Crystalline structure and remarkably enhanced tensile property of β-isotactic polypropylene via overflow microinjection molding

2019 ◽  
Vol 76 ◽  
pp. 448-454 ◽  
Author(s):  
Zhongzhu Liu ◽  
Xianhu Liu ◽  
Lele Li ◽  
Guoqiang Zheng ◽  
Chuntai Liu ◽  
...  

2015 ◽  
Vol 9 (3) ◽  
pp. 308-320 ◽  
Author(s):  
A. Menyhard ◽  
P. Suba ◽  
Zs. Laszlo ◽  
H. M. Fekete ◽  
A. O. Mester ◽  
...  




2016 ◽  
Vol 51 (23) ◽  
pp. 10386-10399 ◽  
Author(s):  
Liyan Yang ◽  
Juqiao Su ◽  
Qi Yang ◽  
Tongying Zhang ◽  
Zhongguo Zhao ◽  
...  




2013 ◽  
Vol 52 (34) ◽  
pp. 11996-12002 ◽  
Author(s):  
Xianhu Liu ◽  
Kun Dai ◽  
Xiaoqiong Hao ◽  
Guoqiang Zheng ◽  
Chuntai Liu ◽  
...  




Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 219
Author(s):  
Zhongguo Zhao ◽  
Xin Zhang ◽  
Qi Yang ◽  
Taotao Ai ◽  
Shikui Jia ◽  
...  

In this work, a series of isotactic polypropylene/poly(ethylene terephthalate) (iPP/PET) samples were prepared by microinjection molding (μIM) and mini-injection molding (IM). The properties of the samples were investigated in detail by differential scanning calorimetry (DSC), Wide-Angle X-ray Diffraction (WAXD), Polarized light microscope (PLM) and scanning electron microscopy (SEM). Results showed that the difference in thermomechanical history between both processing methods leads to the formation of different microstructures in corresponding iPP/PET moldings. For example, the dispersed spherical PET phase deforms and emerges into continuous in-situ microfibrils due to the intensive shearing flow field and temperature field in μIM. Additionally, the incorporation of PET facilitates both the laminar branching and the reservation of oriented molecular chains, thereby leading to forming a typical hybrid structure (i.e., fan-shaped β-crystals and transcrystalline). Furthermore, more compact and higher degrees of oriented structure can be obtained via increasing the content of PET. Such hybrid structure leads to a remarkable enhancement of mechanical property in terms of μIM samples.



1998 ◽  
Vol 31 (20) ◽  
pp. 6926-6934 ◽  
Author(s):  
Dino R. Ferro ◽  
Stefano V. Meille ◽  
Sergio Brückner


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