scholarly journals Flame front/turbulence interaction for syngas fuels in the thin reaction zones regime: turbulent and stretched laminar flame speeds at elevated pressures and temperatures

2013 ◽  
Vol 724 ◽  
pp. 36-68 ◽  
Author(s):  
S. Daniele ◽  
J. Mantzaras ◽  
P. Jansohn ◽  
A. Denisov ◽  
K. Boulouchos

AbstractExperiments were performed in dump-stabilized axisymmetric flames to assess turbulent flame speeds (${S}_{T} $) and mean flamelets speeds (stretched laminar flame speeds, ${S}_{L, k} $). Fuels with significantly different thermodiffusive properties have been investigated, ranging from pure methane to syngas (${\mathrm{H} }_{2} \text{{\ndash}} \mathrm{CO} $ blends) and pure hydrogen, while the pressure was varied from 0.1 to 1.25 MPa. Flame front corrugation was measured with planar laser-induced fluorescence (PLIF) of the OH radical, while turbulence quantities were determined with particle image velocimetry (PIV). Two different analyses based on mass balance were performed on the acquired flame images. The first method assessed absolute values of turbulent flame speeds and the second method, by means of an improved fractal methodology, provided normalized turbulent flame speeds (${S}_{T} / {S}_{L, k} $). Deduced average Markstein numbers exhibited a strong dependence on pressure and hydrogen content of the reactive mixture. It was shown that preferential-diffusive-thermal (PDT) effects acted primarily on enhancing the stretched laminar flame speeds rather than on increasing the flame front corrugations. Interaction between flame front and turbulent eddies measured by the fractal dimension was shown to correlate with the eddy temporal activity.

Author(s):  
Pradeep Parajuli ◽  
Tyler Paschal ◽  
Mattias A. Turner ◽  
Eric L. Petersen ◽  
Waruna D. Kulatilaka

Abstract Natural gas is a major fuel source for many industrial and power-generation applications. The primary constituent of natural gas is methane (CH4), while smaller quantities of higher order hydrocarbons such as ethane (C2H6) and propane (C3H8) can also be present. Detailed understanding of natural gas combustion is important to obtain the highest possible combustion efficiency with minimal environmental impact in devices such as gas turbines and industrial furnaces. For a better understanding the combustion performance of natural gas, several important parameters to study are the flame temperature, heat release zone, flame front evolution, and laminar flame speed as a function of flame equivalence ratio. Spectrally and temporally resolved, high-speed chemiluminescence imaging can provide direct measurements of some of these parameters under controlled laboratory conditions. A series of experiments were performed on premixed methane/ethane-air flames at different equivalence ratios inside a closed flame speed vessel that allows the direct observation of the spherically expanding flame front. The vessel was filled with the mixtures of CH4 and C2H6 along with respective partial pressures of O2 and N2, to obtain the desired equivalence ratios at 1 atm initial pressure. A high-speed camera coupled with an image intensifier system was used to capture the chemiluminescence emitted by the excited hydroxyl (OH*) and methylidyne (CH*) radicals, which are two of the most important species present in the natural gas flames. The calculated laminar flame speeds for an 80/20 methane/ethane blend based on high-speed chemiluminescence images agreed well with the previously conducted Z-type schlieren imaging-based measurements. A high-pressure test, conducted at 5 atm initial pressure, produced wrinkles in the flame and decreased flame propagation rate. In comparison to the spherically expanding laminar flames, subsequent turbulent flame studies showed the sporadic nature of the flame resulting from multiple flame fronts that were evolved discontinuously and independently with the time. This paper documents some of the first results of quantitative spherical flame speed experiments using high-speed chemiluminescence imaging.


Processes ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 1894
Author(s):  
Li Yang ◽  
Wubin Weng ◽  
Yanqun Zhu ◽  
Yong He ◽  
Zhihua Wang ◽  
...  

Syngas produced by gasification, which contains a high hydrogen content, has significant potential. The variation in the hydrogen content and dilution combustion are effective means to improve the steady combustion of syngas and reduce NOx emissions. OH planar laser-induced fluorescence technology (OH-PLIF) was applied in the present investigation of the turbulence of a premixed flame of syngas with varied compositions of H2/CO. The flame front structure and turbulent flame velocities of syngas with varied compositions and turbulent intensities were analyzed and calculated. Results showed that the trend in the turbulent flame speed with different hydrogen proportions and dilutions was similar to that of the laminar flame speed of the corresponding syngas. A higher hydrogen proportion induced a higher turbulent flame speed, higher OH concentration, and a smaller flame. Dilution had the opposite effect. Increasing the Reynolds number also increased the turbulent flame speed and OH concentration. In addition, the effect of the turbulence on the combustion of syngas was independent of the composition of syngas after the analysis of the ratio between the turbulent flame speed and the corresponding laminar flame speed, for the turbulent flames under low turbulent intensity. These research results provide a theoretical basis for the practical application of syngas with a complex composition in gas turbine power generation.


Author(s):  
A. Morones ◽  
S. Ravi ◽  
D. Plichta ◽  
E. L. Petersen ◽  
N. Donohoe ◽  
...  

Hydrogen-based fuels have become a primary interest in the gas turbine market. To better predict the reactivity of mixtures containing different levels of hydrogen, laminar and turbulent flame speed experiments have been conducted. The laminar flame speed measurements were performed for various methane and natural gas surrogate blends with significant amounts of hydrogen at elevated pressures (up to 5 atm) and temperatures (up to 450 K) using a heated, high-pressure, cylindrical, constant-volume vessel. The hydrogen content ranged from 50% to 90% by volume. All measurements were compared to a chemical kinetic model, and good agreement within experimental measurement uncertainty was observed over most conditions. Turbulent combustion experiments were also performed for pure H2 and 50:50 H2:CH4 mixtures using a fan-stirred flame speed vessel. All tests were made with a fixed integral length scale of 27 mm and with a turbulent intensity level of 1.5 m/s at 1 atm initial pressure. Most of the turbulent flame speed results were in either the corrugated or thin reaction zones when plotted on a Borghi diagram, with Damköhler numbers up to 100 and turbulent Reynolds numbers between about 100 and 450. Flame speeds for a 50:50 blend of H2:CH4 for both laminar and turbulent cases were about a factor of 1.8 higher than for pure methane.


Author(s):  
Eoin M. Burke ◽  
Felix Güthe ◽  
Rory F. D. Monaghan

The aim of this work is to provide insight into the state-of-the-art turbulent flame speed (ST) correlations and to determine the most appropriate correlations to use under different turbulent premixed combustion conditions. The accuracies of 16 correlations for ST are determined using a large volume of data over a range of conditions. Accuracy is based on a mean absolute percentage error (MAPE). The comparison is completed once using the original authors’ adjustable parameters and a second time using parameters proposed by the current work that minimize MAPE for four different groups of data. Based on the results of the analysis using the newly-suggested parameters, the five most accurate correlations are then further examined to evaluate their respective abilities to predict trends under various turbulent conditions. While many correlations perform well over the range of data (MAPE < 33%), no single correlation can predict all experimentally-observed trends for methane flames under these conditions. Further issues are found when predicting trends for larger hydrocarbons; ethane and propane. Although low errors are again found (MAPE < 25%), correlations are not generally able to replicate the observed trends of experimental data for C2H6 and C3H8. While it is commonly accepted that no single correlation can accurately predict ST, this work has shown that the correlation derived by Muppala provides the closest overall agreement to the data examined. However it cannot be defined as a general correlation. For this reason the authors have proposed to continue development of an ST modeling tool based on a modified version of the Cantera 1D freely propagating laminar flame speed (SL) code. Greater cooperation in the ST research community to expand the range of available experimental data and better enable direct comparison of data and correlations from different experiments is also recommended.


Author(s):  
Matthieu A. Andre ◽  
Philippe M. Bardet

Shear instabilities induced by the relaxation of laminar boundary layer at the free surface of a high speed liquid jet are investigated experimentally. Physical insights into these instabilities and the resulting capillary wave growth are gained by performing non-intrusive measurements of flow structure in the direct vicinity of the surface. The experimental results are a combination of surface visualization, planar laser induced fluorescence (PLIF), particle image velocimetry (PIV), and particle tracking velocimetry (PTV). They suggest that 2D spanwise vortices in the shear layer play a major role in these instabilities by triggering 2D waves on the free surface as predicted by linear stability analysis. These vortices, however, are found to travel at a different speed than the capillary waves they initially created resulting in interference with the waves and wave growth. A new experimental facility was built; it consists of a 20.3 × 146.mm rectangular water wall jet with Reynolds number based on channel depth between 3.13 × 104 to 1.65 × 105 and 115. to 264. based on boundary layer momentum thickness.


Author(s):  
Sean D. Salusbury ◽  
Ehsan Abbasi-Atibeh ◽  
Jeffrey M. Bergthorson

Differential diffusion effects in premixed combustion are studied in a counter-flow flame experiment for fuel-lean flames of three fuels with different Lewis numbers: methane, propane, and hydrogen. Previous studies of stretched laminar flames show that a maximum reference flame speed is observed for mixtures with Le ≳ 1 at lower flame-stretch values than at extinction, while the reference flame speed for Le ≪ 1 increases until extinction occurs when the flame is constrained by the stagnation point. In this work, counter-flow flame experiments are performed for these same mixtures, building upon the laminar results by using variable high-blockage turbulence-generating plates to generate turbulence intensities from the near-laminar u′/SLo=1 to the maximum u′/SLo achievable for each mixture, on the order of u′/SLo=10. Local, instantaneous reference flamelet speeds within the turbulent flame are extracted from high-speed PIV measurements. Instantaneous flame front positions are measured by Rayleigh scattering. The probability-density functions (PDFs) of instantaneous reference flamelet speeds for the Le ≳ 1 mixtures illustrate that the flamelet speeds are increasing with increasing turbulence intensity. However, at the highest turbulence intensities measured in these experiments, the probability seems to drop off at a velocity that matches experimentally-measured maximum reference flame speeds in previous work. In contrast, in the Le ≪ 1 turbulent flames, the most-probable instantaneous reference flamelet speed increases with increasing turbulence intensity and can, significantly, exceed the maximum reference flame speed measured in counter-flow laminar flames at extinction, with the PDF remaining near symmetric for the highest turbulence intensities. These results are reinforced by instantaneous flame position measurements. Flame-front location PDFs show the most probable flame location is linked both to the bulk flow velocity and to the instantaneous velocity PDFs. Furthermore, hydrogen flame-location PDFs are recognizably skewed upstream as u′/SLo increases, indicating a tendency for the Le ≪ 1 flame brush to propagate farther into the unburned reactants against a steepening average velocity gradient.


Author(s):  
P. Griebel ◽  
R. Bombach ◽  
A. Inauen ◽  
R. Scha¨ren ◽  
S. Schenker ◽  
...  

The present experimental study focuses on flame characteristics and turbulent flame speeds of lean premixed flames typical for stationary gas turbines. Measurements were performed in a generic combustor at a preheating temperature of 673 K, pressures up to 14.4 bars (absolute), a bulk velocity of 40 m/s, and an equivalence ratio in the range of 0.43–0.56. Turbulence intensities and integral length scales were measured in an isothermal flow field with Particle Image Velocimetry (PIV). The turbulence intensity (u′) and the integral length scale (LT) at the combustor inlet were varied using turbulence grids with different blockage ratios and different hole diameters. The position, shape, and fluctuation of the flame front were characterized by a statistical analysis of Planar Laser Induced Fluorescence images of the OH radical (OH-PLIF). Turbulent flame speeds were calculated and their dependence on operating conditions (p, φ) and turbulence quantities (u′, LT) are discussed and compared to correlations from literature. No influence of pressure on the most probable flame front position or on the turbulent flame speed was observed. As expected, the equivalence ratio had a strong influence on the most probable flame front position, the spatial flame front fluctuation, and the turbulent flame speed. Decreasing the equivalence ratio results in a shift of the flame front position farther downstream due to the lower fuel concentration and the lower adiabatic flame temperature and subsequently lower turbulent flame speed. Flames operated at leaner equivalence ratios show a broader spatial fluctuation as the lean blow-out limit is approached and therefore are more susceptible to flow disturbances. In addition, because of a lower turbulent flame speed these flames stabilize farther downstream in a region with higher velocity fluctuations. This increases the fluctuation of the flame front. Flames with higher turbulence quantities (u′, LT) in the vicinity of the combustor inlet exhibited a shorter length and a higher calculated flame speed. An enhanced turbulent heat and mass transport from the recirculation zone to the flame root location due to an intensified mixing which might increase the preheating temperature or the radical concentration is believed to be the reason for that.


Author(s):  
M. El-Gamal ◽  
E. Gutheil ◽  
J. Warnatz

In high-pressure flames that occur in many practical combustion devices such as industrial furnaces, rocket propulsion and internal engine combustion, the assumption of an ideal gas is not appropriate. The present paper presents a model that includes modifications of the equation of state, transport and thermodynamic properties. The model is implemented into a Fortran program that was developed to simulate numerically one-dimensional planar premixed flames. The influence of the modifications for the real gas behavior on the laminar flame speed and on flame structure is illustrated for stoichiometric H


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