽  
Vol 60 (7) ◽  
pp. 1349-1370
Author(s):  
S Z Smirnov ◽  
A V Rybin ◽  
N N Kruk ◽  
T Yu Timina ◽  
E N Sokolova ◽  
...  

Abstract Detailed mineralogical and melt and fluid inclusion constraints on magma storage, and the evolution of melts, are presented for the large-volume caldera eruption on the Vetrovoy Isthmus on Itutrup Island (Kuril Islands, Russia). The shallow magma reservoir beneath the Vetrovoy Isthmus is composed of a mush of plagio-rhyolitic melt, phenocrysts and the products of peritectic reaction(s). The melt appears to have formed as a result of partial melting of previously erupted rocks, which probably had andesitic to basaltic compositions and were metamorphosed into amphibole-bearing assemblages. The breakdown of amphibole in the partially melted precursor rocks led to the formation of early Mg-rich clino- and orthopyroxene, along with plagioclase and Fe–Ti oxides, and the release of aqueous fluids. Variations in fluid pressure are recorded by a strong increase of An contents in plagioclase. Crystallization took place at around 850°C with pressure ranging from 0·9 to 3 kbar. This study demonstrates that dacitic magmas erupted during the course of a 20 kyr voluminous eruption were the result of mixing between plagio-rhyolitic partial melts and the breakdown reaction minerals (i.e. pyroxenes, plagioclase and Fe–Ti oxides). Plagioclase and quartz were the last minerals to crystallize from these melts prior to eruption.


2000 ◽  
Vol 105 (B8) ◽  
pp. 19273-19288 ◽  
Author(s):  
Stéphane Bonnet ◽  
François Guillocheau ◽  
Jean-Pierre Brun ◽  
Jean Van Den Driessche

2005 ◽  
Vol 220 (1-2) ◽  
pp. 21-45 ◽  
Author(s):  
Valérie Bosse ◽  
Gilbert Féraud ◽  
Michel Ballèvre ◽  
Jean-Jacques Peucat ◽  
Michel Corsini
Keyword(s):  

1994 ◽  
Vol 68 (3) ◽  
pp. 451-460 ◽  
Author(s):  
Patrick R. Racheboeuf ◽  
Paul Copper ◽  
Fernando Alvarez

Cryptonella? cailliaudi Barrois, 1889, from the Lower Devonian of the Armorican Massif, is tentatively assigned to the athyridid brachiopod genus Planalvus Carter, thus far known only from the Lower Carboniferous of eastern North America. In addition, a new species, Planalvus rufus, is described from the Bois-Roux Formation (Pragian) of Brittany, France. These French species are small brachiopods with complex spiralial and jugal structures, which permit assignment to the order Athyridida.


2013 ◽  
Vol 651 ◽  
pp. 163-167
Author(s):  
Shu Rui Li ◽  
Xue Min Wang ◽  
Xin Lai He

The influence of Ti oxide on the toughness of heat affected zone for low carbon bainitic steels has been investigated. The optical microscope, SEM and TEM were used to analyze the composition, size and distribution of the inclusions, and the microstructure and mechanical properties after welding thermal simulation were also investigated. The effect of Ti oxide inclusion on the transformation of acicular ferrite has also been studied. The results show that after the melting with Ti dioxide technique the inclusion is complex, in the core is Ti oxides about 1-3 micron and around it is MnS. It has been found the acicular ferrite can nucleate at the inclusions and the Ti oxide inclusion will promote the nucleation of acicular ferrite, and the acicular ferrite will block the growth of bainite. Therefore by introducing the Ti oxide in the steels the microstructure of HAZ could be refined markedly therefore the toughness of HAZ can be improved evidently.


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