scholarly journals Autoignition and detonation development from a hot spot inside a closed chamber: Effects of end wall reflection

Author(s):  
Peng Dai ◽  
Zheng Chen ◽  
Xiaohua Gan ◽  
Mikhail A. Liberman
2020 ◽  
pp. 146808742094461
Author(s):  
Jingyi Su ◽  
Peng Dai ◽  
Zheng Chen

Natural gas is a promising alternative fuel which can be used in internal combustion engines to achieve low carbon emission and high thermal efficiency. However, at high compression ratio, super-knock due to detonation development might occur. In this study, the autoignitive reaction front propagation and detonation development from a hot spot were investigated numerically and the main component of natural gas, methane, was considered. The objective is to assess the performance of different kinetic models in terms of predicting hot spot–induced detonation development in methane/air mixtures. First, simulations for the constant-volume homogeneous ignition in a stoichiometric methane/air mixture were conducted. The ignition delay time, excitation time, critical temperature gradient, thermal sensitivity and reduced activation energy predicted by different kinetic models were obtained and compared. It was found that there are notable discrepancies among the predictions by different kinetic models. Then, hundreds of one-dimensional simulations were conducted for detonation development from a hot spot in a stoichiometric CH4/air mixture. Different autoignition modes were identified and the detonation regimes were derived based on the peak pressure and reaction front propagation speed. It was found that even at the same conditions, different propagation modes can be predicted by different kinetic models. The broadest detonation development regime was predicted by the reduced GRI mechanism, while a relatively narrow regime was predicted by the recent kinetic models such as FFCM-1 and Aramco 3.0. The present results indicate that super-knock prediction strongly depends on the kinetic model used in simulations. Therefore, significant efforts should be devoted to the development and validation of kinetic models for natural gas at engine conditions.


2016 ◽  
Author(s):  
M. Burger ◽  
S. Berger ◽  
I. Spangenberg ◽  
C. Blodau

Abstract. Ponds smaller than 10000 m2 likely account for about one third of the global lake perimeter. The release of methane (CH4) and carbon dioxide (CO2) from these ponds is often high and significant on the landscape scale. We measured CO2 and CH4 fluxes in a temperate peatland in southern Ontario, Canada, in summer 2014 along a transect from the open water of a small pond (847 m2) towards the surrounding floating mat (5993 m2) and in a peatland reference area. We used a high-frequency closed chamber technique and distinguished between diffusive and ebullitive CH4 fluxes. CH4 fluxes and CH4 bubble frequency increased from a median of 0.14 (0.00 to 0.43) mmol m−2 h−1 and 4 events m−2 h−1 on the open water to a median of 0.80 (0.20 to 14.97) mmol m−2 h−1 and 168 events m−2 h−1 on the floating mat. The mat was a summer hot spot of CH4 emissions. Fluxes were one order of magnitude higher than at an adjacent peatland site. During daytime the pond was a net source of CO2 equivalents to the atmosphere amounting to 0.13 (−0.02 to 1.06) g CO2 equivalents m−2 h−1, whereas the adjacent peatland site acted as a sink of −0.78 (−1.54 to 0.29) g CO2 equivalents m−2 h−1. The photosynthetic CO2 uptake on the floating mat did not counterbalance the high CH4 emissions, which turned the floating mat into a strong net source of 0.21 (−0.11 to 2.12) g CO2 equivalents m−2h−1. This study highlights the large small-scale variability of CH4 fluxes and CH4 bubble frequency at the peatland-pond interface and the importance of the often large ecotone areas surrounding small ponds as a source of greenhouse gases to the atmosphere.


2016 ◽  
Vol 13 (12) ◽  
pp. 3777-3791 ◽  
Author(s):  
Magdalena Burger ◽  
Sina Berger ◽  
Ines Spangenberg ◽  
Christian Blodau

Abstract. Ponds smaller than 10 000 m2 likely account for about one-third of the global lake perimeter. The release of methane (CH4) and carbon dioxide (CO2) from these ponds is often high and significant on the landscape scale. We measured CO2 and CH4 fluxes in a temperate peatland in southern Ontario, Canada, in summer 2014 along a transect from the open water of a small pond (847 m2) towards the surrounding floating mat (5993 m2) and in a peatland reference area. We used a high-frequency closed chamber technique and distinguished between diffusive and ebullitive CH4 fluxes. CH4 fluxes and CH4 bubble frequency increased from a median of 0.14 (0.00 to 0.43) mmol m−2 h−1 and 4 events m−2 h−1 on the open water to a median of 0.80 (0.20 to 14.97) mmol m−2 h−1 and 168 events m−2 h−1 on the floating mat. The mat was a summer hot spot of CH4 emissions. Fluxes were 1 order of magnitude higher than at an adjacent peatland site. During daytime the pond was a net source of CO2 equivalents to the atmosphere amounting to 0.13 (−0.02 to 1.06) g CO2 equivalents m−2 h−1, whereas the adjacent peatland site acted as a sink of −0.78 (−1.54 to 0.29) g CO2 equivalents m−2 h−1. The photosynthetic CO2 uptake on the floating mat did not counterbalance the high CH4 emissions, which turned the floating mat into a strong net source of 0.21 (−0.11 to 2.12) g CO2 equivalents m−2 h−1. This study highlights the large small-scale variability of CH4 fluxes and CH4 bubble frequency at the peatland–pond interface and the importance of the often large ecotone areas surrounding small ponds as a source of greenhouse gases to the atmosphere.


1996 ◽  
Vol 75 (04) ◽  
pp. 546-550 ◽  
Author(s):  
Marianne Schwartz ◽  
Albert Békássy ◽  
Mikael Donnér ◽  
Thomas Hertel ◽  
Stefan Hreidarson ◽  
...  

SummaryTwelve different mutations in the WASP gene were found in twelve unrelated families with Wiskott-Aldrich syndrome (WAS) or X-linked thrombocytopenia (XLT). Four frameshift, one splice, one nonsense mutation, and one 18-base-pair deletion were detected in seven patients with WAS. Only missense mutations were found in five patients diagnosed as having XLT. One of the nucleotide substitutions in exon 2 (codon 86) results in an Arg to Cys replacement. Two other nucleotide substitutions in this codon, R86L and R86H, have been reported previously, both giving rise to typical WAS symptoms, indicating a mutational hot spot in this codon. The finding of mutations in the WASP gene in both WAS and XLT gives further evidence of these syndromes being allelic. The relatively small size of the WASP gene facilitates the detection of mutations and a reliable diagnosis of both carriers and affected fetuses in families with WAS or XLT.


2013 ◽  
Vol 10 (3) ◽  
pp. 342-358 ◽  
Author(s):  
Apostolos G. Papadopoulos ◽  
Christos Chalkias ◽  
Loukia-Maria Fratsea

The paper explores the challenges faced today, in a context of severe economic crisis, by immigrant associations (ΙΜΑs) and Non-Governmental Organizations (NGOs) in Greece. The data analysed here was collected between October 2009 and February 2010 and incorporates references to all recorded migration-related social actors operating in Greece. The paper takes into account such indicators as legal form, objectives, financial capacity and geographical range of activity, concluding with a typology of civil society actors dealing with migration issues. This study aims at informing the migration policymaking and migrant integration processes. By a spatial hot-spot clustering of IMAs and NGOs, we also illustrate the concentration patterns of civil society actors in Greece.


2020 ◽  
pp. 116-122
Author(s):  
Emre Öztürk ◽  
Mehmet Aktaş ◽  
Tunç Şenyüz

The purpose of this research is to reach good correlation between sun load simulation and solar focusing test for exterior automotive lighting products. Light coming from sun is highly collimated (parallel rays) and focusable from lenses with concave structure. Focusing incidence leads to a hot spot on lens surrounding plastic parts which may cause melting failures at high temperature zones. Sun load simulation is performing to eliminate risk of discoloration, deformation, out gassing, coating failures and fire with prolonged exposure from field. Irradiance values in W/m2 defined in simulation as heat source depending of an angle of incidence of the sun radiation. At first step, simulation is performing with 5 degree intervals to define the critical zones then intervals decreased to 2 degree to detect the critical azimuth and inclination angles. Critical azimuth and inclination angles is checking with ray trace analysis to check the bouncing of sun rays and possible solution to eliminate focuses with design solutions. After numerical analysis to release and validate the automotive lighting products regarding the sun load test, measurement with first parts is necessary. Measurement is performing for all critical angles which have been detected at simulation with thermal camera under ultra high-collimation solar simulator. Measured temperatures are settled according to environment conditions and correlation is checking with simulations.


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