Semi-aromatic polyamides containing fluorenyl pendent toward excellent thermal stability, mechanical properties and dielectric performance

Polymer ◽  
2021 ◽  
pp. 123757
Author(s):  
Bo-Wen Liu ◽  
Jia-Wei Long ◽  
Li Chen ◽  
Xiang-Xin Xiao ◽  
Xue-Bao Lin ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87013-87020 ◽  
Author(s):  
Kaiju Luo ◽  
Yan Wang ◽  
Junrong Yu ◽  
Jing Zhu ◽  
Zuming Hu

Aromatic furanic polyamides with relatively high molecular weight were synthesized, and good thermal stability and mechanical properties were demonstrated.


2015 ◽  
Vol 816 ◽  
pp. 546-550
Author(s):  
Chao Yuan ◽  
Huan Wang ◽  
Jian Ting Guo ◽  
He Yong Qin

During long-term and high temperature service, microstructures of superalloys may change and then have an adverse impact on mechanical properties, so the stabilities of a wrought Ni-base superalloy aging without stress at 650°C were investigated in this paper. The results showed that the size and morphology of γ' precipitates in the alloy were not obviously influenced with the increase of exposure time, and primary MC carbides present excellent thermal stability. Moreover, almost no detrimental phase was found. Tensile strength and plasticity at room temperature after aging remained steady. Under the condition of 650°C/823MPa, the stress ruptures life presented increasing trend overall and plasticity decreases slightly. In conclusion, the experiment alloy presents a good thermal stability at 650°C.


2020 ◽  
Vol 2 (2) ◽  
pp. 691-698 ◽  
Author(s):  
Bo Zhao ◽  
Shengya Zhang ◽  
Shuai Duan ◽  
Jingyan Song ◽  
Xiangjun Li ◽  
...  

Polycrystalline diamond with high mechanical properties and excellent thermal stability plays an important role in industry and materials science.


RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105869-105879 ◽  
Author(s):  
Wei Yang ◽  
Zhongjing Jia ◽  
Yani Chen ◽  
Yunran Zhang ◽  
Jingyu Si ◽  
...  

Modified carbon nanotube reinforced polylactide/basalt fiber composites containing aluminium hypophosphite were prepared via melt blending method. The composites showed excellent thermal stability, flame retardancy, and mechanical properties.


2015 ◽  
Vol 10 (1) ◽  
pp. 155892501501000 ◽  
Author(s):  
Bin-Jie Xin ◽  
Wenjie Chen

In this paper, the morphology, structure and properties of electrospun Polysulfonamide (PSA)/multi-walled carbon nanotubes (MWCNTs) fibers are investigated systematically. The experimental results indicate that the diameter of electrospun PSA fiber increased by the blending of MWCNTs while its crystallinity decreased. Both the conductivity and mechanical properties of PSA/MWCNT fibers were improved by the blending of MWCNTs at a concentration below 5% MWCNT. The thermal behavior of the electrospun fibers was influenced by the MWCNT concentrations through the Thermogravimetric Analysis (TGA). The new developed PSA/MWCNTs composite nanofiber has excellent thermal stability and mechanical properties compared with the usual PSA fibers.


2019 ◽  
Vol 960 ◽  
pp. 140-147
Author(s):  
Na Li ◽  
Xing Ke Zhang ◽  
Jun Rong Yu ◽  
Yan Wang ◽  
Jing Zhu ◽  
...  

Copolymerized poly (m-phenylene isophthalamide) (co-PMIA) fibers with excellent thermal stability and good mechanical properties were developed via solution polycondensation process based on m-phenylenediamine (MPD), isophthaloyl dichloride (IPC), and 3,4′-oxydianiline (3,4′-ODA). Effects of the ether moiety on the structure and properties of the copolymers were investigated. A series of co-PMIA nascent fibers were produced using wet-spinning method. The coagulation process to form co-PMIA nascent fibers were studied by examination of SEM and strength tester. The co-PMIA nascent fibers with the MPD/3,4′-ODA molar ratio of 8:2 showed an optimum dye uptake. Keywords: Copolymerization; High performance material; Wet spinning; Dyeability.


2020 ◽  
Author(s):  
Junpeng Wang ◽  
Devavrat Sathe ◽  
Junfeng Zhou ◽  
Hanlin Chen ◽  
Hsin-Wei Su ◽  
...  

Abstract A promising solution to address the challenges in plastics sustainability is to replace current polymers with chemically recyclable ones that can depolymerise into their constituent monomers for circular use of materials. Despite the progress, few depolymerisable polymers exhibit the excellent thermal stability and strong mechanical properties of traditional polymers. Here we report a series of chemically recyclable polymers that show excellent thermal stability (decomposition temperature > 370 ºC) and tunable mechanical properties. The polymers are formed via ring-opening metathesis polymerisation of cyclooctene with a trans-cyclobutane installed at the 5,6-positions. The additional ring converts the non-depolymerisable polycyclooctene into a depolymerisable polymer by reducing the ring strain energy in the monomer (from 8.2 kcal/mol in unsubstituted cyclooctene to 4.9 kcal/mol in the fused ring). The fused-ring monomer enables a broad scope of functionalities to be incorporated, providing access to chemically recyclable elastomers and plastics that show promise as next-generation sustainable materials.


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