Iron-activated bermudagrass-derived biochar for adsorption of aqueous sulfamethoxazole: Effects of iron impregnation ratio on biochar properties, adsorption, and regeneration

2021 ◽  
Vol 750 ◽  
pp. 141691 ◽  
Author(s):  
Shengquan Zeng ◽  
Yong-Keun Choi ◽  
Eunsung Kan
2020 ◽  
Vol 41 (1) ◽  
pp. 74-79
Author(s):  
Sahira Joshi ◽  
Bishnu K.C.

Series of activated carbons (ACs) have been prepared from Sugarcane bagasse powder by ZnCl2 activation at various impregnation ratios of ZnCl2 to Sugarcane bagasse powder of 0.25:1, 0.5:1, 1:1 and 2:1 by weight. Characteristics of the activated carbons (ACs) were determined by iodine number, methylene blue number, surface area, scanning electron microscopy (SEM) and x-ray diffraction. Iodine number (IN) indicated that, microporosity of the AC were increased with increasing impregnation ratio ZnCl2 to Sugarcane bagasse upto 1:1 then started to decrease. However, mesoporosity as well as surface area was increased progressively. The maximum value of iodine number (868 mg/g) was achieved in the AC prepared at impregnation ratio of ZnCl2 to sugarcane bagasse 1:1. SEM micrographs also show the presence of well developed pores on its surface of AC-1. The broad peaks in the XRD patterns indicated that, all the ACs is amorphous materials. From results, it is concluded that ZnCl2 concentration used in impregnation is effective for development of porosity and surface area of the AC prepared from Sugarcane bagasse.


2013 ◽  
Vol 16 (1) ◽  
pp. 22-31
Author(s):  
Phung Thi Kim Le ◽  
Kien Anh Le

Agricultural wastes are considered to be a very important feedstock for activated carbon production as they are renewable sources and low cost materials. This study present the optimize conditions for preparation of durian peel activated carbon (DPAC) for removal of methylene blue (MB) from synthetic effluents. The effects of carbonization temperature (from 673K to 923K) and impregnation ratio (from 0.2 to 1.0) with potassium hydroxide KOH on the yield, surface area and the dye adsorbed capacity of the activated carbons were investigated. The dye removal capacity was evaluated with methylene blue. In comparison with the commercial grade carbons, the activated carbons from durian peel showed considerably higher surface area especially in the suitable temperate and impregnation ratio of activated carbon production. Methylene blue removal capacity appeared to be comparable to commercial products; it shows the potential of durian peel as a biomass source to produce adsorbents for waste water treatment and other application. Optimize condition for preparation of DPAC determined by using response surface methodology was at temperature 760 K and IR 1.0 which resulted the yield (51%), surface area (786 m2/g), and MB removal (172 mg/g).


2020 ◽  
Vol 2 (2) ◽  
pp. 22-32
Author(s):  
Ira Tyas Kurniasari ◽  
Cucun Alep Riyanto ◽  
Yohanes Martono

Humans need water with good quality to fulfill their needs. Water with high hardness content will have a bad impact if consumed continuously, so the adsorption method is carried out to reduce the concentration of Ca2+ and Mg2+ ions. The adsorption process uses sugarcane bagasse activated carbon (SBAC) and the tested water sample is well water in District Jati, Kudus. Synthesis of  SBAC was conducted with H3PO4 30% as an activator at an impregnation ratio of 1:5 (w/w) at temperature 700°C. The FTIR result showed that SBAC contains O-H, C-H, C=C, C≡C, and C-O as functional groups. Analysis result with the XRD instrument showed that the microstructure of SBAC that is formed is turbostatic structure and amorphous. Modeling isotherm suitable for SBAC adsorption on Ca2+ ions is Langmuir isotherm where the R2 value is 0.9134 which shows that the adsorption process occurs chemically and monolayer. Modeling isotherm suitable for SBAC adsorption on Mg2+ ions is Elovich isotherm where the R2 value is 0.8638 which means that the adsorption process is multilayer and adsorption in non-ideal conditions. Modeling kinetics suitable for SBAC adsorption on  Ca2+ and Mg2+ ions is Pseudo Orde 2 where the R2 value is 0.9395 and 0.7274. Percent efficiency value of sugarcane activated carbon adsorption of Ca2+ dan Mg2+ ions on District Jati, Kudus well water is 14.44% and 8.94% and 40 minutes stirring time.


Author(s):  
J. S. Weiner ◽  
Chris Stringer

Almost any single one of the techniques employed in the investigations suffices to reveal the elaborateness of the deception which was perpetrated at Piltdown. The anatomical examination, the tests for fluorine and nitrogen bear particularly good witness to this; even the radio-activity results taken alone, led the physicists to remark on the ‘great range of activity shown by specimens from this one little site’; ‘it is difficult to avoid the conclusion that the different bones in the Piltdown assemblage have had very different geological and chemical histories’. We have merely to take account of the stained condition of the whole assemblage, to realize the thoroughness of the fraud. From the Vandyke brown colour of the unnaturally abraded canine we infer with certainty that it was deliberately ‘planted’. The superficiality of the iron impregnation, combined with the chromium, tells as much as regards the orang jaw. And it is this iron-staining which finally shows that the rest, human and animal, was without doubt, all ‘planted’. The iron-staining has two peculiar features. It seems probable that ferric ammonium sulphate (iron alum) was the salt employed. This salt is slightly acid. The peculiarity of this salt (and, indeed, of any acid sulphate) is that in bone which contains little organic matter such as the cranium of Piltdown I, or Piltdown II, the beaver bones and hippo teeth, it brings about a detectable change in the crystal structure of the bone. In the apatite in which the calcium of the bone is held, the phosphate is replaced by sulphate to form gypsum. This change is quite unnatural, for neither gypsum nor sufficient sulphate occur in the gravels at Piltdown to bring it about. So the iron-sulphate-staining is an integral part of the forger’s necessary technique. He also used chromium compounds to aid the iron-staining probably because he thought it would assist the production of iron oxide. Chromium compounds are oxidizing. The basic strategy underlying the Piltdown series of forgeries now seems reasonably clear. Two main elements in the plan taken together explain nearly all the features of the affair quite satisfactorily.


2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Daouda Kouotou ◽  
Horace Ngomo Manga ◽  
Abdelaziz Baçaoui ◽  
Abdelrani Yaacoubi ◽  
Joseph Ketcha Mbadcam

In this study, activated carbons were prepared from oil palm shells by physicochemical activation. The methodology of experimental design was used to optimize the preparation conditions. The influences of the impregnation ratio (0.6–3.4) and the activation temperature between 601°C and 799°C on the following three responses: activated carbon yield (R/AC-H3PO4), the iodine adsorption (I2/AC-H3PO4), and the methylene blue adsorption (MB/AC-H3PO4) results were investigated using analysis of variance (ANOVA) to identify the significant parameters. Under the experimental conditions investigated, the activation temperature of 770°C and impregnation ratio of 2/1 leading to the R/AC-H3PO4of 52.10%, theI2/AC-H3PO4of 697.86 mg/g, and the MB/AC-H3PO4of 346.25 mg/g were found to be optimum conditions for producing activated carbon with well compromise of desirability. The two factors had both synergetic and antagonistic effects on the three responses studied. The micrographs of activated carbons examined with scanning electron microscopy revealed that the activated carbons were found to be mainly microporous and mesoporous.


2009 ◽  
Vol 10 (1-3) ◽  
pp. 115-120 ◽  
Author(s):  
Naïma Bouchemal ◽  
Meriem Belhachemi ◽  
Zoulikha Merzougui ◽  
Fatima Addoun

2009 ◽  
Vol 18 (1) ◽  
pp. 13-19 ◽  
Author(s):  
Wei Xia ◽  
Johannes H. Bitter ◽  
Dangsheng Su ◽  
Jun Qian ◽  
Martin Muhler

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