Effect of Wetting and Drying of Soil on Sorption and Biodegradation of Atrazine

Weed Science ◽  
1995 ◽  
Vol 43 (2) ◽  
pp. 298-305 ◽  
Author(s):  
Daniel R. Shelton ◽  
Ali M. Sadeghi ◽  
Jeffrey S. Karns ◽  
Cathleen J. Hapeman
Keyword(s):  
Soil Solution ◽  
Crop Residues ◽  
Soil Drying ◽  
Short Term ◽  
Sorptive Capacity ◽  
Wetting And Drying ◽  
Unamended Soil ◽  
Drying And Rewetting ◽  
Independent Analysis ◽  
Kinetics Of

Short term incubations (4 d) were conducted to assess the effect of a wetting/drying cycle on atrazine sorption, as well as biodegradation, as a function of various atrazine concentrations (ca. 5, 10, and 25 μg g−1soil) and levels of added crop residues (0, 5, and 10% cornstalks by weight), using a technique that allowed independent analysis of soluble and sorbed atrazine. Soil solution atrazine concentrations decreased, and KdSincreased with increasing crop residues. The sorptive capacity of cornstalks for atrazine was estimated to be 860 μg g−1vs 28 μg g−1for unamended soil. Drying and rewetting resulted in lower soil solution concentrations and decreased extraction efficiencies (13 to 22%) for sorbed atrazine; the effect was most pronounced with added cornstalks. High recoveries of14C from soils (combustion data) indicated that atrazine was not lost to volatilization. Rapid rates of biodegradation were observed in cornstalkamended soils shortly after rewetting; degradation was not observed in unamended soil. A longer incubation (6 wk) was conducted with ca. 10 μg g−1atrazine and 5% cornstalks to assess metabolites and kinetics of biodegradation. Atrazine disappearance was observed after ca. 2 wk with concomitant production of deethyl- and deisopropyl-atrazine at a ratio of ca. 2:1. Dealkylated-atrazine accumulated after ca. 3 wk; there was no evidence for hydroxy-atrazine production. These data suggest that biodegradation may play an important role in atrazine losses in the field despite wetting/drying cycles. In addition, there may be apparent losses of atrazine due to decreased extraction efficiencies as a consequence of wetting/drying cycles, resulting in underestimation of field residues.

Porous Structure and Transport Properties of a Carbonized Phenolic Resin

1995 ◽  
Vol 60 (2) ◽  
pp. 172-187 ◽  
Author(s):  
Pavel Fott ◽  
František Kolář ◽  
Zuzana Weishauptová
Keyword(s):  
Porous Structure ◽  
Transport Properties ◽  
Phenolic Resin ◽  
Arrhenius Equation ◽  
Mercury Porosimetry ◽  
Micropore Volume ◽  
Microporous Structure ◽  
Wetting And Drying ◽  
Phenolic Resins ◽  
Kinetics Of

On carbonizing phenolic resins, the development of porous structure takes place which influences the transport properties of carbonized materials. To give a true picture of this effect, specimens in the shape of plates were prepared and carbonized at various temperatures. The carbonizates obtained were studied by adsorption methods, electron microscopy, and mercury porosimetry. Diffusivities were evaluated in terms of measuring the kinetics of wetting and drying. It was found out that the porous structure of specimens in different stages of carbonization is formed mostly by micropores whose volumes were within 0.06 to 0.22 cm3/g. The maximum micropore volume is reached at the temperature of 750 °C. The dependence of diffusivity on the carbonization temperature is nearly constant at first, begins to increase in the vicinity of 400 °C, and at 600 °C attains its maximum. The experimental results reached are in agreement with the conception of the development and gradual closing of the microporous structure in the course of carbonization. The dependence of diffusivity on temperature can be expressed by the Arrhenius equation. In this connection, two possible models of mass transport were discussed.

scholarly journals Crop residues on short-term CO2 emissions in sugarcane production areas

2013 ◽  
Vol 33 (4) ◽  
pp. 699-708 ◽  
Author(s):  
Mariana M. Corradi ◽  
Alan R. Panosso ◽  
Marcílio V. Martins Filho ◽  
Newton La Scala Junior
Keyword(s):  
Co2 Emissions ◽  
Field Experiments ◽  
Crop Residues ◽  
Soil Surface ◽  
Dry Mass ◽  
Agricultural Crop ◽  
Short Term ◽  
Sugarcane Production ◽  
Soil Temperatures ◽  
Production Areas

The proper management of agricultural crop residues could produce benefits in a warmer, more drought-prone world. Field experiments were conducted in sugarcane production areas in the Southern Brazil to assess the influence of crop residues on the soil surface in short-term CO2 emissions. The study was carried out over a period of 50 days after establishing 6 plots with and without crop residues applied to the soil surface. The effects of sugarcane residues on CO2 emissions were immediate; the emissions from residue-covered plots with equivalent densities of 3 (D50) and 6 (D100) t ha-1 (dry mass) were less than those from non-covered plots (D0). Additionally, the covered fields had lower soil temperatures and higher soil moisture for most of the studied days, especially during the periods of drought. Total emissions were as high as 553.62 ± 47.20 g CO2 m-2, and as low as 384.69 ± 31.69 g CO2 m-2 in non-covered (D0) and covered plot with an equivalent density of 3 t ha-1 (D50), respectively. Our results indicate a significant reduction in CO2 emissions, indicating conservation of soil carbon over the short-term period following the application of sugarcane residues to the soil surface.

scholarly journals A comparison of the short-term kinetics of zinc metabolism in women during fasting and following a breakfast meal

1998 ◽  
Vol 80 (4) ◽  
pp. 363-370 ◽  
Author(s):  
Nicola M. Lowe ◽  
Leslie R. Woodhouse ◽  
Janet C. King
Keyword(s):  
Energy Content ◽  
Compartment Model ◽  
Zinc Metabolism ◽  
Short Term ◽  
Compartment System ◽  
Breakfast Meal ◽  
Physiological Importance ◽  
Two Compartment Model ◽  
Zn Concentration ◽  
Kinetics Of

The physiological importance and mechanism of the postprandial fall in plasma Zn concentration is not well understood. In order to gain further information on this apparent redistribution of plasma Zn, a stable isotope, 70Zn, was used to study the effect of a breakfast meal on plasma Zn kinetics. Nine women participated in two trials, a fasting trial and a breakfast-meal trial; five of the women participated in a third trial in which the energy content of the breakfast meal was doubled. At each trial, 0.1mg of 70Zn was infused intravenously, and the plasma disappearance of the isotope was analysed using a two-compartment model of Zn kinetics. Plasma Zn concentration fell significantly following the two trials in which the subjects were given meals, reaching low points that were 13 and 19 %, respectively, below concentrations at comparable times during the fasting trial. Kinetic analysis revealed that after the doubled breakfast meal there was a significant fall (P < 0.007) in the size of the most rapidly turning over Zn pool (pool (a)) from 2.90 (se 0.13)mg in the fasting state to 2.47 (se 0.14) mg postprandially. The fractional turnover rate of pool (a) to other extravascular Zn pools, i.e. outside the two-compartment system, was also significantly elevated after the doubled breakfast meal (P < 0.05). These results suggest that the decline in plasma Zn concentration following a meal is due to a redistribution of Zn from the plasma to other more slowly turning over extravascular pools that may be involved in the assimilation and metabolism of fuels following food intake.

scholarly journals Vertisols and Cambisols had contrasting short term greenhouse gas responses to crop residue management

2020 ◽  
Vol 66 (No. 5) ◽  
pp. 222-233 ◽  
Author(s):  
Giuseppe Badagliacca ◽  
Robert Martin Rees ◽  
Dario Giambalvo ◽  
Sergio Saia
Keyword(s):  
Faba Bean ◽  
Crop Residues ◽  
Residue Management ◽  
Short Term ◽  
N Dynamics ◽  
Total N ◽  
Soil C ◽  
Residue Decomposition ◽  
Soil C And N ◽  
C And N

In sustainable agriculture crop residues management should consider the interactions between soil and residue properties, which can affect the decomposition and global greenhouse gases (GHGs) emission. Through a laboratory experiment, we investigated the effect of the management (incorporation and surface placement) of wheat and faba bean residues on their decomposition and CO<sub>2</sub>, CH<sub>4</sub> and N<sub>2</sub>O emissions from two soils, a Chromic Vertisol and an Eutric Cambisol. In the Vertisol, wheat residues increased the CO<sub>2</sub> emission more than faba bean when left on the surface whereas no differences among residues were observed when incorporated. In the Cambisol, faba bean emitted more than wheat when left in the surface and less when incorporated. Total CH<sub>4</sub> emissions were higher in faba bean in Cambisol for both management and only when applied in the surface in Vertisol. Total N<sub>2</sub>O emission in the Vertisol was higher when faba bean was incorporated, and wheat was left on the surface. In the Cambisol, wheat addition increased total N<sub>2</sub>O emissions by 20% compared to faba bean, with no differences between managements. Our study confirmed that contrasting properties among tested soils resulted in significant interactions with residues own degradability and their placement affecting residue decomposition, soil C and N dynamics, and GHGs emission.

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