scholarly journals Thin films in partial wetting: stability, dewetting and coarsening

2018 ◽  
Vol 845 ◽  
pp. 642-681 ◽  
Author(s):  
A. Alizadeh Pahlavan ◽  
L. Cueto-Felgueroso ◽  
A. E. Hosoi ◽  
G. H. McKinley ◽  
R. Juanes

A uniform nanometric thin liquid film on a solid substrate can become unstable due to the action of van der Waals (vdW) forces. The instability leads to dewetting of the uniform film and the formation of drops. To minimize the total free energy of the system, these drops coarsen over time until one single drop remains. Here, using a thermodynamically consistent framework, we derive a new model for thin films in partial wetting with a free energy that resembles the Cahn–Hilliard form with a height-dependent surface tension that leads to a generalized disjoining pressure, and revisit the dewetting problem. Using both linear stability analysis and nonlinear simulations we show that the new model predicts a slightly smaller critical instability wavelength and a significantly (up to six-fold) faster growth rate than the classical model in the spinodal regime; this faster growth rate brings the theoretical predictions closer to published experimental observations. During coarsening at intermediate times, the dynamics become self-similar and model-independent; we therefore observe the same scalings in both the classical (with and without thermal noise) and new models. Both models also lead to a mean-field Lifshitz–Slyozov–Wagner (LSW)-type droplet-size distribution at intermediate times for small drop sizes. We, however, observe a skewed drop-size distribution for larger drops in the new model; while the tail of the distribution follows a Smoluchowski equation, it is not associated with a coalescence-dominated coarsening, calling into question the association made in some earlier experiments. Our observations point to the importance of the height dependence of surface tension in the early and late stages of dewetting of nanometric films and motivate new high-resolution experimental observations to guide the development of improved models of interfacial flows at the nanoscale.

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Changsheng Dou ◽  
Jialiang Wang ◽  
Weiwei Wang

AbstractWe investigate the effect of (interface) surface tensor on the linear Rayleigh–Taylor (RT) instability in stratified incompressible viscous fluids. The existence of linear RT instability solutions with largest growth rate Λ is proved under the instability condition (i.e., the surface tension coefficient ϑ is less than a threshold $\vartheta _{\mathrm{c}}$ ϑ c ) by the modified variational method of PDEs. Moreover, we find a new upper bound for Λ. In particular, we directly observe from the upper bound that Λ decreasingly converges to zero as ϑ goes from zero to the threshold $\vartheta _{\mathrm{c}}$ ϑ c .


2015 ◽  
Vol 115 (3) ◽  
Author(s):  
Amir Alizadeh Pahlavan ◽  
Luis Cueto-Felgueroso ◽  
Gareth H. McKinley ◽  
Ruben Juanes

2007 ◽  
Vol 992 ◽  
Author(s):  
Christos F. Karanikas ◽  
James J. Watkins

AbstractThe kinetics of the deposition of ruthenium thin films from the hydrogen assisted reduction of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II), [Ru(tmhd)2cod], in supercritical carbon dioxide was studied in order to develop a rate expression for the growth rate as well as to determine a mechanism for the process. The deposition temperature was varied from 240°C to 280°C and the apparent activation energy was 45.3 kJ/mol. Deposition rates up to 30 nm/min were attained. The deposition rate dependence on precursor concentrations between 0 and 0.2 wt. % was studied at 260°C with excess hydrogen and revealed first order deposition kinetics with respect to precursor at concentrations lower then 0.06 wt. % and zero order dependence at concentrations above 0.06 wt. %. The effect of reaction pressure on the growth rate was studied at a constant reaction temperature of 260°C and pressures between 159 bar to 200 bar and found to have no measurable effect on the growth rate.


2021 ◽  
Vol 7 (1) ◽  
pp. 14
Author(s):  
Dewi Suriyani Che Halin ◽  
Kamrosni Abdul Razak ◽  
Mohd Arif Anuar Mohd Salleh ◽  
Mohd Izrul Izwan Ramli ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
...  

Ag/TiO2 thin films were prepared using the sol-gel spin coating method. The microstructural growth behaviors of the prepared Ag/TiO2 thin films were elucidated using real-time synchrotron radiation imaging, its structure was determined using grazing incidence X-ray diffraction (GIXRD), its morphology was imaged using the field emission scanning electron microscopy (FESEM), and its surface topography was examined using the atomic force microscope (AFM) in contact mode. The cubical shape was detected and identified as Ag, while the anatase, TiO2 thin film resembled a porous ring-like structure. It was found that each ring that coalesced and formed channels occurred at a low annealing temperature of 280 °C. The energy dispersive X-ray (EDX) result revealed a small amount of Ag presence in the Ag/TiO2 thin films. From the in-situ synchrotron radiation imaging, it was observed that as the annealing time increased, the growth of Ag/TiO2 also increased in terms of area and the number of junctions. The growth rate of Ag/TiO2 at 600 s was 47.26 µm2/s, and after 1200 s it decreased to 11.50 µm2/s and 11.55 µm2/s at 1800 s. Prolonged annealing will further decrease the growth rate to 5.94 µm2/s, 4.12 µm2/s and 4.86 µm2/s at 2400 s, 3000 s and 3600 s, respectively.


2019 ◽  
Vol 233 (8) ◽  
pp. 1109-1127
Author(s):  
Biraj Kumar Barman ◽  
Kanak Roy ◽  
Mahendra Nath Roy

Abstract Structurally different Molecules namely Pentoxifylline and Pralidoxim were chosen along with α-cyclodextrin and β-cyclodextrin to study host-guest inclusion phenomena. The formations of host guest inclusion complexes were confirmed by studying 1H-NMR spectra, FT-IR spectra, apparent molar volume and viscosity co-efficient. The stabilities of inclusion complexes were compared calculating the binding constant from UV-VIS spectroscopic study. The 1:1 stoichiometry of the inclusion complexes were also determined by analysing the Jobs plot and surface tension data. The values for Gibbs’ free energy were found negative for both the processes. Based on all the above experiments the inclusion processes were found feasible for both the compounds. These types of inclusion complexes are of high interest in the field of research and industry as these are used as drug delivery systems.


1993 ◽  
Vol 248 ◽  
pp. 363-381 ◽  
Author(s):  
G. H. Wheless ◽  
G. T. Csanady

We used a compound matrix method to integrate the Orr–Sommerfeld equation in an investigation of short instability waves (λ < 6 cm) on the coupled shear flow at the air–sea interface under suddenly imposed wind (a gust model). The method is robust and fast, so that the effects of external variables on growth rate could easily be explored. As expected from past theoretical studies, the growth rate proved sensitive to air and water viscosity, and to the curvature of the air velocity profile very close to the interface. Surface tension had less influence, growth rate increasing somewhat with decreasing surface tension. Maximum growth rate and minimum wave speed nearly coincided for some combinations of fluid properties, but not for others.The most important new finding is that, contrary to some past order of magnitude estimates made on theoretical grounds, the eigenfunctions at these short wavelengths are confined to a distance of the order of the viscous wave boundary-layer thickness from the interface. Correspondingly, the perturbation vorticity is high, the streamwise surface velocity perturbation in typical cases being five times the orbital velocity of free waves on an undisturbed water surface. The instability waves should therefore be thought of as fundamentally different flow structures from free waves: given their high vorticity, they are akin to incipient turbulent eddies. They may also be expected to break at a much lower steepness than free waves.


Anales AFA ◽  
2020 ◽  
Vol 31 (3) ◽  
pp. 107-111
Author(s):  
J.R. Mac Intyre ◽  
◽  
J.M. Gomba ◽  
C. A. Perazzo ◽  
◽  
...  

We study the migration of droplets on a solid surface which is under a uniform temperature gradient. The present article focus on partial wetting fluids which surface tension depends on the squared temperature. These type of liquids, called self-rewetting, show a complex dynamics and here we will compare with those liquids of linear dependence in the temperature. Unlike to the latter ones, the droplet width increases with the time.


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