Structural characterization of partially amorphous SnO2 nanoparticles by factor analysis of XAS and FT-IR spectra

1999 ◽  
Vol 116 (1-2) ◽  
pp. 117-127 ◽  
Author(s):  
V Jiménez
Keyword(s):  
Factor Analysis ◽  
Ir Spectra ◽  
Structural Characterization ◽  
Sno2 Nanoparticles ◽  
Ft Ir

Synthesis and Structural Characterization of Mg/Al Hydrotalcite-Like Compounds

2012 ◽  
Vol 549 ◽  
pp. 353-357 ◽  
Author(s):  
Yan Guo ◽  
Wei Jun Liu ◽  
Shu Hua Zhang ◽  
Si Yuan Yang ◽  
Kai Fei Zhang ◽  
...  
Keyword(s):  
Ir Spectra ◽  
Structural Characterization ◽  
Pore Volume ◽  
Positive Charge ◽  
High Surface ◽  
High Surface Area ◽  
Total Pore Volume ◽  
Hydroxyl Groups ◽  
Ft Ir

Hydrotalcites consist of Brucite-like layers with positive charge and anionic compounds in the interlayer to form neutral materials. The general formula of hydrotalcite compounds (HTLc) was Mg-A1-HTLc. All samples were characterized by XRD, FT-IR spectra and TG. After calcination, the transformation of hydrotalcite structure can be characterized by vibration infrared bands corresponding to hydroxyl groups, octahedral layers and interlayer species. Moreover, the calcined samples show a relatively high surface area and total pore volume.

scholarly journals Synthesis and Characterization of Some Novel Oxazine, Thiazine and Pyrazol Derivatives

2016 ◽  
Vol 13 (2) ◽  
pp. 244-252
Author(s):  
Baghdad Science Journal
Keyword(s):  
Acetic Acid ◽  
Ir Spectra ◽  
Glacial Acetic Acid ◽  
Basic Medium ◽  
Synthesis And Characterization ◽  
Pyrazole Derivatives ◽  
Phenyl Hydrazine ◽  
H Nmr ◽  
Ft Ir

In this paper, some chalcone derivatives (C1, C2) were synthesized based on the reaction of equal amount of substituted acetophenone and substituted banzaldehyde in basic medium. Oxazine and thiazine derivatives were prepared from the reaction of chalcones (C1-C2) with urea and thiourea respectively in a basic medium. Pyrazole derivatives were prepared based on the reaction of chalcones with hydrazine mono hydrate or phenyl hydrazine in the presence of glacial acetic acid as a catalyst. The new synthesized compounds were identified using various physical techniques like1 H-NMR and FT-IR spectra.

scholarly journals Characterization of a Natural Dye by Spectroscopic and Chromatographic Techniques

2012 ◽  
Vol 1374 ◽  
pp. 49-59 ◽  
Author(s):  
Y. Espinosa-Morales ◽  
J. Reyes ◽  
B. Hermosín ◽  
J. A. Azamar-Barrios
Keyword(s):  
Molecular Structure ◽  
Phenolic Compounds ◽  
Central America ◽  
Structural Characterization ◽  
Chemical Properties ◽  
The Other ◽  
Chromatographic Techniques ◽  
Ft Ir ◽  
Color Source

ABSTRACTNatural dyes have been extracted from both plants and animal to give color to textiles and handicrafts. This is the case of purple dye extracted from Justicia spicigera Schldt, an acanthaceae used as a color source since pre-Hispanic period in the Mayan area of Mexico and Central America. Spectroscopic (UV-Vis and FT-IR) and chromatographic (PY-GC/MS) techniques were employed in order to characterize some of their chemical properties. UV-VIS absorption spectra indicates a λmaxpeak at 581 nm, value associated to anthocyanins group under bathochromic effect. On the other hand, a structural characterization realized by FT-IR and Py-GC/MS indicated the presence of polar hydroxibenzoic acids and phenolic compounds which are characteristics of the molecular structure of anthocyanins.

Preparation and Characterization of the Amidoxime-Modified Polyacrylonitrile (PAN-Amidoxime) Nanofibre Composite

2014 ◽  
Vol 633-634 ◽  
pp. 30-33 ◽  
Author(s):  
Min Hu ◽  
Yu Hao Ma ◽  
Zong Jie Li ◽  
Wei Min Kang ◽  
Bo Wen Cheng
Keyword(s):  
Ir Spectra ◽  
Protective Layers ◽  
Ultrasonic Bonding ◽  
Ft Ir ◽  
Bonding Method ◽  
Amidoxime Group

In this research, a kind of nonwoven composite used for the absorption of heavy mental ions has been made. The composite was made of two layers of ES thermal bonded nonwovens as the protective layers and the PAN-amidoxime nanofibers which are prepared through the modification of electrospun PAN nanofibers as the interlayer. The composition was achieved by the ultrasonic bonding method. After the composition the PAN nanofibers were modified by grafting the amidoxime group to PAN. The results of FT-IR spectra and FE-SEM indicated that nitrile groups in PAN were partly converted into amidoxime groups and there were no serious cracks on the surface of PAN-amidoxime nanofibers. The results show that the amidoxime groups have been proved to be grafted to the PAN nanofibers with the percent grafting of 81.6%.

Structural characterization of steam-heat treated Tectona grandis wood analyzed by FT-IR and 2D-IR correlation spectroscopy

2015 ◽  
Vol 26 (2) ◽  
pp. 221-225 ◽  
Author(s):  
Ming-Yu Li ◽  
Shi-Chao Cheng ◽  
Dan Li ◽  
Shen-Nan Wang ◽  
An-Min Huang ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Tectona Grandis ◽  
Correlation Spectroscopy ◽  
2D Ir ◽  
Heat Treated ◽  
Ft Ir ◽  
Steam Heat

Spectroscopic characterization of enzymatic flax retting: Factor analysis of FT-IR and FT-Raman data

1998 ◽  
Author(s):  
D. D. Archibald ◽  
G. Henrikssen ◽  
D. E. Akin ◽  
F. E. Barton
Keyword(s):  
Factor Analysis ◽  
Spectroscopic Characterization ◽  
Ft Ir ◽  
Ft Raman

One- and two-dimensional PbII compounds resulting from reaction of PbBr2 and Pb(SCN)2 with pyrimidine-2-thione

2021 ◽  
Vol 77 (7) ◽  
Author(s):  
Vânia Denise Schwade ◽  
Bárbara Tirloni
Keyword(s):  
Structural Characterization ◽  
Diffuse Reflectance ◽  
Tautomeric Form ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Ft Ir ◽  
Compound Ii

Pyrimidine-2-thione (HSpym) reacts with lead(II) thiocyanate and lead(II) bromide in N,N-dimethylformamide (DMF) to form poly[(μ-isothiocyanato-κ2 N:S)(μ4-pyrimidine-2-thiolato-κ6 N 1,S:S:S:S,N 3)lead(II)], [Pb(C4H3N2S)(NCS)] n or [Pb(Spym)(NCS)] n , (I), and the polymeric one-dimensional (1D) compound catena-poly[[μ4-bromido-di-μ-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)] N,N-dimethylformamide monosolvate], {[Pb2Br3(C4H3N2S)(C4H4N2S)]·C3H7NO} n or {[Pb2Br3(Spym)(HSpym)]·DMF} n , (IIa), respectively. Poly[μ4-bromido-di-μ3-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)], [Pb2Br3(C4H3N2S)(C4H4N2S)] n or [Pb2Br3(Spym)(HSpym)] n , (IIb), could be obtained as a mixture with (IIa) when using a lesser amount of solvent. In the crystal structures of the pseudohalide/halide PbII stable compounds, coordination of anionic and neutral HSpym has been observed. Both Spym− (in the thiolate tautomeric form) and NCS− ligands were responsible for the two-dimensional (2D) arrangement in (I). The Br− ligands establish the 1D polymeric arrangement in (IIa). Eight-coordinated metal centres have been observed in both compounds, when considering the Pb...S and Pb...Br interactions. Both compounds were characterized by FT–IR and diffuse reflectance spectroscopies, as well as by powder X-ray diffraction. Compound (IIa) and its desolvated version (IIb) represent the first structurally characterized PbII compounds containing neutral HSpym and anionic Spym− ligands. After a prolonged time in solution, (IIa) is converted to another compound due to complete deprotonation of HSpym. The structural characterization of (I) and (II) suggests HSpym as a good candidate for the removal of PbII ions from solutions containing thiocyanate or bromide ions.

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