scholarly journals Direct numerical simulation of turbulent scalar transport across a flat surface

2014 ◽  
Vol 744 ◽  
pp. 217-249 ◽  
Author(s):  
H. Herlina ◽  
J. G. Wissink

AbstractTo elucidate the physical mechanisms that play a role in the interfacial transfer of atmospheric gases into water, a series of direct numerical simulations of mass transfer across the air–water interface driven by isotropic turbulence diffusing from below has been carried out for various turbulent Reynolds numbers ($R_T=84,195,507$). To allow a direct (unbiased) comparison of the instantaneous effects of scalar diffusivity, in each of the DNS up to six scalar advection–diffusion equations with different Schmidt numbers were solved simultaneously. As far as the authors are aware this is the first simulation that is capable to accurately resolve the realistic Schmidt number, $\mathit{Sc}=500$, that is typical for the transport of atmospheric gases such as oxygen in water. For the range of turbulent Reynolds numbers and Schmidt numbers considered, the normalized transfer velocity $K_L$ was found to scale with $R_T^{-{1/2}}$ and $\mathit{Sc}^{-{1/2}}$, which indicates that the largest eddies present in the isotropic turbulent flow introduced at the bottom of the computational domain tend to determine the mass transfer. The $K_L$ results were also found to be in good agreement with the surface divergence model of McCready, Vassiliadou & Hanratty (AIChE J., vol. 32, 1986, pp. 1108–1115) when using a constant of proportionality of 0.525. Although close to the surface large eddies are responsible for the bulk of the gas transfer, it was also observed that for higher $R_T$ the influence of smaller eddies becomes more important.

2017 ◽  
Vol 830 ◽  
pp. 5-34 ◽  
Author(s):  
J. G. Wissink ◽  
H. Herlina ◽  
Y. Akar ◽  
M. Uhlmann

The influence of surface contamination upon the mass transfer rate of a low diffusivity gas across a flat surface is studied using direct numerical simulations. The interfacial mass transfer is driven by isotropic turbulence diffusing from below. Similar to Shen et al. (J. Fluid Mech., vol. 506, 2004, pp. 79–115) the surface contamination is modelled by relating the normal gradient of the horizontal velocities at the top to the horizontal gradients of the surfactant concentrations. A broad range of contamination levels is considered, including clean to severely contaminated conditions. The time-averaged results show a strong correlation between the gas transfer velocity and the clean surface fraction of the surface area. In the presence of surface contamination the mass transfer velocity $K_{L}$ is found to scale as a power of the Schmidt number, i.e. $Sc^{-q}$, where $q$ smoothly transitions from $q=1/2$ for clean surfaces to $q=2/3$ for very dirty interfaces. A power law $K_{L}\propto Sc^{-q}$ is proposed in which both the exponent $q$ and the constant of proportionality become functions of the clean surface fraction.


2016 ◽  
Vol 797 ◽  
pp. 665-682 ◽  
Author(s):  
H. Herlina ◽  
J. G. Wissink

Direct numerical simulations were performed to investigate the effect of severe contamination on interfacial gas transfer in the presence of isotropic turbulence diffusing from below. A no-slip boundary condition was employed at the interface to model the severe contamination effect. The influence of both Schmidt number ($Sc$) and turbulent Reynolds number ($R_{T}$) on the transfer velocity ($K_{L}$) was studied. In the range from $Sc=2$ up to $Sc=500$ it was found that $K_{L}\propto Sc^{-2/3}$, which is in agreement with predictions based on solid–liquid transport models, see e.g. Davies (1972, Turbulence Phenomena, Academic). For similar $R_{T}$, the transfer velocity was observed to reduce significantly compared with the free-slip conditions. The reduction becomes more pronounced with increasing Schmidt number. Similar to the observation for free-slip conditions made by Theofanous et al. (Intl J. Heat Mass Transfer, vol. 19 (6), 1976, pp. 613–624), the normalized $K_{L}$ in the present no-slip case was also found to depend on $R_{T}^{-1/2}$ and $R_{T}^{-1/4}$ for small and large turbulent Reynolds numbers, respectively.


2015 ◽  
Vol 787 ◽  
pp. 508-540 ◽  
Author(s):  
J. G. Wissink ◽  
H. Herlina

A series of direct numerical simulations of mass transfer across the air–water interface driven by buoyancy-induced convection have been carried out to elucidate the physical mechanisms that play a role in the transfer of heat and atmospheric gases. The buoyant instability is caused by the presence of a thin layer of cold water situated on top of a body of warm water. In time, heat and atmospheric gases diffuse into the uppermost part of the thermal boundary layer and are subsequently transported down into the bulk by falling sheets and plumes of cold water. Using a specifically designed numerical code for the discretization of scalar convection and diffusion, it was possible to accurately resolve this buoyant-instability-induced transport of atmospheric gases into the bulk at a realistic Prandtl number ($\mathit{Pr}=6$) and Schmidt numbers ranging from$\mathit{Sc}=20$to$\mathit{Sc}=500$. The simulations presented here provided a detailed insight into instantaneous gas transfer processes. The falling plumes with highly gas-saturated fluid in their core were found to penetrate deep inside the bulk. With an initial temperature difference between the water surface and the bulk of slightly above$2$ K, peaks in the instantaneous heat flux in excess of$1600~\text{W}~\text{m}^{-2}$were observed, proving the potential effectiveness of buoyant-convective heat and gas transfer. Furthermore, the validity of the scaling law for the ratio of gas and heat transfer velocities$K_{L}/H_{L}\propto (\mathit{Pr}/\mathit{Sc})^{0.5}$for the entire range of Schmidt numbers considered was confirmed. A good time-accurate approximation of$K_{L}$was found using surface information such as velocity fluctuations and convection cell size or surface divergence. A reasonable time accuracy for the$K_{L}$estimation was obtained using the horizontal integral length scale and the root mean square of the horizontal velocity fluctuations in the upper part of the bulk.


2016 ◽  
Vol 799 ◽  
pp. 352-382 ◽  
Author(s):  
D. Buaria ◽  
P. K. Yeung ◽  
B. L. Sawford

Statistics of the trajectories of molecules diffusing via Brownian motion in a turbulent flow are extracted from simulations of stationary isotropic turbulence, using a postprocessing approach applicable in both forward and backward reference frames. Detailed results are obtained for Schmidt numbers ($Sc$) from 0.001 to 1000 at Taylor-scale Reynolds numbers up to 1000. The statistics of displacements of single molecules compare well with the earlier theoretical work of Saffman (J. Fluid Mech. vol. 8, 1960, pp. 273–283) except for the scaling of the integral time scale of the fluid velocity following the molecular trajectories. For molecular pairs we extend Saffman’s theory to include pairs of small but finite initial separation, which is in excellent agreement with numerical results provided that data are collected at sufficiently small times. At intermediate times the separation statistics of molecular pairs exhibit a more robust Richardson scaling behaviour than for the fluid particles. The forward scaling constant is very close to 0.55, whereas the backward constant is approximately 1.53–1.57, with a weak Schmidt number dependence, although no scaling exists if $Sc\ll 1$ at the Reynolds numbers presently accessible. An important innovation in this work is to demonstrate explicitly the practical utility of a Lagrangian description of turbulent mixing, where molecular displacements and separations in the limit of small backward initial separation can be used to calculate the evolution of scalar fluctuations resulting from a known source function in space. Lagrangian calculations of the production and dissipation rates of the scalar fluctuations are shown to agree very well with Eulerian results for the case of passive scalars driven by a uniform mean gradient. Although the Eulerian–Lagrangian comparisons are made only for $Sc\sim O(1)$, the Lagrangian approach is more easily extended to both very low and very high Schmidt numbers. The well-known scalar dissipation anomaly is accordingly also addressed in a Lagrangian context.


Author(s):  
D. Ambesi ◽  
C. R. Kleijn

We study laminar forced convection mass transfer to single layer arrays of equidistantly and non-equidistantly spaced micro-spheres. We report average Sherwood numbers as a function of geometry and flow conditions, for open frontal area fractions between 0.04 and 0.95, Schmidt numbers between 0.7 and 10, and Reynolds numbers (based on micro-sphere diameter and the free stream velocity) between 0.1 and 100. For equidistantly spaced arrays of micro-spheres we propose a general analytical expression for the average Sherwood number as a function of the Reynolds number, Schmidt number and the open frontal area fraction, as well as asymptotic scaling rules for small and large Reynolds. For all studied Schmidt numbers, equidistant arrays exhibit decreasing average Sherwood numbers for decreasing open frontal area fractions at low Reynolds numbers. For high Reynolds numbers, the Sherwood number approaches that of a single spheres in cross-flow, independent of the open frontal area fraction. For equal open frontal area fractions, the Sherwood number in non-equidistant arrays is lower than in equidistant arrays for intermediate Reynolds numbers. For very low and high Reynolds numbers, non-uniformity does not influence mass transfer.


2016 ◽  
Vol 796 ◽  
pp. 617-658 ◽  
Author(s):  
Peter J. Ireland ◽  
Andrew D. Bragg ◽  
Lance R. Collins

In this study, we analyse the statistics of both individual inertial particles and inertial particle pairs in direct numerical simulations of homogeneous isotropic turbulence in the absence of gravity. The effect of the Taylor microscale Reynolds number, $R_{{\it\lambda}}$, on the particle statistics is examined over the largest range to date (from $R_{{\it\lambda}}=88$ to 597), at small, intermediate and large Kolmogorov-scale Stokes numbers $St$. We first explore the effect of preferential sampling on the single-particle statistics and find that low-$St$ inertial particles are ejected from both vortex tubes and vortex sheets (the latter becoming increasingly prevalent at higher Reynolds numbers) and preferentially accumulate in regions of irrotational dissipation. We use this understanding of preferential sampling to provide a physical explanation for many of the trends in the particle velocity gradients, kinetic energies and accelerations at low $St$, which are well represented by the model of Chun et al. (J. Fluid Mech., vol. 536, 2005, pp. 219–251). As $St$ increases, inertial filtering effects become more important, causing the particle kinetic energies and accelerations to decrease. The effect of inertial filtering on the particle kinetic energies and accelerations diminishes with increasing Reynolds number and is well captured by the models of Abrahamson (Chem. Engng Sci., vol. 30, 1975, pp. 1371–1379) and Zaichik & Alipchenkov (Intl J. Multiphase Flow, vol. 34 (9), 2008, pp. 865–868), respectively. We then consider particle-pair statistics, and focus our attention on the relative velocities and radial distribution functions (RDFs) of the particles, with the aim of understanding the underlying physical mechanisms contributing to particle collisions. The relative velocity statistics indicate that preferential sampling effects are important for $St\lesssim 0.1$ and that path-history/non-local effects become increasingly important for $St\gtrsim 0.2$. While higher-order relative velocity statistics are influenced by the increased intermittency of the turbulence at high Reynolds numbers, the lower-order relative velocity statistics are only weakly sensitive to changes in Reynolds number at low $St$. The Reynolds-number trends in these quantities at intermediate and large $St$ are explained based on the influence of the available flow scales on the path-history and inertial filtering effects. We find that the RDFs peak near $St$ of order unity, that they exhibit power-law scaling for low and intermediate $St$ and that they are largely independent of Reynolds number for low and intermediate $St$. We use the model of Zaichik & Alipchenkov (New J. Phys., vol. 11, 2009, 103018) to explain the physical mechanisms responsible for these trends, and find that this model is able to capture the quantitative behaviour of the RDFs extremely well when direct numerical simulation data for the structure functions are specified, in agreement with Bragg & Collins (New J. Phys., vol. 16, 2014a, 055013). We also observe that at large $St$, changes in the RDF are related to changes in the scaling exponents of the relative velocity variances. The particle collision kernel closely matches that computed by Rosa et al. (New J. Phys., vol. 15, 2013, 045032) and is found to be largely insensitive to the flow Reynolds number. This suggests that relatively low-Reynolds-number simulations may be able to capture much of the relevant physics of droplet collisions and growth in the adiabatic cores of atmospheric clouds.


2022 ◽  
Vol 933 ◽  
Author(s):  
Michele Pinelli ◽  
H. Herlina ◽  
J.G. Wissink ◽  
M. Uhlmann

We present direct numerical simulation results of turbulent open channel flow at bulk Reynolds numbers up to 12 000, coupled with (passive) scalar transport at Schmidt numbers up to 200. Care is taken to capture the very large-scale motions which appear already for relatively modest Reynolds numbers. The transfer velocity at the flat, free surface is found to scale with the Schmidt number to the power ‘ $-1/2$ ’, in accordance with previous studies and theoretical predictions for uncontaminated surfaces. The scaling of the transfer velocity with Reynolds number is found to vary, depending on the Reynolds number definition used. To compare the present results with those obtained in other systems, we define a turbulent Reynolds number at the edge of the surface-influenced layer. This allows us to probe the two-regime model of Theofanous et al. (Intl J. Heat Mass Transfer, vol. 19, 1976, pp. 613–624), which is found to correctly predict that small-scale vortices significantly affect the mass transfer for turbulent Reynolds numbers larger than 500. It is further established that the root mean square of the surface divergence is, on average, proportional to the mean transfer velocity. However, the spatial correlation between instantaneous surface divergence and transfer velocity tends to decrease with increasing Schmidt number and increase with increasing Reynolds number. The latter is shown to be caused by an enhancement of the correlation in high-speed regions, which in turn is linked to the spatial distribution of surface-parallel vortices.


1981 ◽  
Vol 46 (7) ◽  
pp. 1566-1576
Author(s):  
František Vašák ◽  
Václav Kolář ◽  
Zdeněk Brož

Theoretical relation derived in the last study for calculation of the mass transfer coefficient in the region of not fully developed concentration profile at high Schmidt numbers has been verified experimentally. This experimental study has been devoted to measurements of the rate of benzoic acid dissolution into aqueous solutions of glycerol from the internal surface of the pipe of circular cross section in the range 933 ⪬ Sc ⪬ 225 000 and 5 000 ⪬ Re ⪬ 50 000. It has been possible to explain on basis of the theoretical model, the differences between the data of various authors and to obtain a unified description of the phenomena.


Ecosphere ◽  
2021 ◽  
Vol 12 (7) ◽  
Author(s):  
Keridwen M. Whitmore ◽  
Nehemiah Stewart ◽  
Andrea C. Encalada ◽  
Esteban Suárez ◽  
Diego A. Riveros‐Iregui

Sign in / Sign up

Export Citation Format

Share Document