Nanosheets of Nickel Iron Hydroxy Carbonate Hydrate with Pronounced OER Activity under Alkaline and Near-Neutral Conditions

2019 ◽  
Vol 58 (3) ◽  
pp. 1895-1904 ◽  
Author(s):  
Kannimuthu Karthick ◽  
Sengeni Anantharaj ◽  
Sivasankara Rao Ede ◽  
Subrata Kundu
Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


2020 ◽  
Author(s):  
wenda wu ◽  
Jian Luo ◽  
Fang Wang ◽  
Bing Yuan ◽  
Tianbiao Liu

Aqueous organic redox flow batteries (AORFBs) have become increasing attractive for scalable energy storage. However, it remains challenging to develop high voltage, powerful AORFBs because of the lack of catholytes with high redox potential. Herein, we report methyl viologen dibromide (<b>[MV]Br<sub>2</sub></b>) as a facile self-trapping, bipolar redox electrolyte material for pH neutral redox flow battery applications. The formation of the <b>[MV](Br<sub>3</sub>)<sub>2</sub></b> complex was computationally predicted and experimentally confirmed. The low solubility <b>[MV](Br<sub>3</sub>)<sub>2</sub></b> complex in the catholyte during the battery charge process not only mitigates the crossover of charged tribromide species (Br<sub>3</sub><sup>-</sup>) and addresses the toxicity concern of volatile bromine simultaneously. A 1.53 V bipolar MV/Br AORFB delivered outstanding battery performance at pH neutral conditions, specifically, 100% total capacity retention, 133 mW/cm<sup>2</sup> power density, and 60% energy efficiency at 40 mA/cm<sup>2</sup>.


Author(s):  
Tiantian Chen ◽  
Yang Yang ◽  
Liyu Xie ◽  
Haijian Yang ◽  
Guangbin Dong ◽  
...  

<p>We report a Ni(0)-catalyzed cross coupling reaction between simple ketones and 1,3-dienes. A variety of a-allylic alkylation products were formed in an 1,2-addition manner with excellent regioselectivity. Water was found to significantly accelerate this transformation. A HO-Ni-H species generated from oxidative addition of Ni(0) to H<sub>2</sub>O is proposed to play a “dual role” in activating both the ketone and the diene substrate.</p>


2019 ◽  
Author(s):  
Ashley DiPuma ◽  
Kelly Rivera ◽  
Edward Ester

Working memory (WM) performance can be improved by an informative cue presented during storage. This effect, termed a retro-cue benefit, can be used to explore mechanisms of attentional prioritization in WM. Directing attention to a single item stored in memory is known to increase memory precision while decreasing the likelihood of incorrect item reports and random guesses, but it is unclear whether similar benefits manifest when participants direct attention to multiple items stored in memory. We tested this possibility by quantifying memory performance when participants were cued to prioritize one or two items stored in working memory. Consistent with prior work, cueing participants to prioritize a single memory item yielded higher recall precision, fewer swap errors, and fewer guesses relative to a neutral cue condition. Conversely, cueing participants to prioritize two memory items yielded fewer swap errors relative to a neutral condition, but no differences in recall precision or guess rates. Although swap rates were less likely during the cue-two vs. neutral conditions, planned comparisons revealed that when participants made swap errors during cue-two trials they were far more likely to confuse two prioritized stimuli than they were to confuse a prioritized stimulus vs. a non-prioritized stimulus. Our results suggest that it is possible to prioritize multiple items stored in memory, with the caveat that doing so may increase the probability of confusing prioritized items.


Alloy Digest ◽  
1975 ◽  
Vol 24 (6) ◽  

Abstract ALLOY 48 is a vacuum-melted, 48% nickel-iron alloy designed for high permeability, and low core losses. It is ideal in applications requiring efficient magnetic core materials, such as audio and instrument transformers, instrument relays, and many other communication equipment devices. It is excellent for rotor and stator laminations, and is also a very effective magnetic shielding material. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Fe-52. Producer or source: Magnetics Specialty Metals Division. See also Alloy Digest Fe-96, April 1992.


Alloy Digest ◽  
1969 ◽  
Vol 18 (10) ◽  

Abstract Niromet 46 is a 46% nickel-iron alloy having low and controlled coefficient of expansion. It is recommended for metal-to-glass seals and terminal bands in vitreous enameled resistors. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Fe-39. Producer or source: Wilbur B. Driver Company.


Alloy Digest ◽  
1968 ◽  
Vol 17 (1) ◽  

Abstract N1-SPAN-C alloy 902 is an age-hardenable, nickel-iron-chromium alloy. Its outstanding characteristic is a controllable thermoelastic coefficient. Proper combination of cold work and thermal treatment can produce an essentially constant modulus of elasticity from -50 F to +150 F. The alloy is especially suitable for many types of precision equipment where elastic members are subject to temperature fluctuations. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness and fatigue. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Fe-32. Producer or source: Huntington Alloy Products Division, An INCO Company.


Alloy Digest ◽  
1964 ◽  
Vol 13 (3) ◽  

Abstract INVAR is a 36% nickel-iron alloy having the lowest coefficient of expansion, recommended for applications requiring no dimensional changes with temperature variations. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Fe-24. Producer or source: Carpenter.


Alloy Digest ◽  
1992 ◽  
Vol 41 (5) ◽  

Abstract INCO ALLOY 330 is a nickel/iron/chromium austenitic alloy, not hardenable by heat treatment. It is a solid solution strengthened high-temperature alloy. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-403. Producer or source: Inco Alloys International Inc..


Alloy Digest ◽  
1953 ◽  
Vol 2 (10) ◽  

Abstract KOVAR A is a cobalt, nickel, iron alloy recommended for sealing into hard glass. Has similar expansion curve as glass, makes firm bond between metal and glass, is easy to machine and form, and has high resistance to thermal shock. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on forming, heat treating, machining, joining, and surface treatment. Filing Code: Fe-3. Producer or source: Carborundum Company, Refractories Division.


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