Phase behavior of isotactic polypropylene/C4-solvents at high pressure. Experimental data and SAFT modeling

2001 ◽  
Vol 21 (2) ◽  
pp. 93-103 ◽  
Author(s):  
P.M. Ndiaye ◽  
C. Dariva ◽  
J. Vladimir Oliveira ◽  
F.W. Tavares
Keyword(s):  
Experimental Data ◽  
High Pressure ◽  
Phase Behavior ◽  
Isotactic Polypropylene

scholarly journals Phase Behavior at High Pressure of the Ternary System: CO2, Ionic Liquid and Disperse Dye

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Helen R. Mazzer ◽  
José C. O. Santos ◽  
Vladimir F. Cabral ◽  
Claudio Dariva ◽  
Marcos H. Kunita ◽  
...  
Keyword(s):  
Experimental Data ◽  
Carbon Dioxide ◽  
High Pressure ◽  
Phase Behavior ◽  
Ternary Systems ◽  
High Pressure Phase Behavior ◽  
Phase Transition Pressure ◽  
Binary And Ternary Systems ◽  
Pressure Phase ◽  
Good Agreement

High pressure phase behavior experimental data have been measured for the systems carbon dioxide (CO2) + 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim] [PF6]) and carbon dioxide (CO2) + 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim] [PF6]) + 1-amino-2-phenoxy-4-hydroxyanthraquinone (C.I. Disperse Red 60). Measurements were performed in the pressure up to 18 MPa and at the temperature (323 to 353 K). As reported in the literature, at higher concentrations of carbon dioxide the phase transition pressure increased very steeply. The experimental data for the binary and ternary systems were correlated with good agreement using the Peng-Robinson equation of state. The amount of water in phase behavior of the systems was evaluated.

Properties of nanocomposites based on isotactic polypropylene and high-pressure polyethylene with metal-containing nanofillers

2020 ◽  
pp. 59-64
Author(s):  
N. I. Kurbanova ◽  
◽  
T. M. Gulieva ◽  
N. Ya. Ischenko ◽  
◽  
...  
Keyword(s):  
High Pressure ◽  
Synergistic Effect ◽  
Polymer Matrix ◽  
Isotactic Polypropylene ◽  
Rheological Parameters ◽  
Mechanochemical Method ◽  
X Ray ◽  
Effect Of Additives ◽  
High Pressure Polyethylene ◽  
Properties Of Composites

The effect of additives of nanofillers (NF) containing nanoparticles (NP) of copper oxide, stabilized by a polymer matrix of maleized polyethylene (MPE), obtained by the mechanochemical method, on the properties of composites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) was studied by X-ray phase (XRD) and thermogravimetric (TGA) analyzes. The enhancement of strength, deformation, and rheological parameters, as well as the thermo-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is due to the synergistic effect of the interaction of copper-containing nanoparticles with anhydride groups of MPE. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing and injection molding and extrusion, which expands the scope of its application.

scholarly journals Revisiting Kelvin equation and Peng–Robinson equation of state for accurate modeling of hydrocarbon phase behavior in nano capillaries

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ilyas Al-Kindi ◽  
Tayfun Babadagli
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Equation Of State ◽  
Phase Behavior ◽  
Pore Radius ◽  
Microfluidic Chips ◽  
Tight Sandstone ◽  
Kelvin Equation ◽  
Rock Samples ◽  
Robinson Equation

AbstractThe thermodynamics of fluids in confined (capillary) media is different from the bulk conditions due to the effects of the surface tension, wettability, and pore radius as described by the classical Kelvin equation. This study provides experimental data showing the deviation of propane vapour pressures in capillary media from the bulk conditions. Comparisons were also made with the vapour pressures calculated by the Peng–Robinson equation-of-state (PR-EOS). While the propane vapour pressures measured using synthetic capillary medium models (Hele–Shaw cells and microfluidic chips) were comparable with those measured at bulk conditions, the measured vapour pressures in the rock samples (sandstone, limestone, tight sandstone, and shale) were 15% (on average) less than those modelled by PR-EOS.

Microemulsion Phase Behavior Observations, Thermodynamic Essentials, Mathematical Simulation

1981 ◽  
Vol 21 (06) ◽  
pp. 747-762 ◽  
Author(s):  
Karl E. Bennett ◽  
Craig H.K. Phelps ◽  
H. Ted Davis ◽  
L.E. Scriven
Keyword(s):  
Experimental Data ◽  
Phase Behavior ◽  
Experimental Studies ◽  
Mathematical Framework ◽  
Alkyl Aryl Sulfonate ◽  
Phase Volume ◽  
Displacement Efficiency ◽  
Alkyl Aryl ◽  
Theoretical Understanding ◽  
Tie Lines

Abstract The phase behavior of microemulsions of brine, hydrocarbon, alcohol, and a pure alkyl aryl sulfonate-sodium 4-(1-heptylnonyl) benzenesulfonate (SHBS or Texas 1) was investigated as a function of the concentration of salt (NaCl, MgCl2, or CaCl2), the hydrocarbon (n-alkanes, octane to hexadecane), the alcohol (butyl and amyl isomers), the concentration of surfactant, and temperature. The phase behavior mimics that of similar systems with the commercial surfactant Witco TRS 10–80. The phase volumes follow published trends, though with exceptions.A mathematical framework is presented for modeling phase behavior in a manner consistent with the thermodynamically required critical tie lines and plait point progressions from the critical endpoints. Hand's scheme for modeling binodals and Pope and Nelson's approach to modeling the evolution of the surfactant-rich third phase are extended to satisfy these requirements.An examination of model-generated progressions of ternary phase diagrams enhances understanding of the experimental data and reveals correlations of relative phase volumes (volume uptakes) with location of the mixing point (overall composition) relative to the height of the three-phase region and the locations of the critical tie lines (critical endpoints and conjugate phases). The correlations account, on thermodynamic grounds, for cases in which the surfactant is present in more than one phase or the phase volumes change discontinuously, both cases being observed in the experimental study. Introduction The phase behavior of a surfactant-based micellar formulation is one of the major factors governing the displacement efficiency of any chemical flooding process employing that formulation. Knowledge of phase behavior is, thus, important for the interpretation of laboratory core floods, the design of flooding processes, and the evaluation of field tests. Phase behavior is connected intimately with other determinants of the flooding process, such as interfacial tension and viscosity. Since the number of equilibrium phases and their volumes and appearances are easier to measure and observe than phase compositions, viscosities, and interfacial tensions, there is great interest in understanding the phase-volume/phase-property relationships. Commercial surfactants, such as Witco TRS 10-80, are sulfonates of crude or partially refined oil. While they seem to be the most economically practicable surfactants for micellar flooding, their behavior, particularly with crude oils and reservoir brines, can be difficult to interpret, the phases varying with time and from batch to batch. Phase behavior studies with a small number of components, in conjunction with a theoretical understanding of phase behavior progressions, can aid in understanding more complex behavior. In particular, one can begin to appreciate which seemingly abnormal experimental observations (e.g., surfactant present in more than one phase or a discontinuity in phase volume trends) are merely features of certain regions of any phase diagram and which are peculiar to the specific crude oil or commercial surfactant used in the study.We report here experimental studies of the phase behavior of microemulsions of a pure sulfonate surfactant (Texas 1), a single normal alkane hydrocarbon, a simple brine, and a small amount of a suitable alcohol as cosurfactant or cosolvent. The controlled variables are hydrocarbon chain length, alcohol, salinity, salt type (NaCl, MgCl2, or CaCl2), surfactant purity, surfactant concentration, and temperature. Many of these experimental data were presented earlier. SPEJ P. 747^

3D-Atom Probe Investigation of Vacancy Induced Interdiffusion during High Pressure Torsion Deformation

2006 ◽  
Vol 503-504 ◽  
pp. 433-438 ◽  
Author(s):  
Xavier Sauvage
Keyword(s):  
Experimental Data ◽  
High Pressure ◽  
Long Range ◽  
High Pressure Torsion ◽  
Pearlitic Steel ◽  
Atom Probe ◽  
Concentration Gradients ◽  
Deformed State ◽  
Torsion Deformation ◽  
Probe Investigation

Concentration gradients resulting from long range diffusion during Severe Plastic Deformation (SPD) have been investigated with the 3D Atom Probe technique (3D-AP). First, in a pearlitic steel where alloying elements (Mn, Si and Cr) are partitioned between the ferrite and carbides in the non-deformed state. After processing by High Pressure Torsion (HPT), they are homogeneously distributed in the nanostructure, indicating that long range diffusion occurred along with the dissolution of carbides. 3D-AP data of a Cu-Fe composite processed by HPT show as well a significant interdiffusion of Cu and Fe, probably promoted by additional vacancies. On the basis of these experimental data, and using the theory described for irradiated materials, vacancy fluxes and vacancy production rates were estimated assuming that new vacancies are continuously produced and eliminated on grain boundaries.

High-Pressure Phase Behavior of Systems with Ionic Liquids:  Part IV. Binary System Carbon Dioxide + 1-Hexyl-3-methylimidazolium Tetrafluoroborate

2005 ◽  
Vol 50 (1) ◽  
pp. 52-55 ◽  
Author(s):  
Marco Costantini ◽  
Vincent A. Toussaint ◽  
Alireza Shariati ◽  
Cor J. Peters ◽  
Ireneo Kikic
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Ionic Liquids ◽  
Binary System ◽  
Phase Behavior ◽  
High Pressure Phase ◽  
High Pressure Phase Behavior ◽  
Pressure Phase

scholarly journals CO2 Induced Foaming Behavior of Polystyrene near the Glass Transition

2017 ◽  
Vol 2017 ◽  
pp. 1-15
Author(s):  
Salah Al-Enezi
Keyword(s):  
Experimental Data ◽  
High Pressure ◽  
Glass Transition ◽  
Dissolved Gas ◽  
Foaming Process ◽  
Foaming Behavior ◽  
Potential Applications ◽  
Model C ◽  
Parameter Values ◽  
Good Agreement

This paper examines the effect of high-pressure carbon dioxide on the foaming process in polystyrene near the glass transition temperature and the foaming was studied using cylindrical high-pressure view cell with two optical windows. This technique has potential applications in the shape foaming of polymers at lower temperatures, dye impregnation, and the foaming of polystyrene. Three sets of experiments were carried out at operating temperatures of 50, 70, and 100°C, each over a range of pressures from 24 to 120 bar. Foaming was not observed when the polymer was initially at conditions below Tg but was observed above Tg. The nucleation appeared to occur randomly leading to subsequent bubble growth from these sites, with maximum radius of 0.02–0.83 mm. Three models were applied on the foaming experimental data. Variable diffusivity and viscosity model (Model C) was applied to assess the experimental data with the WLF equation. The model shows very good agreement by using realistic parameter values. The expansion occurs by diffusion of a dissolved gas from the supersaturated polymer envelope into the bubble.

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