Metallurgical Effects of Grain Boundary Ledges

1977 ◽  
Vol 35 ◽  
pp. 126-129
Author(s):  
L.E. Murr
Keyword(s):  
Grain Boundary ◽  
Quantitative Data ◽  
Mechanical Treatment ◽  
Unit Length ◽  
Physical And Mechanical Properties ◽  
Direct Observations ◽  
Transmission Electron ◽  
Properties Of Materials ◽  
Thermo Mechanical Treatment ◽  
Ledge Density

Ledges in grain boundaries can be identified by their characteristic contrast features (straight, black-white lines) distinct from those of lattice dislocations, for example1,2 [see Fig. 1(a) and (b)]. Simple contrast rules as pointed out by Murr and Venkatesh2, can be established so that ledges may be recognized with come confidence, and the number of ledges per unit length of grain boundary (referred to as the ledge density, m) measured by direct observations in the transmission electron microscope. Such measurements can then give rise to quantitative data which can be used to provide evidence for the influence of ledges on the physical and mechanical properties of materials.It has been shown that ledge density can be systematically altered in some metals by thermo-mechanical treatment3,4.

scholarly journals EFFECT OF THERMO-MECHANICAL TREATMENT ON PROPERTIES OF PARICA PLYWOODS (Schizolobium amazonicum Huber ex Ducke)

2017 ◽  
Vol 41 (1) ◽  
Author(s):  
Mírian de Almeida Costa ◽  
Cláudio Henrique Soares Del Menezzi
Keyword(s):  
Mechanical Properties ◽  
Mechanical Treatment ◽  
Physical And Mechanical Properties ◽  
The Other ◽  
Modulus Of Rupture ◽  
Thermal Treatments ◽  
Mechanical Compression ◽  
Specific Mass ◽  
Thermo Mechanical Treatment ◽  
Temperature And Pressure

ABSTRACT Thermo-mechanical treatment is a technique for wood modification in which samples are densified by means of heat and mechanical compression, applied perpendicularly to fibers, which under different combinations of time, temperature, and pressure increases wood density and thus improve some of its properties. This study aimed to treat thermo-mechanically parica plywood and observe the effects on its physical and mechanical properties. Specimens were submitted to two treatments, 120 and 150 ºC, remaining under pressure for seven minutes and, subsequently, under zero pressure for 15 minutes. Results showed a significant increase in specific mass from 0.48 g cm-3 to an average of 0.56 g cm-3, and a compression ratio of about 31.7% on average. Physical properties also varied significantly and results showed that treated samples swelled and absorbed more water than those untreated, leading to a greater thickness non-return rate. This indicates the proposed thermal treatments did not release the internal compressive stress generated during panel pressing, not improving its dimensional stability as a result. On the other hand, mechanical properties were positively affected, leading to an increase of 27.5% and 51.8% in modulus of rupture after treatments at 120 and 150 ºC, respectively. Modulus of elasticity and glue-line shear strength did not vary statistically and Janka hardness was 29.7% higher after treatment at 150 ºC.

Grain Boundary Engineering of Metals by Thermo-Mechanical Treatment

2010 ◽  
Vol 659 ◽  
pp. 349-354
Author(s):  
Péter János Szabó
Keyword(s):  
Heat Treatment ◽  
Grain Boundary ◽  
Stainless Steels ◽  
Mechanical Treatment ◽  
Austenitic Stainless Steels ◽  
Grain Boundary Engineering ◽  
Aisi 304 ◽  
Relative Fraction ◽  
Heat Treated ◽  
Thermo Mechanical Treatment

The relative fraction of the special grain boundaries can be increased by thermo-mechanical treatments. During this work, AISI 304-type austenitic stainless steels were plastically deformed and heat treated under different conditions, and then the grain boundary network, which developed during the treatments was investigated. Results showed that cyclic application of large cold rolling (30% reduction of thickness) and quick heat treatment at high temperature (800 °C, 2 minutes) gave the best grain boundary network. A possible reason of this behaviour is that grains which did not recrystallize after the first cycle, stored a high elastic energy, which helped the grain boundary motions in the next cycles. To characterize the developed grain boundary network, different parameters are also suggested in this paper.

Tailoring Grain-Boundary Segregation to Control Mechanical Properties

1999 ◽  
Vol 586 ◽  
Author(s):  
D. B. Williams ◽  
V. J. Keast
Keyword(s):  
Mechanical Properties ◽  
Grain Boundary ◽  
Boundary Segregation ◽  
X Ray ◽  
Transmission Electron ◽  
Intergranular Brittle Fracture ◽  
Properties Of Materials ◽  
Boundary Chemistry ◽  
First Time

ABSTRACTRecent advances in our understanding of the role of the chemistry of grain boundaries in controlling the mechanical properties of materials (in particular intergranular brittle fracture) are reviewed. It is now possible in a modem field-emission gun (FEG) analytical transmission electron microscope (AEM) to measure the chemistry of sub-nanometer films of GB segregants while at the same time observing the effect (if any) on the bonding of the atoms within a nanometer of the boundary plane. This has been accomplished by the development of X-ray mapping (XRM) a powerful new tool for the study of segregation. For the first time, in the same instrument, on the same grain boundary, any changes in the boundary chemistry can be correlated with the occurrence or absence of brittle failure, which is often associated with boundary segregation. There is strong evidence that boundary segregation is extremely nonuniform, even in some strongly embrittling systems (e.g. Cu-Bi) and in these same systems, embrittling segregants introduce subtle but consistent changes in the bonding. Non-embrittling segregants (e.g. Ag in Cu) do not introduce detectable bonding changes.

Direct Observations of Grain Boundary Phenomena during Indentation of Al and Al-Mg Thin Films

2003 ◽  
Vol 795 ◽  
Author(s):  
W. A. Soer ◽  
J. Th. M. De Hosson ◽  
A. M. Minor ◽  
E. A. Stach ◽  
J. W. Morris
Keyword(s):  
Thin Films ◽  
Grain Boundary ◽  
Grain Boundaries ◽  
Dislocation Dynamics ◽  
Direct Observations ◽  
Transmission Electron ◽  
The Matrix ◽  
Grain Boundary Motion

ABSTRACTThe deformation behavior of Al and Al-Mg thin films has been studied with the unique experimental approach of in-situ nanoindentation in a transmission electron microscope. This paper concentrates on the role of solute Mg additions in the transfer of plasticity across grain boundaries. The investigated Al alloys were deposited onto a Si substrate as thin films with a thickness of 200–300 nm and Mg concentrations of 0, 1.1, 1.8, 2.6 and 5.0 wt% Mg. The results show that in the Al-Mg alloys, the solutes effectively pin high-angle grain boundaries, while in pure Al considerable grain boundary motion is observed at room temperature. The mobility of low-angle grain boundaries is however not affected by the presence of Mg. In addition, Mg was observed to affect dislocation dynamics in the matrix.

Grain Refinement in AZ91E Magnesium Alloy by Thermo-Mechanical Treatments

2005 ◽  
Vol 475-479 ◽  
pp. 493-496 ◽  
Author(s):  
Atsushi Yamamoto ◽  
Masahiko Ikeda ◽  
Harushige Tsubakino
Keyword(s):  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Boundary ◽  
Grain Refinement ◽  
Mechanical Treatment ◽  
Fine Grained ◽  
Heat Treated ◽  
Cold Rolled ◽  
Thermo Mechanical Treatment ◽  
Hot Rolled

In order to improve poor formability in magnesium alloy, grain refinement has been attempted on AZ91E alloy by a thermo-mechanical treatment. Specimens were firstly cold-rolled at 10 %, then solution heat treated at 673 K for 86.4 ks, and hot-rolled at 573 K with about 5 % for four passes, or hot-rolled at 20 % with one pass. The rolled specimens were finally heat treated at 473 to 673 K for 3.6 to 36 ks. Microstructures in the starting material characterized by grain boundary precipitates and aluminum rich regions with about 180 µm in grain size were changed into fine grained microstructures with about 10 to 30 µm in diameter, in which precipitates of Mg17Al12 were uniformly distributed. Although the specimen was prepared by rolling, the (0001) texture was not so remarkable.

scholarly journals Emission of Dislocations from Grain Boundaries and Its Role in Nanomaterials

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 41
Author(s):  
James C. M. Li ◽  
C. R. Feng ◽  
Bhakta B. Rath
Keyword(s):  
Electron Microscopy ◽  
Grain Boundary ◽  
Grain Boundaries ◽  
Polycrystalline Materials ◽  
Supporting Evidence ◽  
Petch Relation ◽  
Direct Observations ◽  
Transmission Electron ◽  
Alternate Mechanism

The Frank-Read model, as a way of generating dislocations in metals and alloys, is widely accepted. In the early 1960s, Li proposed an alternate mechanism. Namely, grain boundary sources for dislocations, with the aim of providing a different model for the Hall-Petch relation without the need of dislocation pile-ups at grain boundaries, or Frank-Read sources inside the grain. This article provides a review of his model, and supporting evidence for grain boundaries or interfacial sources of dislocations, including direct observations using transmission electron microscopy. The Li model has acquired new interest with the recent development of nanomaterial and multilayers. It is now known that nanocrystalline metals/alloys show a behavior different from conventional polycrystalline materials. The role of grain boundary sources in nanomaterials is reviewed briefly.

Void-Lattice Formation in Natural Fluorite by Electron Irradiation

1976 ◽  
Vol 34 ◽  
pp. 614-615 ◽  
Author(s):  
L.E. Murr
Keyword(s):  
Electron Microscope ◽  
Electron Irradiation ◽  
Heavy Ion ◽  
High Energy ◽  
Stoichiometric Ratio ◽  
Direct Observations ◽  
Transmission Electron ◽  
Anion Vacancies ◽  
Cation And Anion Vacancies ◽  
Lattice Formation

The production of void lattices in metals as a result of displacement damage associated with high energy and heavy ion bombardment is now well documented. More recently, Murr has shown that a void lattice can be developed in natural (colored) fluorites observed in the transmission electron microscope. These were the first observations of a void lattice in an irradiated nonmetal, and the first, direct observations of color-center aggregates. Clinard, et al. have also recently observed a void lattice (described as a high density of aligned "pores") in neutron irradiated Al2O3 and Y2O3. In this latter work, itwas pointed out that in order that a cavity be formed,a near-stoichiometric ratio of cation and anion vacancies must aggregate. It was reasoned that two other alternatives to explain the pores were cation metal colloids and highpressure anion gas bubbles.Evans has proposed that void lattices result from the presence of a pre-existing impurity lattice, and predicted that the formation of a void lattice should restrict swelling in irradiated materials because it represents a state of saturation.

Interface structures in polycrystalline ceramic materials

1986 ◽  
Vol 44 ◽  
pp. 468-471
Author(s):  
K. J. Morrissey
Keyword(s):  
Electron Microscopy ◽  
Analytical Electron Microscopy ◽  
Physical And Mechanical Properties ◽  
High Resolution Electron Microscopy ◽  
Ceramic Materials ◽  
Polycrystalline Materials ◽  
Transmission Electron ◽  
Resolution Electron ◽  
Interface Structures

Grain boundaries and interfaces play an important role in determining both physical and mechanical properties of polycrystalline materials. To understand how the structure of interfaces can be controlled to optimize properties, it is necessary to understand and be able to predict their crystal chemistry. Transmission electron microscopy (TEM), analytical electron microscopy (AEM,), and high resolution electron microscopy (HREM) are essential tools for the characterization of the different types of interfaces which exist in ceramic systems. The purpose of this paper is to illustrate some specific areas in which understanding interface structure is important. Interfaces in sintered bodies, materials produced through phase transformation and electronic packaging are discussed.

Structural analysis of a Σ5 grain boundary in YBa2Cu3O7δ

1993 ◽  
Vol 51 ◽  
pp. 942-943
Author(s):  
J.-Y. Wang ◽  
Y. Zhu ◽  
A.H. King ◽  
M. Suenaga
Keyword(s):  
Grain Boundary ◽  
Lattice Mismatch ◽  
Weak Link ◽  
Coincidence Site Lattice ◽  
Large Angle ◽  
Dislocation Core ◽  
Superconducting Order Parameter ◽  
Outstanding Problem ◽  
Transmission Electron

One outstanding problem in YBa2Cu3O7−δ superconductors is the weak link behavior of grain boundaries, especially boundaries with a large-angle misorientation. Increasing evidence shows that lattice mismatch at the boundaries contributes to variations in oxygen and cation concentrations at the boundaries, while the strain field surrounding a dislocation core at the boundary suppresses the superconducting order parameter. Thus, understanding the structure of the grain boundary and the grain boundary dislocations (which describe the topology of the boundary) is essential in elucidating the superconducting characteristics of boundaries. Here, we discuss our study of the structure of a Σ5 grain boundary by transmission electron microscopy. The characterization of the structure of the boundary was based on the coincidence site lattice (CSL) model.Fig.l shows two-beam images of the grain boundary near the projection. An array of grain boundary dislocations, with spacings of about 30nm, is clearly visible in Fig. 1(a), but invisible in Fig. 1(b).

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