scholarly journals Reproduction of the Interstellar Ice Band by Grain Mantle Analogs

1980 ◽  
Vol 87 ◽  
pp. 387-388
Author(s):  
W. Hagen ◽  
A.G.G.M. Tielens ◽  
J. M. Greenberg
Keyword(s):  
Low Temperature ◽  
Interstellar Dust ◽  
Near Infrared ◽  
Absorption Feature ◽  
Band Shape ◽  
Interstellar Ice ◽  
Infrared Spectrometer ◽  
Simple Molecules ◽  
Many Sources ◽  
Dust Grain

The near-infrared spectrum of many sources associated with molecular clouds shows a broad absorption feature at 3.08 μm (e.g. Merrill et al., 1976; Harris et al., 1978). This feature has usually been attributed to absorption by H2O ice frozen on grains, but it has been impossible to satisfactorily reproduce the observed band shape (Merrill et al., 1976; Mukai et al., 1978). We have been able to obtain a complete fit of this absorption feature in the laboratory using very low temperature mixtures of H2O with other polar molecules. The preparation of these interstellar dust grain-mantle analogs has been described elsewhere (Greenberg, 1979; Hagen et al., 1979). They are prepared by allowing a gas mixture of simple molecules (e.g. CO, H2O, NH3, CH4 etc.) to condense on a low temperature (10 K) substrate. This frozen mixture can be heated and recooled. The samples are analyzed with an infrared spectrometer.

The surface composition of asteroid 162173 Ryugu from Hayabusa2 near-infrared spectroscopy

Science ◽  
2019 ◽  
pp. eaav7432 ◽  
Author(s):  
K. Kitazato ◽  
R. E. Milliken ◽  
T. Iwata ◽  
M. Abe ◽  
M. Ohtake ◽  
...  
Keyword(s):  
Near Infrared ◽  
Surface Composition ◽  
Parent Body ◽  
Absorption Feature ◽  
Direct Measurements ◽  
Band Position ◽  
Infrared Spectrometer ◽  
Sample Return Mission ◽  
Near Infrared Spectrometer ◽  
Rubble Pile

The near-Earth asteroid 162173 Ryugu, the target of Hayabusa2 sample return mission, is thought to be a primitive carbonaceous object. We report reflectance spectra of Ryugu’s surface acquired with the Near Infrared Spectrometer (NIRS3) on Hayabusa2, to provide direct measurements of the surface composition and geological context for the returned samples. A weak, narrow absorption feature centered at 2.72 μm was detected across the entire observed surface, indicating that hydroxyl (OH)-bearing minerals are ubiquitous there. The intensity of the OH feature and low albedo are similar to thermally- and/or shock-metamorphosed carbonaceous chondrite meteorites. There are few variations in the OH-band position, consistent with Ryugu being a compositionally homogeneous rubble-pile object, generated from impact fragments of an undifferentiated aqueously altered parent body.

scholarly journals O2 signature in thin and thick O2−H2O ices

2018 ◽  
Vol 620 ◽  
pp. A46 ◽  
Author(s):  
B. Müller ◽  
B. M. Giuliano ◽  
L. Bizzocchi ◽  
A. I. Vasyunin ◽  
P. Caselli
Keyword(s):  
Near Infrared ◽  
Pure Water ◽  
Future Mission ◽  
Infrared Spectral ◽  
Infrared Spectrometer ◽  
The One ◽  
Dust Grain ◽  
Comet 67P ◽  
O 10

Aims. In this paper we investigate the detectability of the molecular oxygen in icy dust grain mantles towards astronomical objects. Methods. We present a systematic set of experiments with O2−H2O ice mixtures designed to disentangle how the molecular ratio affects the O2 signature in the mid- and near-infrared spectral regions. All the experiments were conducted in a closed-cycle helium cryostat coupled to a Fourier transform infrared spectrometer. The ice mixtures comprise varying thicknesses from 8 × 10−3 to 3 μm. The absorption spectra of the O2−H2O mixtures are also compared to the one of pure water. In addition, the possibility to detect the O2 in icy bodies and in the interstellar medium is discussed. Results. We are able to see the O2 feature at 1551 cm−1 even for the most diluted mixture of H2O:O2 = 9:1, comparable to a ratio of O2/H2O = 10% which has already been detected in situ in the coma of the comet 67P/Churyumov-Gerasimenko. We provide an estimate for the detection of O2 with the future mission of the James Webb Space Telescope (JWST).

Photochemical Evolution of Interstellar/Precometary Organic Material

1997 ◽  
Vol 161 ◽  
pp. 23-47 ◽  
Author(s):  
Louis J. Allamandola ◽  
Max P. Bernstein ◽  
Scott A. Sandford
Keyword(s):  
Origin Of Life ◽  
Building Blocks ◽  
Complex Species ◽  
Infrared Observations ◽  
Interstellar Ice ◽  
Polycyclic Aromatic ◽  
Ultraviolet Photolysis ◽  
The Origin Of Life ◽  
Simple Molecules ◽  
Complex Organic

AbstractInfrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Since comets are thought to be a major source of the volatiles on the primative earth, their organic inventory is of central importance to questions concerning the origin of life. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, CH4, H2, and probably some NH3and H2CO, as well as more complex species including nitriles, ketones, and esters. The evidence for these, as well as carbonrich materials such as polycyclic aromatic hydrocarbons (PAHs), microdiamonds, and amorphous carbon is briefly reviewed. This is followed by a detailed summary of interstellar/precometary ice photochemical evolution based on laboratory studies of realistic polar ice analogs. Ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and the moderately complex organic molecules: CH3CH2OH (ethanol), HC(= O)NH2(formamide), CH3C(= O)NH2(acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C6H12N4), as well as more complex species including polyoxymethylene and related species (POMs), amides, and ketones. The ready formation of these organic species from simple starting mixtures, the ice chemistry that ensues when these ices are mildly warmed, plus the observation that the more complex refractory photoproducts show lipid-like behavior and readily self organize into droplets upon exposure to liquid water suggest that comets may have played an important role in the origin of life.

scholarly journals Characterization and mapping of hematite ore mineral classes using hyperspectral remote sensing technique: a case study from Bailadila iron ore mining region

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Ibrahim Shaik ◽  
S. K. Begum ◽  
P. V. Nagamani ◽  
Narayan Kayet
Keyword(s):  
Infrared Absorption ◽  
Near Infrared ◽  
Spectral Feature ◽  
Absorption Feature ◽  
X Ray ◽  
Remote Sensing Technique ◽  
Ore Minerals ◽  
Feature Fitting ◽  
Hematite Ore

AbstractThe study demonstrates a methodology for mapping various hematite ore classes based on their reflectance and absorption spectra, using Hyperion satellite imagery. Substantial validation is carried out, using the spectral feature fitting technique, with the field spectra measured over the Bailadila hill range in Chhattisgarh State in India. The results of the study showed a good correlation between the concentration of iron oxide with the depth of the near-infrared absorption feature (R2 = 0.843) and the width of the near-infrared absorption feature (R2 = 0.812) through different empirical models, with a root-mean-square error (RMSE) between < 0.317 and < 0.409. The overall accuracy of the study is 88.2% with a Kappa coefficient value of 0.81. Geochemical analysis and X-ray fluorescence (XRF) of field ore samples are performed to ensure different classes of hematite ore minerals. Results showed a high content of Fe > 60 wt% in most of the hematite ore samples, except banded hematite quartzite (BHQ) (< 47 wt%).

scholarly journals The Improvement on the Performance of DMD Hadamard Transform Near-Infrared Spectrometer by Double Filter Strategy and a New Hadamard Mask

Micromachines ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 149 ◽  
Author(s):  
Zifeng Lu ◽  
Jinghang Zhang ◽  
Hua Liu ◽  
Jialin Xu ◽  
Jinhuan Li
Keyword(s):  
Near Infrared ◽  
Signal To Noise Ratio ◽  
Nonuniform Distribution ◽  
Stray Light ◽  
Spectral Energy ◽  
Hadamard Transform ◽  
Digital Micromirror Device ◽  
Infrared Spectrometer ◽  
Near Infrared Spectrometer ◽  
The Impact

In the Hadamard transform (HT) near-infrared (NIR) spectrometer, there are defects that can create a nonuniform distribution of spectral energy, significantly influencing the absorbance of the whole spectrum, generating stray light, and making the signal-to-noise ratio (SNR) of the spectrum inconsistent. To address this issue and improve the performance of the digital micromirror device (DMD) Hadamard transform near-infrared spectrometer, a split waveband scan mode is proposed to mitigate the impact of the stray light, and a new Hadamard mask of variable-width stripes is put forward to improve the SNR of the spectrometer. The results of the simulations and experiments indicate that by the new scan mode and Hadamard mask, the influence of stray light is restrained and reduced. In addition, the SNR of the spectrometer also is increased.

Investigating the total antioxidant capacity of gluten-free grains with miniaturized near-infrared spectrometer

NIR news ◽  
2019 ◽  
Vol 30 (5-6) ◽  
pp. 35-38
Author(s):  
Verena Wiedemair ◽  
Christian Wolfgang Huck
Keyword(s):  
Antioxidant Capacity ◽  
Total Antioxidant Capacity ◽  
High Performance ◽  
Near Infrared ◽  
Least Squares Regression ◽  
Test Set ◽  
Total Antioxidant ◽  
Infrared Spectrometer ◽  
Near Infrared Spectrometer ◽  
Infrared Instruments

The use of ever smaller near-infrared instruments is becoming more and more prevalent, since they are cheaper, more versatile and often advertised as high-performance spectrometer. The last claim is rarely verified by independent researchers, which is why the presented work evaluates the performance of three hand-held spectrometers in comparison to a benchtop instrument. Seventy-seven samples comprising buckwheat, millet and oat were investigated for their total antioxidant capacity using Folin–Ciocalteu and near-infrared spectroscopy. Partial least squares regression models were established using cross- and test set validation. Results showed that all instruments were able to predict total antioxidant capacity to some extent. The coefficients of determinations ranged from 0.823 to 0.951 for cross-validated and from 0.849 to 0.952 for test set validated models. Errors for cross-validated models ranged from 1.11 to 2.08 mgGAE/g and for test set validated models from 1.02 to 1.86 mgGAE/g.

scholarly journals Connecting the Interstellar Gas and Dust Properties in Distant Galaxies Using Quasar Absorption Systems

2015 ◽  
Vol 11 (S315) ◽  
Author(s):  
Monique C. Aller ◽  
Varsha P. Kulkarni ◽  
Donald G. York ◽  
Daniel E. Welty ◽  
Giovanni Vladilo ◽  
...  
Keyword(s):  
Star Formation ◽  
Galaxy Evolution ◽  
Absorption Feature ◽  
Dust Grains ◽  
Interstellar Gas ◽  
Chemical Enrichment ◽  
Normal Galaxies ◽  
History Of ◽  
Dust Grain ◽  
Grain Properties

AbstractGas and dust grains are fundamental components of the interstellar medium and significantly impact many of the physical processes driving galaxy evolution, such as star-formation, and the heating, cooling, and ionization of the interstellar material. Quasar absorption systems (QASs), which trace intervening galaxies along the sightlines to luminous quasars, provide a valuable tool to directly study the properties of the interstellar gas and dust in distant, normal galaxies. We have established the presence of silicate dust grains in at least some gas-rich QASs, and find that they exist at higher optical depths than expected for diffuse gas in the Milky Way. Differences in the absorption feature shapes additionally suggest variations in the silicate dust grain properties, such as in the level of grain crystallinity, from system-to-system. We present results from a study of the gas and dust properties of QASs with adequate archival IR data to probe the silicate dust grain properties. We discuss our measurements of the strengths of the 10 and 18 μm silicate dust absorption features in the QASs, and constraints on the grain properties (e.g., composition, shape, crystallinity) based on fitted silicate profile templates. We investigate correlations between silicate dust abundance, reddening, and gas metallicity, which will yield valuable insights into the history of star formation and chemical enrichment in galaxies.

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