The systematics of chlorine, fluorine, and water in Izu arc front volcanic rocks: Implications for volatile recycling in subduction zones

While gold partitioning into hydrothermal fluids responsible for the formation of porphyry and epithermal deposits is currently well understood, its behavior during the differentiation of metal-rich silicate melts is still subject of an intense scientific debate. Typically, gold is scavenged into sulfides during crustal fractionation of sulfur-rich mafic to intermediate magmas and development of native forms and alloys of this important precious metal in igneous rocks and associated ores are still poorly documented. We present new data on gold (Cu-Ag-Au, Ni-Cu-Zn-Ag-Au, Ti-Cu-Ag-Au, Ag-Au) alloys from iron oxide deposits in the Lesser Khingan Range (LKR) of the Russian Far East. Gold alloy particles are from 10 to 100 µm in size and irregular to spherical in shape. Gold spherules were formed through silicate-metal liquid immiscibility and then injected into fissures surrounding the ascending melt column, or emplaced through a volcanic eruption. Presence of globular (occasionally with meniscus-like textures) Cu-O micro-inclusions in Cu-Ag-Au spherules confirms their crystallization from a metal melt via extremely fast cooling. Irregularly shaped Cu-Ag-Au particles were formed through hydrothermal alteration of gold-bearing volcanic rocks and ores. Association of primarily liquid Cu-Ag-Au spherules with iron-oxide mineralization in the LKR indicates possible involvement of silicate-metallic immiscibility and explosive volcanism in the formation of the Andean-type iron oxide gold-copper (IOCG) and related copper-gold porphyry deposits in the deeper parts of sub-volcanic epithermal systems. Thus, formation of gold alloys in deep roots of arc volcanoes may serve as a precursor and an exploration guide for high-grade epithermal gold mineralization at shallow structural levels of hydrothermal-volcanic environments in subduction zones.

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Genesis of volcanic rocks related to subduction zones; geochemical point of view

BSGF - Earth Sciences Bulletin ◽

10.2113/gssgfbull.s7-xix.6.1233 ◽

1977 ◽

Vol S7-XIX (6) ◽

pp. 1233-1243 ◽

Cited By ~ 4

Author(s):

C. Dupuy ◽

J. Dostal ◽

J. Vernieres

Keyword(s):

Subduction Zones ◽

Volcanic Rocks ◽

Point Of View

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Magmatic evidence for Late Carboniferous-Early Permian slab breakoff and extension of the southern Mongolia collage system in Central Asia

10.5194/egusphere-egu21-16411 ◽

2021 ◽

Author(s):

Hai Zhou ◽

Guochun Zhao ◽

Donghai Zhang

Keyword(s):

Subduction Zones ◽

Volcanic Rocks ◽

Early Carboniferous ◽

Ocean Basin ◽

Magma Source ◽

Central Asian ◽

Slab Rollback ◽

Slab Breakoff ◽

Subduction Fluids ◽

Arc Setting

Oceanic subduction and its last underthrusted part can both triggers arc-like magmatism. As the existence of multi-subduction zones in the Central Asian Orogenic Belt, controversy still surrounds on when and especially how the subduction of the (Paleo-Asian Ocean) PAO terminated. We present geochronological, geochemical, and Lu-Hf isotopic data for a suite of basalt-andesites, dacite-rhyolites and later trachyandesite-mugearitic dykes from the Khan-Bogd area in the Gobi Tianshan Zone (GTZ) of the southern Mongolia. U-Pb dating of zircons indicate the basalt-andesites and dacite-rhyolites were formed at ~334-338 Ma, and the dykes at ~300 Ma. These Early Carboniferous volcanic rocks display high U/Th, Ba/Th, low La/Sm and variable Zr/Nb ratios, implying the involvement of subduction fluids or sediment melt. They display arc geochemical features such as calc-alkaline and metaluminous nature and positive Ba and U and negative Nb, Ta and Ti anomalies. Moreover, their continental geochemical signals (e.g. positive Pb, K anomalies) and some old captured zircons implying a continental arc setting. Comparatively, the ~300 Ma dykes are characterized by high alkaline contents, which are common for coeval (~320-290 Ma) and widespread post-subductional granites there. Given a mainly crust-derived magma source for those granites, these dykes likely reflect a mantle disturbance due to: (1) their relative low SiO2 (51.71-55.85 wt. %) and high Mg# (40.3-67.3) values, and (2) positive zircon &#400;Hf(t) (most > 12). Considering a slab rollback model during the Carboniferous and Triassic, the mantle disturbance was possibly induced by the oceanic slab breakoff. Combined with previous work, this ~320-290 Ma slab breakoff-induced extension marks the closure of a wide secondary ocean (North Tianshan-Hegenshan ocean) north of the main ocean basin of the PAO. This research was financially supported by NSFC Projects (41730213, 42072264, 41902229, 41972237) and Hong Kong RGC GRF (17307918).

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A revised map of volcanic units in the Oman ophiolite: insights into the architecture of an oceanic proto-arc volcanic sequence

10.5194/se-2019-69 ◽

2019 ◽

Author(s):

Thomas M. Belgrano ◽

Larryn W. Diamond ◽

Yves Vogt ◽

Andrea R. Biedermann ◽

Samuel A. Gilgen ◽

...

Keyword(s):

Subduction Zones ◽

Sedimentary Cover ◽

Phase 1 ◽

Volcanic Rocks ◽

Shear Zones ◽

Magma Ascent ◽

Upper Crust ◽

Vms Deposits ◽

Geochemical Analyses ◽

Semail Ophiolite

Abstract. Recent studies have revealed genetic similarities between Tethyan ophiolites and oceanic proto-arc sequences formed above nascent subduction zones. The Semail ophiolite (Oman–U.A.E.) in particular can be viewed as an analogue for this proto-arc crust. Though proto-arc magmatism and the mechanisms of subduction-initiation are of great interest, insight is difficult to gain from drilling and limited surface outcrops in submarine fore-arcs. In contrast, the Semail ophiolite, in which the 3–5 km thick upper-crustal succession is exposed in an oblique cross-section, presents an opportunity to assess the architecture and volumes of different volcanic rocks that form during the protoarc stage. To determine the distribution of the volcanic rocks and to aid exploration for the volcanogenic massive sulphide (VMS) deposits that they host, we have re-mapped the volcanic units of the Semail ophiolite by integrating new field observations, geochemical analyses and geophysical interpretations with pre-existing geological maps. By linking the major element compositions of the volcanic units to rock magnetic properties, we were able to use aeromagnetic data to infer the extension of each outcropping unit below sedimentary cover, resulting in in a new map showing 2100 km2 of upper-crustal bedrock. Whereas earlier maps distinguished two main volcanostratigraphic units, we have distinguished four, recording the progression from early spreading-axis basalts (Geotimes) through to axial to off-axial depleted basalts (Lasail), to post-axial tholeiites (Tholeiitic Alley) and finally boninites (Boninitic Alley). Geotimes (Phase 1) axial dykes and lavas make up ~55 vol% of the Semail upper crust, whereas post-axial (Phase 2) lavas constitute the remaining ~ 45 vol % and ubiquitously cover the underlying axial crust. The Semail boninites occur as discontinuous accumulations up to 2 km thick at the top of the sequence and constitute ~ 15 vol % of the upper crust. The new map provides a basis for targeted exploration of the gold-bearing VMS deposits hosted by these boninites. The thickest boninite accumulations occur in the Fizh block, where magma ascent occurred along crustal-scale faults that are connected to shear zones in the underlying mantle rocks, which in turn are associated with economic chromitite deposits. Locating major boninite feeder zones may thus be an indirect means to explore for chromitites in the underlying mantle.

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Cenozoic volcanic rocks of North Kamchatka: In search of subduction zones

Geotectonics ◽

10.1134/s0016852111030071 ◽

2011 ◽

Vol 45 (3) ◽

pp. 210-224 ◽

Cited By ~ 3

Author(s):

M. N. Shapiro ◽

A. V. Solov’ev

Keyword(s):

Subduction Zones ◽

Volcanic Rocks

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Cenozoic high Sr/Y volcanic rocks in the Qiangtang terrane, northern Tibet: geochemical and isotopic evidence for the origin of delaminated lower continental melts

Geological Magazine ◽

10.1017/s0016756808004548 ◽

2008 ◽

Vol 145 (4) ◽

pp. 463-474 ◽

Cited By ~ 29

Author(s):

SHEN LIU ◽

RUI-ZHONG HU ◽

CAI-XIA FENG ◽

HAI-BO ZOU ◽

CAI LI ◽

...

Keyword(s):

Subduction Zones ◽

Volcanic Rocks ◽

Mantle Peridotite ◽

Calc Alkaline ◽

Isotopic Data ◽

Slab Melting ◽

Northern Tibet ◽

High K ◽

T Values ◽

Qiangtang Terrane

AbstractGeochemical and Sr–Nd–Pb isotopic data are presented for volcanic rocks from Zougouyouchaco (30.5 Ma) and Dogai Coring (39.7 Ma) of the southern and middle Qiangtang block in northern Tibet. The volcanic rocks are high-K calc-alkaline trachyandesites and dacites, with SiO2 contents ranging from 58.5 to 67.1 wt % The rocks are enriched in light REE (LREE) and contain high Sr (649 to 986 ppm) and relatively low Yb (0.8 to 1.2 ppm) and Y (9.5 to 16.6 ppm) contents, resulting in high La/Yb (29–58) and Sr/Y (43–92) ratios, as well as relatively high MgO contents and Mg no., similar to the compositions of adakites formed by slab melting in subduction zones. However, the adakitic rocks in the Qiangtang block are characterized by relatively low εNd(t) values (−3.8 to −5.0) and highly radiogenic Sr ((87Sr/86Sr)i=0.706–0.708), which are inconsistent with an origin by slab melting. The geochemistry and tectonics indicate that the adakitic volcanic rocks were most likely derived from partial melting of delaminated lower continental crust. As the pristine adakitic melts rose, they interacted with the surrounding mantle peridotite, elevating their MgO values and Mg numbers.

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Lithium, Oxygen and Magnesium Isotope Systematics of Volcanic Rocks in the Okinawa Trough: Implications for Plate Subduction Studies

Journal of Marine Science and Engineering ◽

10.3390/jmse10010040 ◽

2021 ◽

Vol 10 (1) ◽

pp. 40

Author(s):

Zhigang Zeng ◽

Xiaohui Li ◽

Yuxiang Zhang ◽

Haiyan Qi

Keyword(s):

Basaltic Andesite ◽

Subduction Zones ◽

Okinawa Trough ◽

Volcanic Rocks ◽

Philippine Sea Plate ◽

Material Transfer ◽

Magma Compositions ◽

Subduction Input ◽

Back Arc ◽

Plate Subduction

Determining the influence of subduction input on back-arc basin magmatism is important for understanding material transfer and circulation in subduction zones. Although the mantle source of Okinawa Trough (OT) magmas is widely accepted to be modified by subducted components, the role of slab-derived fluids is poorly defined. Here, major element, trace element, and Li, O and Mg isotopic compositions of volcanic lavas from the middle OT (MOT) and southern OT (SOT) were analyzed. Compared with the MOT volcanic lavas, the T9-1 basaltic andesite from the SOT exhibited positive Pb anomalies, significantly lower Nd/Pb and Ce/Pb ratios, and higher Ba/La ratios, indicating that subducted sedimentary components affected SOT magma compositions. The δ7Li, δ18O, and δ26Mg values of the SOT basaltic andesite (−5.05‰ to 4.98‰, 4.83‰ to 5.80‰ and −0.16‰ to −0.09‰, respectively) differed from those of MOT volcanic lavas. Hence, the effect of the Philippine Sea Plate subduction component, (low δ7Li and δ18O and high δ26Mg) on magmas in the SOT was clearer than that in the MOT. This contrast likely appears because the amounts of fluids and/or melts derived from altered oceanic crust (AOC, lower δ18O) and/or subducted sediment (lower δ7Li, higher δ18O and δ26Mg) injected into magmas in the SOT are larger than those in the MOT and because the injection ratio between subducted AOC and sediment is always >1 in the OT. The distance between the subducting slab and overlying magma may play a significant role in controlling the differences in subduction components injected into magmas between the MOT and SOT.

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Generation of Calc-Alkaline Magmas During Crystallization at High Oxygen Fugacity: An Experimental and Petrologic Study of Tephras from Buldir Volcano, Western Aleutian Arc, Alaska, USA

Journal of Petrology ◽

10.1093/petrology/egaa104 ◽

2020 ◽

Author(s):

L E Waters ◽

E Cottrell ◽

M L Coombs ◽

K A Kelley

Keyword(s):

Oxygen Fugacity ◽

Subduction Zones ◽

Volcanic Rocks ◽

High Oxygen ◽

Calc Alkaline ◽

Edge Structure ◽

Liquidus Phase ◽

High Oxygen Fugacity ◽

Alkaline Volcanism ◽

Aleutian Arc

Abstract Despite agreement that calc-alkaline volcanism occurs at subduction zones and is responsible for the genesis of continental landmasses, there is no consensus on the source of the Fe-depleted signature hallmark to calc-alkaline volcanism. In this study, we utilize mafic tephras collected from Buldir Volcano to address the genesis of strongly calc-alkaline volcanic rocks (those with a low Tholeiitic Index; ≤0.7) in a segment of the western Aleutian Arc to determine if the eruptions are plausibly part of a liquid line of descent, if they are mixtures of crustal melts and parental magmas, or if they are mixtures of melts of the mantle and the subducting slab. We conducted a series of H2O-saturated phase equilibrium experiments (1175–1000 °C; 100 MPa) in a rapid-quench cold-seal (MHC) apparatus on the most primitive natural lava from Buldir (9.34 wt% MgO) at oxidizing conditions near the Re-ReO2 buffer. We confirmed that all experiments equilibrated 0.3 ± 0.23 log units above the Re-ReO2 buffer (ΔQFM ∼ +2.8) using X-ray Absorption Near Edge Structure (XANES) spectroscopy. Chromite is the liquidus phase, followed by olivine, then plagioclase, then clinopyroxene, and finally hornblende. Once clinopyroxene saturates, spinel composition shifts to magnetite. We compared our experimental results to the major element geochemistry and petrology of six tephras (51.9–54.8 wt% SiO2) from Buldir collected during the 2015 field season of the GeoPRISMS shared platform. Tephras contain olivine + plagioclase + clinopyroxene + spinel ± hornblende; plagioclase comprises most of the crystalline volume, followed by either olivine or hornblende. Spinel is ubiquitous; with Cr- rich spinel inclusions in olivine and hornblende, and magnetite in the groundmass. Variations in phenocryst assemblages and compositions between samples can be attributed to differences in pre-eruptive temperatures, where hotter samples are devoid of hornblende, and contain Fo-rich olivine and plagioclase with lower An-contents, owing to the position of the mineral-in curves at fluid-saturated conditions. Experimental glasses match the depletion in FeOT observed in the tephra whole rock compositions. The continuous depletion in FeOT is attributable to saturation of spinel as a liquidus phase (initially as chromite) and continuous crystallization through the experimental series (changing to magnetite at colder temperatures). In contrast to the natural samples, the experiments show enrichment in TiO2 with decreasing MgO, suggesting that differentiation did not occur at 100 MPa on Buldir. The TiO2 depletion in volcanic rocks from Buldir can be accounted for if hornblende crystallization occurs close to the liquidus of a parental magma; a condition that is met at higher pressures and hydrous conditions. The emerging picture for Buldir Island is that (1) oxidizing conditions are required to drive the observed depletions in FeOT via crystallization of spinel, and (2) elevated H2O contents and high pressures are required to saturate hornblende close to the liquidus to reproduce the entire suite of major elements. Our study provides a mechanism to generate the calc-alkaline trends observed at Buldir without requiring mixing of slab and mantle melts. We conclude that calc-alkaline volcanic rocks with extremely low Tholeiitic Indices (0.7), like those from Buldir, cannot be generated in absence of high oxygen fugacity, even at high pressure and/or elevated water pressures.

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Oceanic crust generation in an island arc tectonic setting, SE Anatolian orogenic belt (Turkey)

Geological Magazine ◽

10.1017/s0016756804009458 ◽

2004 ◽

Vol 141 (5) ◽

pp. 583-603 ◽

Cited By ~ 85

Author(s):

OSMAN PARLAK ◽

VOLKER HÖCK ◽

HÜSEYİN KOZLU ◽

MICHEL DELALOYE

Keyword(s):

Late Cretaceous ◽

Subduction Zones ◽

Wide Spectrum ◽

Tectonic Setting ◽

Volcanic Rocks ◽

Orogenic Belt ◽

Mature Stage ◽

Magmatic Arc ◽

The North ◽

Suprasubduction Zone

A number of Late Cretaceous ophiolitic bodies are located between the metamorphic massifs of the southeast Anatolian orogenic system. One of them, the Göksun ophiolite (northern Kahramanmaraş), which crops out in a tectonic window bounded by the Malatya metamorphic units on both the north and south, is located in the EW-trending nappe zone of the southeast Anatolian orogenic belt between Göksun and Afşin (northern Kahramanmaraş). It consists of ultramafic–mafic cumulates, isotropic gabbro, a sheeted dyke complex, plagiogranite, volcanic rocks and associated volcanosedimentary units. The ophiolitic rocks and the tectonically overlying Malatya–Keban metamorphic units were intruded by syn-collisional granitoids (∼ 85 Ma). The volcanic units are characterized by a wide spectrum of rocks ranging in composition from basalt to rhyolite. The sheeted dykes consist of diabase and microdiorite, whereas the isotropic gabbros consist of gabbro, diorite and quartzdiorite. The magmatic rocks in the Göksun ophiolite are part of a co-magmatic differentiated series of subalkaline tholeiites. Selective enrichment of some LIL elements (Rb, Ba, K, Sr and Th) and depletion of the HFS elements (Nb, Ta, Ti, Zr) relative to N-MORB are the main features of the upper crustal rocks. The presence of negative anomalies for Ta, Nb, Ti, the ratios of selected trace elements (Nb/Th, Th/Yb, Ta/Yb) and normalized REE patterns all are indicative of a subduction-related environment. All the geochemical evidence both from the volcanic rocks and the deeper levels (sheeted dykes and isotropic gabbro) show that the Göksun ophiolite formed during the mature stage of a suprasubduction zone (SSZ) tectonic setting in the southern branch of the Neotethyan ocean between the Malatya–Keban platform to the north and the Arabian platform to the south during Late Cretaceous times. Geological, geochronological and petrological data on the Göksun ophiolite and the Baskil magmatic arc suggest that there were two subduction zones, the first one dipping beneath the Malatya–Keban platform, generating the Baskil magmatic arc and the second one further south within the ocean basin, generating the Göksun ophiolite in a suprasubduction zone environment.

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Melting of subducted sediments reconciles geophysical images of subduction zones

Nature Communications ◽

10.1038/s41467-021-21657-8 ◽

2021 ◽

Vol 12 (1) ◽

Author(s):

M. W. Förster ◽

K. Selway

Keyword(s):

Subduction Zones ◽

Source Region ◽

Volcanic Rocks ◽

Electrically Conductive ◽

Small Magnitude ◽

Volcanic Arcs ◽

Frictional Strength ◽

Episodic Tremor And Slip ◽

Episodic Tremor ◽

Sediment Melting

AbstractSediments play a key role in subduction. They help control the chemistry of arc volcanoes and the location of seismic hazards. Here, we present a new model describing the fate of subducted sediments that explains magnetotelluric models of subduction zones, which commonly show an enigmatic conductive anomaly at the trenchward side of volcanic arcs. In many subduction zones, sediments will melt trenchward of the source region for arc melts. High-pressure experiments show that these sediment melts will react with the overlying mantle wedge to produce electrically conductive phlogopite pyroxenites. Modelling of the Cascadia and Kyushu subduction zones shows that the products of sediment melting closely reproduce the magnetotelluric observations. Melting of subducted sediments can also explain K-rich volcanic rocks that are produced when the phlogopite pyroxenites melt during slab roll-back events. This process may also help constrain models for subduction zone seismicity. Since melts and phlogopite both have low frictional strength, damaging thrust earthquakes are unlikely to occur in the vicinity of the melting sediments, while increased fluid pressures may promote the occurrence of small magnitude earthquakes and episodic tremor and slip.

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