Locating Al in the DABCO catalyst before and after Al extraction

1990 ◽  
Vol 48 (4) ◽  
pp. 265-267
Author(s):  
Kathleen B. Reuter
Keyword(s):  
Active Site ◽  
Inverse Relationship ◽  
Transverse Direction ◽  
Reaction Rate ◽  
Acid Phosphate ◽  
Fracture Surfaces ◽  
Al Content ◽  
Before And After ◽  
Relationship Of

The reaction rate and efficiency of piperazine to 1,4-diazabicyclo-octane (DABCO) depends on the Si/Al ratio of the MFI topology catalysts. The Al was shown to be the active site, however, in the Si/Al range of 30-200 the reaction rate increases as the Si/Al ratio increases. The objective of this work was to determine the location and concentration of Al to explain this inverse relationship of Al content with reaction rate.Two silicalite catalysts in the form of 1/16 inch SiO2/Al2O3 bonded extrudates were examined: catalyst A with a Si/Al of 83; and catalyst B, the acid/phosphate Al extracted form of catalyst A, with a Si/Al of 175. Five extrudates from each catalyst were fractured in the transverse direction and particles were obtained from the fracture surfaces near the center of the extrudate diameter. Particles were also obtained from the outside surfaces of five extrudates.

The Effect of Active Site-inhibited Factor VIIa on Tissue Factor-initiated Coagulation Using Platelets before and after Aspirin Administration

1997 ◽  
Vol 78 (04) ◽  
pp. 1202-1208 ◽  
Author(s):  
Marianne Kjalke ◽  
Julie A Oliver ◽  
Dougald M Monroe ◽  
Maureane Hoffman ◽  
Mirella Ezban ◽  
...  
Keyword(s):  
Tissue Factor ◽  
Active Site ◽  
Large Scale ◽  
Thrombin Generation ◽  
Factor Viia ◽  
Dependent Manner ◽  
Antithrombotic Agent ◽  
Before And After ◽  
Ic50 Values

SummaryActive site-inactivated factor VIIa has potential as an antithrombotic agent. The effects of D-Phe-L-Phe-L-Arg-chloromethyl ketone-treated factor VIla (FFR-FVIIa) were evaluated in a cell-based system mimicking in vivo initiation of coagulation. FFR-FVIIa inhibited platelet activation (as measured by expression of P-selectin) and subsequent large-scale thrombin generation in a dose-dependent manner with IC50 values of 1.4 ± 0.8 nM (n = 8) and 0.9 ± 0.7 nM (n = 7), respectively. Kd for factor VIIa binding to monocytes ki for FFR-FVIIa competing with factor VIIa were similar (11.4 ± 0.8 pM and 10.6 ± 1.1 pM, respectively), showing that FFR-FVIIa binds to tissue factor in the tenase complex with the same affinity as factor VIIa. Using platelets from volunteers before and after ingestion of aspirin (1.3 g), there were no significant differences in the IC50 values of FFR-FVIIa [after aspirin ingestion, the IC50 values were 1.7 ± 0.9 nM (n = 8) for P-selectin expression, p = 0.37, and 1.4 ± 1.3 nM (n = 7) for thrombin generation, p = 0.38]. This shows that aspirin treatment of platelets does not influence the inhibition of tissue factor-initiated coagulation by FFR-FVIIa, probably because thrombin activation of platelets is not entirely dependent upon expression of thromboxane A2.

Richard Scheringer, the KPD and the Politics of Class and Nation in Germany, 1922–1969

2005 ◽  
Vol 14 (3) ◽  
pp. 317-346 ◽  
Author(s):  
TIMOTHY S. BROWN
Keyword(s):  
Interwar Period ◽  
Third Reich ◽  
Radical Right ◽  
High Profile ◽  
Army Officer ◽  
Modern Germany ◽  
Before And After ◽  
The Third Reich ◽  
Relationship Of ◽  
The Relationship

This article examines the life and times of Richard Scheringer, an army officer and supporter of Adolf Hitler who became famous during the early 1930s for his high-profile conversion to communism. Known in the closing years of the Weimar Republic as a point-man for Communist efforts to win support from the radical right, Scheringer survived the Third Reich to become a leading figure in the postwar Communist Party. His well-documented but little-studied career, bridging critical caesurae of modern Germany history, highlights the unique political constellation of the interwar period, demonstrating fundamental continuities in the relationship of German communism to the nation before and after 1945.

The Relationship of Undifferentiated Mesenchymal Cells to TMJ Articular Tissue Thickness

1992 ◽  
Vol 71 (11) ◽  
pp. 1816-1821 ◽  
Author(s):  
C.A. Bibb ◽  
A.G. Pullinger ◽  
F. Baldioceda
Keyword(s):  
Soft Tissue ◽  
Inverse Relationship ◽  
Biological Processes ◽  
Spearman Correlation ◽  
Articular Eminence ◽  
Tissue Thickness ◽  
Cartilage Layer ◽  
Soft Tissue Thickness ◽  
Relationship Of ◽  
The Relationship

Undifferentiated mesenchymal (UM) cells, the progenitor cells of the cartilage layer, have been assigned a significant role in TMJ articular tissue maintenance. This was based on reports of UM cell reduction with increased soft-tissue thickness for the condyle and temporal component. However, the strength of this inverse relationship was not presented and remained unclear. The purpose of the present study was to assess the strength of the correlation between UM cell presence and soft-tissue thickness in young adult TMJs at autopsy. Sagittal histological sections from the central thirds of 50 joints were evaluated with respect to articular soft-tissue thickness, histological character, and UM cell presence in the condyle and temporal component. The superior sector ofthe condyle and the articular eminence showed the greatest variability in soft-tissue thickness and were the only areas to show localized UM cell absence. The eminence was the only location to show an inverse relationship between soft-tissue thickness and UM cell presence, and this was consistent in both an ANOVA (p = 0.0016) and a Spearman correlation analysis. However, the strength of this correlation was only moderate (rho = -0.52), and no such relationship was observed in any other location. This study suggests that the relationship between UM cell presence and soft-tissue thickness is more complex than previously hypothesized and that the contribution of UM cells to articular tissue maintenance has been overstated, while other biological processes were overlooked.

Inverse Relationship of Subjective Daytime Sleepiness to Sympathetic Activity in Patients With Heart Failure and Obstructive Sleep Apnea

CHEST Journal ◽  
2012 ◽  
Vol 142 (5) ◽  
pp. 1222-1228 ◽  
Author(s):  
Luigi Taranto Montemurro ◽  
John S. Floras ◽  
Philip J. Millar ◽  
Takatoshi Kasai ◽  
Joseph M. Gabriel ◽  
...  
Keyword(s):  
Heart Failure ◽  
Obstructive Sleep Apnea ◽  
Sleep Apnea ◽  
Daytime Sleepiness ◽  
Sympathetic Activity ◽  
Inverse Relationship ◽  
Obstructive Sleep ◽  
Patients With Heart Failure ◽  
Relationship Of

BMI-independent inverse relationship of plasma leptin levels with outcome in patients with acute pulmonary embolism

2012 ◽  
Vol 37 (2) ◽  
pp. 204-210 ◽  
Author(s):  
C Dellas ◽  
M Lankeit ◽  
C Reiner ◽  
K Schäfer ◽  
G Hasenfuß ◽  
...  
Keyword(s):  
Pulmonary Embolism ◽  
Inverse Relationship ◽  
Acute Pulmonary Embolism ◽  
Plasma Leptin ◽  
Relationship Of

RATIONALE FOR MONITORING GROUNDWATER LEVELS IN THE REHABILITATED PEATLANDS OF PRIPYAT POLESIE

2020 ◽  
pp. 33-43
Author(s):  
Olga N. Ratnicava ◽  
Irina P. Lisitsyna ◽  
Inna V. Аgeichik
Keyword(s):  
Field Studies ◽  
Natural State ◽  
Groundwater Levels ◽  
Discharge Water ◽  
Peat Deposits ◽  
Disturbed Areas ◽  
Key Points ◽  
Before And After ◽  
Vegetation Maps ◽  
Relationship Of

Based on studies of geomorphology, stratigraphy, hydrology, various maps of Polesie, zones of influence of amelioration canals, vegetation maps, modern satellite images, as well as field studies of peatlands of Pripyat Polesie, two independent drainage systems have been identified, with a network of amelioration canals that intensively discharge water into the rivers Stwiga and Ybort`. Maps of key points were built In GIS-format, on which five sites were laid in the field within the Mezhch and Neresnya peat deposits for further long-term monitoring of GWL parameters. The locations of the sensors installation are based on the relationship of bog phytocenoses with the average annual GWL values and the amplitude of their fluctuations. Analysis of the GWL parameters before and after environmental rehabilitation measures will allow assessing the effectiveness of planned measures in disturbed areas and obtaining new data on areas of peat deposits in their natural state.

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